Secondary battery including solid electrolyte layer

Patent metadata

Field	Value
Publication number	US-9583786-B2
Application number	US-201414415402-A
Country	US
Kind code	B2
Filing date	Nov 25, 2014
Priority date	Nov 26, 2013
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

Provided are a secondary battery including a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode, wherein the positive electrode and the negative electrode include first solid electrolyte particles, the solid electrolyte layer includes second solid electrolyte particles, and a particle diameter of the second solid electrolyte particles is greater than a particle diameter of the first solid electrolyte particles.
In the secondary battery, the electrode may increase the amount of movement of lithium ions by increasing a contact area between the solid electrolyte particles and electrode active material, and the solid electrolyte layer may minimize the reduction of ionic conductivity by decreasing interfacial resistance due to the contact between the electrode and the solid electrolyte layer. Thus, stability and performance of the secondary battery may be improved.

First claim

The invention claimed is:

1. A secondary battery comprising:
a positive electrode,
a negative electrode, and
a solid electrolyte layer disposed between the positive electrode and the negative electrode,
wherein the positive electrode and the negative electrode comprise first solid electrolyte particles,
the solid electrolyte layer comprises second solid electrolyte particles, and
a particle diameter of the second solid electrolyte particles is greater than a particle diameter of the first solid electrolyte particles.

2. The secondary battery of claim 1 , wherein the first solid electrolyte particles and the second solid electrolyte particles comprise a composite oxide represented by Chemical Formula 1:
Li 3x La (2/3-x) TiO 3 (0 <x< 0.16).  <Chemical Formula 1>

3. The secondary battery of claim 1 , wherein the first solid electrolyte particles are nanosized particles and the second solid electrolyte particles are micron-sized particles.

4. The secondary battery of claim 3 , wherein an average particle diameter of the first solid electrolyte particles is in a range of 1 nm to 100 nm.

5. The secondary battery of claim 3 , wherein an average particle diameter of the second solid electrolyte particles is in a range of 1 μm to 10 μm.

6. The secondary battery of claim 1 , wherein a specific surface area (Brunauer-Emmett-Teller (BET)) of the first solid electrolyte particles is in a range of 100 m 2 /g to 400 m 2 /g, and a specific surface area (BET) of the second solid electrolyte particles is in a range of 10 m 2 /g to 50 m 2 /g.

7. The secondary battery of claim 1 , wherein the first solid electrolyte particles are included in an active layer for the positive electrode by being mixed with an active material for the positive electrode.

8. The secondary battery of claim 7 , wherein a mixing weight ratio of the first solid electrolyte particles to the active material for the positive electrode is in a range of 1:1 to 1:5.

9. The secondary battery of claim 1 , wherein the first solid electrolyte particles are included in an active layer for the negative electrode by being mixed with an active material for the negative electrode.

10. The secondary battery of claim 9 , wherein a mixing weight ratio of the first solid electrolyte particles to the active material for the negative electrode is in a range of 1:1 to 1:5.

11. The secondary battery of claim 1 , wherein a thickness of the solid electrolyte layer is in a range of 10 μm to 20 μm.

12. The secondary battery of claim 1 , wherein the first solid electrolyte particles are obtained by using a liquid-phase method using a lithium precursor, a lanthanum precursor, and a titanium precursor.

13. The secondary battery of claim 1 , wherein the first solid electrolyte particles have an ionic conductivity of 9.0×10 −4 S/cm to 4.0×10 −3 S/cm at room temperature, and the second solid electrolyte particles have an ionic conductivity of 1.0×10 −3 S/cm to 5.0×10 −3 S/cm at room temperature.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Su Hee
• Byun Won Bae
• Kim Dong Hwan
• Park Chee Sung

Classifications

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M2300/0071

  Oxides · CPC title