Methods for arranging nanotube elements within nanotube fabrics and films

Patent metadata

Field	Value
Publication number	US-9574290-B2
Application number	US-94550110-A
Country	US
Kind code	B2
Filing date	Nov 12, 2010
Priority date	Jan 13, 2003
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

A method for arranging nanotube elements within nanotube fabric layers and films is disclosed. A directional force is applied over a nanotube fabric layer to render the fabric layer into an ordered network of nanotube elements. That is, a network of nanotube elements drawn together along their sidewalls and substantially oriented in a uniform direction. In some embodiments this directional force is applied by rolling a cylindrical element over the fabric layer. In other embodiments this directional force is applied by passing a rubbing material over the surface of a nanotube fabric layer. In other embodiments this directional force is applied by running a polishing material over the nanotube fabric layer for a predetermined time. Exemplary rolling, rubbing, and polishing apparatuses are also disclosed.

First claim

What is claimed is:

1. A method for arranging nanotube elements within a nanotube fabric layer, comprising:
forming a nanotube fabric layer by depositing a plurality of nanotube elements in suspension over a material layer, said nanotube fabric layer comprising a plurality of deposited nanotube elements and wherein said nanotube fabric layer is a freely formed, fixed nanotube fabric layer and at least a portion of said nanotube elements within said nanotube fabric layer are unordered; and
translating a directional force with a component normal to said nanotube fabric layer across said nanotube fabric layer to arrange at least a portion of said nanotube elements into an ordered network.

2. The method of claim 1 wherein said directional force is translated over said nanotube fabric layer at least once.

3. The method of claim 2 wherein said translation of said directional force imparts energy into said nanotube fabric layer.

4. The method of claim 3 wherein said imparted energy acts on at least one of said plurality of nanotube elements within said nanotube fabric layer to alter the orientation of said at least one of said plurality of nanotube elements.

5. The method of claim 1 wherein said directional force comprises a force applied in a plurality of directions substantially parallel to the plane of said nanotube fabric layer.

6. The method of claim 1 wherein said directional force comprises a force applied in a linear direction along a plane parallel to said nanotube fabric layer.

7. The method of claim 1 comprising repeatedly applying said directional force for a plurality of iterations across said nanotube fabric layers.

8. The method of claim 7 wherein said plurality of iterations follow substantially follow a fixed path across said nanotube fabric layer.

9. The method of claim 1 wherein said directional force comprises a rubbing force.

10. The method of claim 9 wherein said rubbing force is applied by sliding a rubbing material against the surface of said nanotube fabric layer.

11. The method of claim 10 wherein said rubbing material comprises a material selected from the group consisting of elemental silicon, polytetrafluoroethylene (PTFE), cellulose acetate, cellulose (e.g., rayon), polyesters, polyamides (e.g., nylons), polymeric materials, and a semi-slurries of starch and water.

12. The method of claim 10 wherein said nanotube fabric layer is pressed against said rubbing material as said nanotube fabric layer is slid against said rubbing material.

13. The method of claim 1 wherein said rigid material layer is selected from a group consisting of steel, aluminum, ceramic, and glass.

14. The method of claim 1 wherein said step of applying said directional force significantly reduces the roughness of at least a portion of said nanotube fabric layer.

15. The method of claim 1 wherein said step of applying said directional force significantly reduces the friction of at least a portion of said nanotube fabric layer.

16. The method of claim 1 wherein said step of applying said directional force reduces the size of gaps within at least a portion of said nanotube fabric layer.

17. The method of claim 1 wherein said directional force arranges nanotube elements within at least one preselected region of said nanotube fabric layer into a preselected orientation.

18. The method of claim 1 wherein a first directional force arranges a first region of nanotube elements into a first orientation and a second directional force arranges a second region of nanotube elements into a second orientation.

19. The method of claim 1 wherein said nanotube fabric layer is formed via one of a spin coating operation, a spray coating operation, a dip coating operation, a silk screen printing operation, or a gravure printing operation.

20. The method of claim 1 wherein said nanotube elements comprises carbon nanotubes.

21. The method of claim 1 wherein said nanotube fabric layer is a composite mixture of carbon nanotubes and other materials.

22. The method of claim 21 wherein said other materials are selected from the group consisting of buckyballs, amorphous carbon, silver nanotubes, quantum dots, colloidal silver, monodisperse polystyrene beads, and silica particles.

23. The method of claim 1 further comprising removing said material layer after said step of applying said directional force.

24. The method of claim 1 wherein said directional force is a mechanical force.

25. The method of claim 1 wherein said nanotube fabric layer is substantially free of any suspension medium.

26. The method of claim 1 wherein said directional force is applied directly to said nanotube fabric layer.

Assignees

• Roberts David A
• Lin Hao-Yu
• Bengtson Thomas R
• Rueckes Thomas
• Robinson Karl
• Manning H Montgomery
• Sen Rahul
• Monteiro Michel Pires
• Nantero Inc

Inventors

• Roberts David A
• Lin Hao-Yu
• Bengtson Thomas R
• Rueckes Thomas
• Robinson Karl
• Manning H Montgomery
• Sen Rahul
• Monteiro Michel Pires

Classifications

• D04H1/4382 Primary

  Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B05D3/12

  by mechanical means · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01B31/0253

  Chemistry & Metallurgy · mapped topic