Method for producing acetylenes and syngas

Patent metadata

Field	Value
Publication number	US-9580312-B2
Application number	US-201414758649-A
Country	US
Kind code	B2
Filing date	Jan 15, 2014
Priority date	Jan 16, 2013
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

The invention relates to a continuous method for producing acetylenes and syngas by partially oxidizing hydrocarbons with oxygen. A first feed stream ( 1 ) containing one or more hydrocarbons and a second feed stream ( 2 ) containing oxygen are —mixed in a ratio of the mass flows of the second feed stream ( 2 ) to the first feed stream ( 1 ) corresponding to an oxygen number of less than or equal to 0.31, said streams being heated separately from each other, —and fed to a combustion chamber (FR) via a burner block (BR), the partial oxidation of the hydrocarbons being carried out in said combustion chamber, —thereby obtaining a first cracked gas stream I g . The invention is characterized in that —the first cracked gas stream I g is precooled to a temperature ranging from 100 to 1000° C. in a prequench region (H), thereby obtaining a second cracked gas stream II g , —50 to 90% of the solids contained in the second cracked gas stream II g are separated therefrom in a solid-gas separating device (A), thereby obtaining a solid stream I f and a third cracked gas stream III g , —the third cracked gas stream III g is cooled to 80 to 90° C. by injecting water in a total quench region (B), thereby obtaining a fourth cracked gas stream IV g and a first process water stream I liq , —the fourth cracked gas stream IV g undergoes a fine separation of solids in one or more scrubbing devices (C, D), thereby obtaining one or more process water streams II liq , III liq and a product gas stream VI g , —the process water streams I liq , II liq , III liq are merged into a combined process water stream IV liq , —the combined process water stream IV liq is partly recirculated, as stream V liq , into the total quench region (B) and otherwise undergoes a cleaning process, as stream VI liq , by means of a partial evaporation process, thereby obtaining a cleaned process water stream VII liq , —which is cooled by a recooling device (F), partially recycled, as stream VIII liq , into the method, and otherwise discharged, as stream IX liq .

First claim

The invention claimed is:

1. A continuous process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, comprising:
separately heating in preheaters a first input stream comprising one or more hydrocarbons and a second input stream comprising oxygen,
mixing in a mixing unit the first and second input streams in a ratio of mass flow of the second to first input stream corresponding to an oxygen ratio of less than or equal to 0.31, wherein the oxygen ratio is the amount of oxygen present in the second input stream to the amount of oxygen which is needed stoichiometrically for full combustion of one or more hydrocarbons in the first input stream,
supplying said mixture of the first and second streams via a burner block to a combustion chamber configured for partial oxidation of the one or more hydrocarbons, thus obtaining a first cracking gas stream I g ;
cooling in a prequench said first cracking gas stream I g by injecting an aqueous quench medium to a temperature of 100 to 1,000° C., thus obtaining a second cracking gas stream II g ;
removing in a solid-gas separation apparatus 50 to 90% of the solids present in the second cracking gas stream II g thus obtaining a solids stream I f and a third cracking gas stream III g ,
cooling in a total quench the third cracking gas stream III g by injecting water to a temperature of 80 to 90° C. to obtain a fourth cracking gas stream IV g and a first process water stream I liq ,
scrubbing in one or more scrubbing apparatuses the fourth cracking gas stream IV g to remove solids, thus obtaining process water streams II liq , or II liq and III liq , and a product gas stream VI g ,
combining process water streams I liq , II liq , III liq thus providing a combined process water stream IV liq ,
recycling the combined process water stream IV liq partly as stream V liq into the total quench and partly as stream VI liq to cleaning by partial vaporization in a one-stage flash vessel that being vaporizes stream VI liq in a proportion of 0.01 to 10% by weight, based on the total weight thereof, to obtain a cleaned process water stream VII liq ,
cooling with a re-cooling device cleaned process water stream VII liq and partly recycling it as stream VIII liq into one or more of the one or more scrubbing apparatuses, and partly discharging the rest as stream IX liq .

2. The continuous process according to claim 1 , wherein stream IX liq is discharged at a flow rate corresponding to the water of reaction obtained in the partial oxidation of the hydrocarbons with oxygen.

3. The continuous process according to claim 1 , wherein 60 to 80% of the solids present in the second cracking gas stream II g is separated therefrom in the solid-gas separation apparatus.

4. The continuous process according to claim 1 , wherein the solids stream I f comprises tars, soots and cokes.

5. The continuous process according to claim 1 , wherein the solid-gas separation apparatus is a cyclone separator.

6. The continuous process according to claim 1 , wherein the first cracking gas stream I g is cooled in the prequench to a temperature in the range from 200 to 650° C.

7. The continuous process according to claim 6 , wherein the first cracking gas stream I g is cooled in the prequench to a temperature in the range from 250 to 400° C.

8. The continuous process according to claim 1 , wherein the prequench is a water quench.

9. The continuous process according to claim 8 , wherein the prequench comprises a heat exchanger for extracting heat of reaction in the form of high-pressure steam.

10. The continuous process according to claim 1 , wherein the one or more scrubbing apparatuses comprise a first scrubbing apparatus used is a Venturi scrubber and the second scrubbing apparatus a quench column.

11. The continuous process according to claim 1 , wherein the one or more scrubbing apparatuses comprise a first and second scrubbing apparatus, and wherein the cleaned process water substream VIII liq is supplied to the second scrubbing apparatus.

12. The continuous process according to claim 1 , wherein the re-cooling device is a closed re-cooling device.

13. The continuous process according to claim 1 , wherein the re-cooling device is an open cooling tower.

Assignees

• Basf Se

Inventors

• Vicari Maximilian
• Weichert Christian
• Grossschmidt Dirk
• Russ Michael
• Ehrhardt Kai Rainer
• Neuhauser Horst
• Hayes Michael L

Classifications

• C01B2203/148

  involving a recycle stream to the feed of the process for making hydrogen or synthesis gas · CPC title

• C01B2203/025

  containing a partial oxidation step · CPC title

• C01B2203/0877

  by direct injection of fluid · CPC title

• C01B2203/0894

  Generation of steam · CPC title

• C07C2/78

  Processes with partial combustion · CPC title