High hydroxyl TiO2-SiO2 glass

Patent metadata

Field	Value
Publication number	US-9580350-B2
Application number	US-201514921487-A
Country	US
Kind code	B2
Filing date	Oct 23, 2015
Priority date	Nov 19, 2014
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

Ultralow expansion titania-silica glass. The glass has high hydroxyl content and optionally include one or more dopants. Representative optional dopants include boron, alkali elements, alkaline earth elements or metals such as Nb, Ta, Al, Mn, Sn Cu and Sn. The glass is prepared by a process that includes steam consolidation to increase the hydroxyl content. The high hydroxyl content or combination of dopant(s) and high hydroxyl content lowers the fictive temperature of the glass to provide a glass having a very low coefficient of thermal expansion (CTE), low fictive temperature (T f ), and low expansivity slope.

First claim

What is claimed is:

1. A glass comprising:
9.0 wt % to 16.0 wt % TiO 2 ;
84.0 wt % to 91.0 wt % SiO 2 ;
900 ppm to 3000 ppm OH; and
a combined concentration of 0.1 wt % to 7.0 wt % of one or more dopants selected from the group consisting of B, Al, Li, Na, K, Mg, Ca, Nb, Ta, Mn, Cu and Sn.

2. The glass of claim 1 , wherein the glass comprises 9.5 wt % to 16.0 wt % TiO 2 and 84.0 wt % to 90.5 wt % SiO 2 .

3. The glass of claim 2 , wherein the glass comprises 1000 ppm to 2000 ppm OH.

4. The glass of claim 2 , wherein the glass comprises 1150 ppm to 1700 ppm OH.

5. The glass of claim 1 , wherein the glass has a fictive temperature of less than 825° C., a crossover temperature between 0° C. and 100° C., an expansivity slope equal to zero at a temperature between 10° C. and 95° C., and an expansivity slope at 20° C. less than 1.2 ppb/K 2 .

6. The glass of claim 1 , wherein the glass has a fictive temperature of less than 750° C., a crossover temperature between 0° C. and 80° C., an expansivity slope equal to zero at a temperature between 10° C. and 60° C., and an expansivity slope at 20° C. less than 0.7 ppb/K 2 .

7. The glass of claim 1 , wherein the glass has a fictive temperature of less than 700° C., a crossover temperature between 0° C. and 60° C., an expansivity slope equal to zero at a temperature between 10° C. and 45° C., and an expansivity slope at 20° C. less than 0.4 ppb/K 2 .

8. The glass of claim 1 , wherein the glass comprises 10.0 wt % to 15.0 wt % TiO 2 and 85.0 wt % to 90.0 wt % SiO 2 .

9. The glass of claim 8 , wherein the glass comprises 1000 ppm to 2000 ppm OH.

10. The glass of claim 8 , wherein the glass comprises 1150 ppm to 1700 ppm OH.

11. The glass of claim 8 , wherein the glass has a fictive temperature of less than 825° C., a crossover temperature between 0° C. and 100° C., an expansivity slope equal to zero at a temperature between 10° C. and 95° C., and an expansivity slope at 20° C. less than 1.2 ppb/K 2 .

12. The glass of claim 8 , wherein the glass has a fictive temperature of less than 750° C., a crossover temperature between 0° C. and 80° C., an expansivity slope equal to zero at a temperature between 10° C. and 60° C., and an expansivity slope at 20° C. less than 0.7 ppb/K 2 .

13. The glass of claim 8 , wherein the glass has a fictive temperature of less than 700° C., a crossover temperature between 0° C. and 60° C., an expansivity slope equal to zero at a temperature between 10° C. and 45° C., and an expansivity slope at 20° C. less than 0.4 ppb/K 2 .

14. The glass of claim 1 , wherein the glass comprises 11.0 wt % to 14.0 wt % TiO 2 and 86.0 wt % to 89.0 wt % SiO 2 .

15. The glass of claim 14 , wherein the glass comprises 1000 ppm to 2000 ppm OH.

16. The glass of claim 14 , wherein the glass comprises 1150 ppm to 1700 ppm OH.

17. The glass of claim 14 , wherein the glass has a fictive temperature of less than 825° C., a crossover temperature between 0° C. and 100° C., an expansivity slope equal to zero at a temperature between 10° C. and 95° C., and an expansivity slope at 20° C. less than 1.2 ppb/K 2 .

18. The glass of claim 14 , wherein the glass has a fictive temperature of less than 750° C., a crossover temperature between 0° C. and 80° C., an expansivity slope equal to zero at a temperature between 10° C. and 60° C., and an expansivity slope at 20° C. less than 0.7 ppb/K 2 .

19. The glass of claim 14 , wherein the glass has a fictive temperature of less than 700° C., a crossover temperature between 0° C. and 60° C., an expansivity slope equal to zero at a temperature between 10° C. and 45° C., and an expansivity slope at 20° C. less than 0.4 ppb/K 2 .

Assignees

• Corning Inc

Inventors

• Annamalai Sezhian
• Duran Carlos Alberto
• Hrdina Kenneth Edward

Classifications

• C03C10/0009

  containing silica as main constituent · CPC title

• C03B19/06

  by sintering, {e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction} · CPC title

• C03C2201/54

  containing beryllium, magnesium or alkaline earth metals · CPC title

• C03B2201/40

  doped with transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn · CPC title

• C03B19/1453

  Thermal after-treatment of the shaped article, e.g. dehydrating, consolidating, sintering · CPC title