Dehydrogenation catalyst and process

Patent metadata

Field	Value
Publication number	US-9579632-B2
Application number	US-201113990440-A
Country	US
Kind code	B2
Filing date	Dec 2, 2011
Priority date	Dec 17, 2010
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

A catalyst composition comprises (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) tin or a tin compound, wherein the tin is present in an amount of 0.01 wt % to about 0.25 wt %, the wt % based upon the total weight of the catalyst composition.

First claim

The invention claimed is:

1. A process for the dehydrogenation of a ketone to an aromatic alcohol, the process comprising contacting a feed comprising a cycloaliphatic alcohol or ketone under dehydrogenation conditions with catalyst composition comprising: (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) tin or a tin compound, wherein the tin is present in an amount of 0.01 wt % to about 0.25 wt %, the wt % based upon the total weight of the catalyst composition; and further wherein said dehydrogenation conditions comprise a temperature of about 250° C. to about 500° C., a pressure of about 100 kPa to about 3550 kPa, a weight hourly space velocity of about 0.2 hr −1 to 50 hr −1 , and a hydrogen to cyclohexanone-containing feed molar ratio of about 2 to about 20.

2. The process of claim 1 , wherein said feed comprises cyclohexanone.

3. The process of claim 1 , wherein said at least one metal selected from Groups 6 to 10 of the Periodic Table of Elements comprises platinum, palladium and mixtures thereof.

4. A process for producing phenol from benzene, the process comprising:
(a) reacting benzene and hydrogen with a catalyst under hydroalkylation conditions to produce cyclohexylbenzene;
(b) oxidizing cyclohexylbenzene from (a) to produce cyclohexylbenzene hydroperoxide;
(c) converting cyclohexylbenzene hydroperoxide from (b) to produce an effluent steam comprising phenol and cyclohexanone; and
(d) contacting at least a portion of the effluent stream from (c) with a dehydrogenation catalyst comprising: (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) tin or a tin compound, wherein the tin is present in an amount of 0.01 wt % to about 0.25 wt %, the wt % based upon the total weight of the catalyst composition, wherein the contacting occurs under dehydrogenation conditions effective to convert at least part of the cyclohexanone in the effluent stream into phenol and hydrogen; and further wherein said dehydrogenation conditions comprise a temperature of about 250° C. to about 500° C., a pressure of about 100 kPa to about 3550 kPa, a weight hourly space velocity of about 0.2 hr −1 to 50 hr −1 , and a hydrogen to cyclohexanone-containing feed molar ratio of about 2 to about 20.

Assignees

• Dakka Jihad M
• Decaul Lorenzo C
• Helton Terry E
• Kuechler Keith H
• Wallace Jenna L
• Exxonmobil Chemical Patents Inc

Inventors

• Dakka Jihad M
• Decaul Lorenzo C
• Helton Terry E
• Kuechler Keith H
• Wallace Jenna L

Classifications

• C07C37/06

  by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation · CPC title

• B01J35/0066

  Operations & Transport · mapped topic

• B01J23/626 Primary

  with tin · CPC title

• C07C39/04

  Phenol · CPC title

• B01J21/08

  Silica · CPC title