Methods of reducing old oxides in aluminum castings

Patent metadata

Field	Value
Publication number	US-9574252-B2
Application number	US-201414174240-A
Country	US
Kind code	B2
Filing date	Feb 6, 2014
Priority date	Mar 15, 2013
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

A method of reducing entrained aluminum oxides in aluminum castings. The method comprises preheating a furnace charge to remove moisture and contaminants. The furnace charge is then coated on all free surfaces with a layer of flux. Subsequently the furnace charge is melted in a furnace to form a melt bath of liquid aluminum suitable for casting. The flux layer removes the naturally occurring oxide film from the furnace charge surface as well as provides a cover flux to protect the melt bath from oxidation.

First claim

What is claimed is:

1. A method of reducing entrained aluminum oxides in aluminum castings; the method comprising:
preheating a furnace charge of an aluminum alloy;
coating the furnace charge free surfaces with a layer of flux having approximately 30.8% by weight NaCl by dipping the furnace charge into a molten flux bath; and
melting the furnace charge in a furnace to form a melt bath with a melt surface.

2. The method of claim 1 , wherein coating the furnace charge free surfaces with a layer of flux further comprises coating the furnace charge free surface with a layer of flux at least approximately 1 mm in thickness.

3. The method of claim 1 , wherein coating the furnace charge free surfaces with a layer of flux further comprises coating the furnace charge free surface with a layer of flux approximately 1 mm to approximately 2 mm in thickness.

4. The method of claim 1 , wherein preheating a furnace charge of an aluminum alloy further comprises preheating the furnace charge to at least approximately 150° C.

5. The method of claim 4 , wherein preheating a furnace charge of an aluminum alloy further comprises providing a melting furnace and using hot flue gases of the melting furnace for preheating the furnace charge of the aluminum alloy.

6. The method of claim 4 , wherein preheating a furnace charge of an aluminum alloy further comprises providing a rotary kiln for preheating the furnace charge of the aluminum alloy.

7. The method of claim 6 , wherein providing a rotary kiln for preheating the furnace charge an aluminum alloy further comprises providing a rotary kiln having an atmosphere including an oxygen level below the flammability limits of any organic contaminants on the aluminum alloy.

8. The method of claim 7 , wherein providing a rotary kiln for preheating the furnace charge of an aluminum alloy further comprises providing a the rotary kiln having an oxygen level maintained below 6% oxygen by volume.

9. The method of claim 1 , wherein preheating a furnace charge of aluminum alloy further comprises providing a side well furnace for preheating the furnace charge.

10. The method of claim 1 , further comprising allowing the flux to float to the melt surface and form a cover flux.

11. The method of claim 1 , wherein coating the furnace charge free surfaces with a layer of flux further comprises including a layer of flux having NaCl and KCl in an equimolar ratio.

12. The method of claim 11 , wherein coating the furnace charge free surfaces with a layer of flux further comprises including a layer of flux having at least 0.5% by weight of at least one material selected from the group consisting of CaCl 2 , LiCl, MgCl 2 , MgSO 4 , Na 2 SO 4 , K 2 SO 4 .

13. The method of claim 11 , wherein coating the furnace charge free surfaces with a layer of flux further comprises including a layer of flux having 4.0-6.0% by weight CaCl 2 , 4.0-6.0% by weight LiCl, 4.0-6.0% by weight MgCl 2 , 4.0-6.0% by weight Na 2 SO 4 , 6.5-8.5% by weight K 2 SO 4 and 2.0-3.0% by weight MgSO 4 .

14. The method of claim 1 , wherein coating the furnace charge free surfaces with a layer of flux further comprises including a layer of flux having chlorides of Li, Ca, or Mg; sulfates of Na or K; or their combinations.

15. A method of reducing entrained aluminum oxides in aluminum castings, the method comprising:
preheating a furnace charge of an aluminum alloy to at least approximately 150° C.,
coating the furnace charge free surfaces with a layer of flux at least approximately 1 mm in thickness by dipping the furnace charge into a molten flux bath and wherein the layer of flux comprises 29.8-31.8% by weight NaCl, 38.2%-40.2% by weight KCl, 4.0-6.0% by weight LiCl, 4.0-6.0% by weight MgCl 2 , 4.0-6.0% by weight Na 2 SO 4 , 6.5-8.5% by weight K 2 SO 4 and 2.0-3.0% by weight MgSO 4 .

16. A method of reducing entrained aluminum oxides in aluminum castings; the method comprising:
preheating a furnace charge of an aluminum alloy to between approximately 150° C. and approximately 500° C. in a rotary kiln with an oxygen level maintained between 1% and 2% oxygen by volume,
coating the furnace charge free surfaces with a layer of flux, and to between approximately 1 mm to approximately 2 mm in thickness, and wherein the flux comprises approximately 30.8% by weight NaCl, approximately 39.2% by weight KCl, approximately 5.0% by weight CaCl 2 , approximately 5.0% by weight LiCl, approximately 5.0% by weight MgCl 2 , approximately 5.0% by weight Na 2 SO 4 , approximately 7.5% by weight K 2 SO 4 and approximately 2.5% by weight MgSO 4 ;
melting the furnace charge in a furnace to form a melt bath with a melt surface.

Assignees

• Gm Global Tech Operations Llc
• Gm Global Tech Operations Llc

Inventors

• Wang Qigui
• Gerard Dale A

Classifications

• C22B21/062

  using salt or fluxing agents (C22B21/064, C22B21/066, and C22B21/068 take precedence) · CPC title

• C22B21/02 Primary

  with reducing {(C22B21/04 takes precedence)} · CPC title