Pressurized forward osmosis process and system

Patent metadata

Field	Value
Publication number	US-9580337-B2
Application number	US-201414572956-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 24, 2013
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

A pressurized forward osmotic separation process is disclosed. Generally there are two processes described. One process involves the concentration of a target solute in the first solution; the other process involves the extraction of a solvent from a first solution both by a second solution comprising of water and soluble gas or water, soluble gas, and a compound by creating an osmotic concentration gradient across the semi permeable membrane. The first solution is under pressure from an inert gas and the second solution is under pressure from a soluble gas with equal system pressures greater than 1 atmosphere. The increase or decrease of partial pressure of the soluble gas in the second solution increases or decreases the chemical potential of the second solution to achieve different solution properties. The soluble gas may be carbon dioxide and the compound may be magnesium hydroxide.

First claim

We claim:

1. A pressurized forward osmosis separation method, the method comprising:
providing a semi-permeable membrane comprising a first surface and a second surface, wherein the first semi-permeable membrane surface is opposite to the second semi-permeable membrane surface;
contacting a first solution with the first semi-permeable membrane surface, wherein the first solution comprises a first solvent and a target solute; and
contacting a second solution with the second semi-permeable membrane surface, wherein the second solution comprises a second solvent and a magnesium ion species, wherein the magnesium ion species is at least one selected from the group consisting of magnesium oxide, magnesium hydroxide and magnesium carbonate;
wherein the first and the second semi-permeable membrane surfaces are under the same system pressure, which is equal to or greater than 1 atmosphere,
wherein the first semi-permeable membrane surface is under pressure from an inert gas or air, and
wherein the second semi-permeable membrane surface is under pressure from a gas mixture comprising carbon dioxide at a partial pressure greater than 0.00035 atmosphere, under conditions wherein Mg(HCO 3 ) +1 is formed in the second solution;

whereby an osmotic concentration gradient is formed across the semi-permeable membrane, thus promoting flow of at least a portion of the first solvent from the first solution across the semi-permeable membrane to the second solution,
thereby generating a third solution in contact with the first semi-permeable membrane surface and a fourth solution in contact with the second semi-permeable membrane surface.

2. The method of claim 1 , wherein at least a portion of the fourth solution is processed to release gaseous carbon dioxide and generate a precipitate comprising magnesium carbonate.

3. The method of claim 1 , wherein the target solute is recovered from the third solution.

4. The method of claim 1 , wherein the first solution is an aqueous solution.

5. The method of claim 4 , wherein the first solution is at least one selected from the group consisting of surface water, wastewater, contaminated water, pharmaceutical solution and food grade solution.

6. The method of claim 1 , wherein the first solution contacts the first semi-permeable membrane surface and the second solution contacts the second semi-permeable membrane surface in a cross flow-filtration system.

7. The method of claim 1 , wherein the target solute is at least one selected from the group consisting of salt, sugar, enzyme, protein and microorganism.

8. The method of claim 1 , wherein the first semi-permeable membrane surface is fully immersed in the first solution, and wherein the second semi-permeable membrane surface is fully immersed in the second solution.

9. The method of claim 1 , wherein the semi-permeable membrane comprises organic materials or inorganic materials.

10. The method of claim 2 , wherein the fourth solution is further reacted with at least one selected from the group consisting of magnesium oxide and magnesium hydroxide.

11. The method of claim 1 , wherein the second solution is an aqueous solution.

12. The method of claim 9 , wherein the semi-permeable membrane comprises at least one selected from the group consisting of cellulose acetate, cellulose nitrate, polysulfone, polyvinylidene fluoride, polyamide and acrylonitrile co-polymers.

13. The method of claim 9 , wherein the semi-permeable membrane comprises at least one selected from the group consisting of mineral membrane and ceramic membrane.

14. The method of claim 1 , further wherein at least a portion of the fourth solution is subjected to heating to generate a fifth solution and gaseous carbon dioxide.

15. The method of claim 1 , further wherein at least a portion of the fourth solution is subjected to an ion exchange process to generate a sixth solution comprising magnesium chloride.

16. The method of claim 15 , further wherein the sixth solution is treated with ammonia, forming magnesium hydroxide precipitate and a seventh solution comprising ammonium chloride.

17. The method of claim 16 , further wherein the seventh solution is heated to generate gaseous hydrogen chloride and gaseous ammonia.

Assignees

• Sengupta Arup
• Creighton Robert
• Smith Ryan
• Univ Lehigh

Inventors

• Sengupta Arup
• Creighton Robert
• Smith Ryan

Classifications

• C01F5/24

  Magnesium carbonates · CPC title

• C02F2209/03

  Pressure · CPC title

• C01F5/14

  Magnesium hydroxide · CPC title

• C02F2103/007

  Contaminated open waterways, rivers, lakes or ponds · CPC title

• C02F1/44

  by dialysis, osmosis or reverse osmosis {(general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268)} · CPC title