Optical filter, and solid-state image pickup device and camera module using the optical filter

Patent metadata

Field	Value
Publication number	US-9575213-B2
Application number	US-201214351268-A
Country	US
Kind code	B2
Filing date	Oct 12, 2012
Priority date	Oct 14, 2011
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

The problem of the present invention is to overcome drawbacks of conventional optical filters such as near-infrared cut filters and to provide an optical filter which generates little scatted light even during light absorption and has excellent transmittance property. The optical filter of the present invention is characterized by containing a squarylium-based compound and a compound which absorbs or quenches fluorescence of the squarylium-based compound. The optical filter of the present invention preferably contains a near-infrared absorbing dye containing a squarylium compound (A) and at least one compound (B) selected from the group consisting of a phthalocyanine-based compound (B-1) and a cyanine-based compound (B-2).

First claim

The invention claimed is:

1. A near-infrared cut filter comprising:
near-infrared absorbing dye which comprises a squarylium-based compound (A) and a phthalocyanine-based compound (B-1),
wherein the absorption maximum of the squarylium-based compound (A) is present on the side of shorter wavelength than the absorption maximum of the phthalocyanine-based compound (B-1),
wherein the squarylium-based compound (A) has the absorption maximum in the wavelength region of not less than 650 nm but less than 740 nm, and the phthalocyanine-based compound (B-1) has the absorption maximum in the wavelength region of more than 670 nm but not more than 760 nm, and the difference in the absorption maximum wavelength between the squarylium-based compound (A) and the phthalocyanine-based compound (B—I) is from 10 to 60 nm, and
wherein an average transmittance of the near-infrared cut filter in a wavelength region of from 430 nm to 580 nm is at least 87%, and an average transmittance of the near-infrared cut filter in a wavelength region of from 800 nm to 1000 nm is at most 1%.

2. The near-infrared cut filter according to claim 1 , which comprises a resin substrate comprising the near-infrared absorbing dye and a resin.

3. The near-infrared cut filter according to claim 2 , wherein the content of the total near-infrared absorbing dye is 0.01 to 5.0 parts by weight based on 100 parts by weight of the resin.

4. The near-infrared cut filter according to claim 3 , wherein the resin is at least one resin selected from the group consisting of a cyclic polyolefin-based resin, an aromatic polyether-based resin, a polyimide-based resin, a fluorene polycarbonate-based resin, a fluorene polyester-based resin, a polycarbonate-based resin, a polyamide-based resin, a polyarylate-based resin, a polysulfone-based resin, a polyether sulfone-based resin, a polyparaphenylene-based resin, a polyamidoimide-based resin, a polyethylene naphthalate-based resin, a fluorinated aromatic polymer-based resin, a (modified) acrylic resin, an epoxy-based resin, an allyl ester-based curing resin and a silsesquioxane-based ultraviolet curing resin.

5. The near-infrared cut filter according to claim 1 , which further comprises at least one near-ultraviolet absorbing agent selected from the group consisting of an azomethine-based compound, an indole-based compound, a benzotriazole-based compound and a triazine-based compound.

6. The near-infrared cut filter according to claim 1 , which is for a solid-state image pickup device.

7. A solid-state image pickup device comprising the near-infrared cut filter according to claim 6 .

8. A camera module comprising the near-infrared cut filter according to claim 6 .

9. The near-infrared cut filter according to claim 1 , wherein when the amount of the total near-infrared absorbing dye is 100% by weight, the content of the squarylium-based compound (A) is 20 to 95% by weight, and the content of the phthalocyanine-based compound (B-1) is 5 to 80% by weight.

