Methods for making battery electrode systems

Patent metadata

Field	Value
Publication number	US-9583767-B2
Application number	US-201213344539-A
Country	US
Kind code	B2
Filing date	Jan 5, 2012
Priority date	Jan 5, 2012
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

Methods for making battery electrode system are disclosed herein. In an example of the method, a mixture of a polymer binder, an active material and a conductive filler is deposited on a current collector. The deposited mixture is exposed to an external field having a field direction that is normal to a surface of the current collector. The exposure aligns, outward from and normal to the surface of the current collector, the active material and the conductive filler to form a plurality of discrete structures that extend outward from and normal to the surface of the current collector and are respectively aligned with a field line of the external field. Each of the plurality of discrete structures includes some of the active material and some of the conductive filler.

First claim

The invention claimed is:

1. A method for making a battery electrode system, the method comprising:
depositing a mixture of a polymer binder, active material particles and conductive filler material particles on a current collector; and
exposing the deposited mixture to an external field having a field direction that is normal to a surface of the current collector, thereby aligning, outward from and normal to the surface of the current collector, the active material particles and the conductive filler particles to form an electrode having an anisotropic morphology which includes a plurality of discrete, field aligned structures that extend outward from and normal to the surface of the current collector and are respectively aligned with a field line of the external field, wherein each of the plurality of discrete, field aligned structures includes:
some of the active material particles;
some of the polymer binder; and
some of the conductive filler particles;
wherein each of the active material particles and the conductive filler material particles is in an aligned position within the polymer binder, and the aligned position corresponds with the field line of the external field applied to form the field aligned structures;
wherein the electrode includes from about 90% to about 99% of the active material particles and the conductive filler material particles, and less than 10% of the polymer binder.

2. The method as defined in claim 1 wherein:
the exposing forms the electrode;
the polymer binder is a homopolymer;
the electrode includes from about 90% to about 99% of the active material and the conductive filler, and less than 10% of the polymer binder;
the exposing forms the plurality of discrete structures, each of which includes some of the polymer binder; and
each of the plurality of discrete, field aligned structures is physically separate from each other of the plurality of discrete, field aligned structures.

3. The method as defined in claim 1 wherein:
the polymer binder is a curable polymer;
the mixture further includes a solvent; and
the method further includes:
evaporating the solvent; and
curing the curable polymer.

4. The method as defined in claim 3 wherein the exposing occurs one of:
simultaneously with the evaporating and the curing;
prior to the evaporating and the curing; or
after the evaporating and the curing has been initiated but prior to the evaporating and the curing has been completed.

5. The method as defined in claim 1 , further comprising:
choosing a magnetic field or an electric field as the external field; and
choosing an external field strength such that i) when the magnetic field is chosen, the field strength ranges from about 1 A/m to about 10 6 A/m; or ii) when the electric field is chosen, the field strength ranges from about 10 V/m to about 10 7 V/m.

6. The method as defined in claim 1 wherein the same material is selected for the active material particles and the conductive filler particles.

7. A battery electrode system, comprising:
a current collector; and
an electrode formed on a surface of the current collector, the electrode having an anisotropic morphology which includes field aligned structures that extend outward from and normal to a surface of the current collector, each of the field aligned structures including:
active material particles;
a polymer binder; and
conductive filler material particles;
wherein each of the active material particles and the conductive filler material particles is in an aligned position within the polymer binder, and the aligned position corresponds with field lines of an external field applied to form the field aligned structures;
wherein the electrode includes from about 90% to about 99% of the active material particles and the conductive filler material particles, and less than 10% of the polymer binder.

8. The battery electrode system as defined in claim 7 wherein the field aligned structures include the polymer binder, and wherein each field aligned structure is separated from an adjacent field aligned structure via a space.

9. The battery electrode system as defined in claim 7 wherein the electrode is a cathode.

10. A battery electrode system, comprising:
a current collector; and
an electrode formed on a surface of the current collector, the electrode having an anisotropic morphology which includes field aligned structures that extend outward from and normal to a surface of the current collector, each of the field aligned structures including:
active material particles; and
conductive filler material particles;

wherein:
the electrode further includes a block copolymer;
a first polymer of the block copolymer is miscible with, and includes the active material particles and the conductive filler material particles; and
a second polymer of the block copolymer is immiscible with, and does not include the active material particles and the conductive filler material particles.

11. The battery electrode system as defined in claim 7 wherein the field aligned structures form up to 95% of the electrode.

12. A lithium ion battery, comprising:
a positive electrode, including:
a current collector; and
field aligned structures having an anisotropic morphology, that extend outward from and normal to a surface of the current collector, each of the field aligned structures including active material particles, a polymer binder, and conductive filler material particles, wherein each of the active material particles and the conductive filler material particles is in an aligned position within the polymer binder, and the aligned position corresponds with field lines of an external field applied to form the field aligned structures;
wherein the electrode includes from about 90% to about 99% of the active material particles and the conductive filler material particles, and less than 10% of the polymer binder;

a negative electrode; and
a microporous polymer separator disposed between the negative electrode and the positive electrode.

13. The battery electrode system as defined in claim 10 wherein the active material particles and the conductive filler material particles are graphite.

Assignees

• Verbrugge Mark W
• Xie Tao
• Kia Hamid G
• Gm Global Tech Operations Llc

Inventors

• Verbrugge Mark W
• Xie Tao
• Kia Hamid G

Classifications

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/04

  Processes of manufacture in general · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title