Aqueous polyacrylate copolymer dispersions with high OH group content

Patent metadata

Field	Value
Publication number	US-9574078-B2
Application number	US-201214366277-A
Country	US
Kind code	B2
Filing date	Dec 20, 2012
Priority date	Dec 22, 2011
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

The present invention relates to aqueous secondary copolymer dispersion comprising a copolymer (P) synthesized from a mixture of free-radically polymerizable monomers (M) comprising: (M1) cycloaliphatic esters of acrylic and/or methylacrylic acid; (M3) hydroxy-functional, free-radically polymerizable monomers; (M4) carboxyl-functional, free-radically polymerizable monomers and (M5) hydroxyl- and carboxyl-free (meth)acrylic esters having C1 to C12 hydrocarbon radicals in the alcohol moiety and/or vinylaromatics, wherein the mixture further comprises polyols (PO) selected from the group of polyester polyols and/or polycarbonate polyols, the polyols having an average hydroxyl group functionality of at least 2. The invention also relates to a method for the production of such a dispersion, to the use of the dispersion as a coating and as a binder in 2K polyurethane coatings.

First claim

The invention claimed is:

1. An aqueous copolymer dispersion comprising a copolymer (P) synthesized from a mixture of free-radically polymerizable monomers (M) comprising:
(M1) a cycloaliphatic ester of acrylic and/or methylacrylic acid,
(M3) a hydroxy-functional, free-radically polymerizable monomer,
(M4) a carboxyl-functional, free-radically polymerizable monomer,
(M5) a hydroxyl- and carboxyl-free (meth)acrylic ester having C1 to C12 hydrocarbon radicals in the alcohol moiety different from (M1) and/or a vinyl aromatic monomer,
wherein the mixture further comprises a polyol different from (M3) selected from the group of polyester polyol, polycarbonate polyol, and mixtures thereof, wherein the polyol has an average hydroxyl group functionality of at least 2, and wherein the polyol has a hydroxyl group content of ≧15 weight-% to ≦35 weight-%.

2. The dispersion according to claim 1 , wherein the mixture of free-radically polymerizable monomers (M) does not comprise:
(M2) vinyl esters of aliphatic carboxylic acids.

3. The dispersion according to claim 1 , wherein the copolymer (P) has a hydroxyl group content of ≧5 weight-% to ≦15 weight-%.

4. The dispersion according to claim 1 , wherein the polyol is a polyester polyol obtained from the reaction of an at least trifunctional alcohol with a lactone.

5. The dispersion according to claim 4 , wherein the polyester polyol is obtained from trimethylolpropane and ε-caprolactone.

6. The dispersion according to claim 1 , wherein the aqueous dispersion further comprises a compound comprising an element of sub-groups 5 and/or 6 of the periodic table.

7. The dispersion according to claim 1 , wherein:
(M1) is isobornyl (meth)acrylate,
(M3) is hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate and/or butanediol mono(meth)acrylate,
(M4) is (meth)acrylic acid,
(M5) is styrene, methyl (meth)acrylate and/or n-butyl (meth)acrylate.

8. The dispersion according to claim 1 , wherein the monomers (M1), (M3), (M4) and (M5) are used in the following amounts:
(M1) ≧5 weight-% to ≦25 weight-%,
(M3) ≧25 weight-% to ≦45 weight-%,
(M4) ≧1 weight-% to ≦10 weight-%,
(M5) ≧25 weight-% to ≦45 weight-%,
and the polyols (PO) in amounts of ≧5 weight-% to ≦20 weight-%,
based on the total weight of the solids in the dispersion, the amounts given adding up to ≦100 weight-%.

9. A method for producing a dispersion according to claim 1 , comprising the step of free-radically polymerizing a mixture of monomers (M) comprising:
(M1) cycloaliphatic ester of acrylic and/or methylacrylic acid,
(M3) hydroxy-functional, free-radically polymerizable monomer,
(M4) carboxyl-functional, free-radically polymerizable monomer,
(M5) hydroxyl- and carboxyl-free (meth)acrylic ester having C1 to C12 hydrocarbon radicals in the alcohol moiety different from (M1) and/or a vinyl aromatic monomer,
wherein the mixture further comprises a polyol different from (M3) selected from the group of polyester polyol, polycarbonate polyol, and mixtures thereof, wherein the polyol has an average hydroxyl group functionality of at least 2.

10. The method according to claim 9 , wherein the polyol is polyester polyol obtained from the reaction of an at least trifunctional alcohol with a lactone.

11. The method according to claim 9 , wherein:
(M1) is isobornyl (meth)acrylate,
(M3) is hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate and/or butanediol mono(meth)acrylate,
(M4) is (meth)acrylic acid, and
(M5) is styrene, methyl (meth)acrylate and/or n-butyl (meth)acrylate.

12. A method comprising utilizing the dispersion according to claim 1 as a coating material.

Assignees

• Bayer Ip Gmbh
• Covestro Deutschland Ag

Inventors

• Schrinner Marc Claudius
• Gewiss Heinz-Dietmar
• Stingl Thomas
• Melchiors Martin

Classifications

• C08F283/02 Primary

  on to polycarbonates or saturated polyesters {(C08F283/004 takes precedence)} · CPC title

• C08G18/706

  the liquid medium being water · CPC title

• C09D151/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08G18/4277

  Caprolactone and/or substituted caprolactone · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title