10. The near-infrared cut filter according to claim 1 , wherein the squarylium-based compound (A) is a compound represented by the following formula (I) or (II):

wherein R a , R b and Y satisfy the following condition (i) or (ii):
(i) plural R a are each independently a hydrogen atom, a halogen atom, a sulfo group, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a phosphoric acid group, -L 1 or a NR e R f group, wherein R e and R f are each independently a hydrogen atom, -L a , -L b , -L c , -L d or L e ,
plural R b are each independently a hydrogen atom, a halogen atom, a sulfo group, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a phosphoric acid group, -L 1 or a —NR g R h group, wherein R g and R h are each independently a hydrogen atom, -L a , -L b , -L c , -L d , L e or a —C(O)R i group, wherein R i is -L a , -L b , -L c , -L d or -L e ,
plural Y are each independently a —NR j R k group, wherein R j and R k are each independently a hydrogen atom, -L a , -L b , -L c , -L d , or -L e ,
L 1 is
(L a ) an aliphatic hydrocarbon group of 1 to 9 carbon atoms, which may have a substituent L,
(L b ) a halogen-substituted alkyl group of 1 to 9 carbon atoms, which may have a substituent L,
(L c ) an alicyclic hydrocarbon group of 3 to 14 carbon atoms, which may have a substituent L,
(L d ) an aromatic hydrocarbon group of 6 to 14 carbon atoms, which may have a substituent L,
(L e ) a heterocyclic group of 3 to 14 carbon atoms, which may have a substituent L,
(L 1 ) an alkoxy group of 1 to 9 carbon atoms, which may have a substituent L,
(L g ) an acyl group of 1 to 9 carbon atoms, which may have a substituent L, or
(L h ) an alkoxycarbonyl group of 1 to 9 carbon atoms, which may have a substituent L,
the substituent L is at least one kind selected from the group consisting of an aliphatic hydrocarbon group of 1 to 9 carbon atoms, a halogen-substituted alkyl group of 1 to 9 carbon atoms, an alicyclic hydrocarbon group of 3 to 14 carbon atoms, an aromatic hydrocarbon group of 6 to 14 carbon atoms and a heterocyclic group of 3 to 14 carbon atoms, and the above L a to L h may further have at least one atom or group selected from the group consisting of a halogen atom, a sulfo group, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a phosphoric acid group and an amino group;
(ii) at least one of two R a on one benzene ring and Y on the same benzene ring are bonded to each other to form a heterocyclic ring of 5 or 6 constituent atoms containing at least one nitrogen atom, and the heterocyclic ring may have a substituent, and
R b and R a which does not take part in the formation of the heterocyclic ring have the same meanings as those of R b and R a in the condition (i), respectively;

wherein X is O, S, Se, N—R c or C—R d R d ,
plural R e are each independently a hydrogen atom, -L a , -L b , -L c , -L d or -L e ,
plural R d are each independently a hydrogen atom, a halogen atom, a sulfo group, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a phosphoric acid group, -L 1 or a —NR e R f group, and neighboring R d and R d may be bonded to each other to form a ring which may have a substituent, and
L a to L e , L 1 , R e and R f have the same meanings as those of L a to L e , L 1 , R e and R f defined in the formula (I).

11. The near-infrared cut filter according to claim 10 , wherein the phthalocyanine-based compound (B-1) is a compound represented by the following formula (III):

wherein M represents two hydrogen atoms, two monovalent metal atoms, a divalent metal atom, or substituted metal atoms containing a trivalent or tetravalent metal atom,
plural R a , R b , R c and R d are each independently a hydrogen atom, a halogen atom, a hydroxyl group, a carboxyl group, a nitro group, an amino group, an amide group, an imide group, a cyano group, a silyl group, -L 1 , —S-L 2 , —SS-L 2 , —SO 2 -L 3 or —N═N-L 4 , or at least one combination of R a and R b , R b and R c , and R c and R d is bonded to form at least one group selected from the group consisting of groups represented by the following formulas (A) to (H), and at least one of R a , R b , R c and R d bonded to the same aromatic ring is not a hydrogen atom,
the amino group, the amide group, the imide group and the silyl group may have a substituent L defined

Assignees

• Jsr Corp

Inventors

• Nagaya Katsuya
• Kishida Hiroyuki
• Tsubouchi Takashi
• Nakajima Mitsuru
• Mitsuboshi Ran
• Tanaka Yukie

Classifications

• G02B5/208 Primary

  for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation · CPC title

• G02B2207/113

  Fluorescence · CPC title

• C09B57/007

  Squaraine dyes · CPC title

• C09B67/0033 Primary

  Blends of pigments; Mixtured crystals; Solid solutions · CPC title

• C09B67/0034

  Mixtures of two or more pigments or dyes of the same type · CPC title