Processes and compositions for injection blow molding

Patent metadata

Field	Value
Publication number	US-9574064-B2
Application number	US-200913056710-A
Country	US
Kind code	B2
Filing date	Aug 28, 2009
Priority date	Aug 28, 2008
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

The invention provides a process for injection blow molding an article, said process comprising injecting into a mold cavity a composition, comprising at least one ethylene-based polymer and less than, or equal to, 1000 ppm of a mold release agent, based on the total weight of the composition. The invention also provides a composition comprising a blend, wherein the blend comprises at least one high molecular weight (HMW) ethylene-based polymer, and at least one low molecular weight (LMW) ethylene-based polymer, and wherein the blend has an unsaturation level, as determined by IR, and expressed as vinyls per 1000 carbon atoms, less than, or equal to, 0.5 vinyls per 1000 carbon atoms, and wherein the high molecular weight (HMW) ethylene-based polymer has a density from 0.925 to 0.950 g/cc.

First claim

The invention claimed is:

1. A process for injection blow molding an article, said process comprising injecting into a mold cavity a composition, comprising at least one ethylene-based polymer and less than, or equal to, 1000 ppm of a mold release agent, based on the total weight of the composition, and
wherein the composition has a molecular weight distribution (Mw/Mn) from 8 to 30, as determined by high temperature GPC, equipped with an infrared detector; and
wherein the composition has a high flow melt index (I 21 ) from 22 to 32 g/10 min; and
wherein the composition is injected around a core pin to form a pre-form, and the pre-form is inserted into the mold cavity and equilibrated at an elevated temperature; and
wherein air is blown into the inner area of the pre-form, and the mold cavity is cooled to form the article, and the article is released from the mold cavity, and
wherein the composition comprises at least one high molecular weight (HMW) ethylene-based polymer, and at least one low molecular weight (LMW) ethylene-based polymer, and
wherein the LMW ethylene-based polymer has a melt index, I 2 , from 300 g/10 min to 900 g/10 min; and
wherein both the high molecular weight (HMW) ethylene-based polymer, and the low molecular weight (LMW) ethylene-based polymer are prepared using a Ziegler/Natta catalyst.

2. The process of claim 1 , wherein the mold release agent is a zinc-containing metal soap or an amide.

3. The process of claim 1 , wherein the mold release agent is zinc stearate or erucamide.

4. The process of claim 1 , wherein the composition has a molecular weight distribution (Mw/Mn) from 10 to 25, as determined by high temperature GPC equipped with an infrared detector.

5. The process of claim 1 , wherein the composition has a density from 0.950 to 0.965 g/cc.

6. The process of claim 1 , wherein the composition has a melt index (I 2 ) from 0.1 to 3 g/10 min.

7. The process of claim 1 , wherein the HMW ethylene-based polymer has a high flow melt index, I 21 , from 0.1 g/10 min to 10 g/10 min.

8. An article comprising at least one component formed from the process of claim 1 .

9. The process of claim 1 , wherein the HMW ethylene-based polymer and the LMW ethylene-based polymer comprise greater than 95 weight percent of the total weight of the composition.

10. The process of claim 1 , wherein the composition has an I2 from 0.3 to 0.7 g/10 min.

11. A composition comprising a blend, wherein the blend comprises at least one high molecular weight (HMW) ethylene-based polymer, and at least one low molecular weight (LMW) ethylene-based polymer, and
wherein the blend has an unsaturation level, as determined by IR, and expressed as vinyls per 1000 carbon atoms, less than, or equal to, 0.5 vinyls per 1000 carbon atoms, and wherein the blend has a high flow melt index (I 21 ) from 22 to 32 g/10 min,
wherein the high molecular weight (HMW) ethylene-based polymer has a density greater than, or equal to, 0.935 g/cc, and
wherein the weight ratio of the high molecular weight component to the low molecular weight component is from 40/60 to 70/30; and
wherein the LMW ethylene-based polymer has a melt index, I 2 , greater than or equal to 300 g/10 min, and
wherein the HMW ethylene-based polymer and the LMW ethylene-based polymer comprise greater than 95 weight percent of the total weight of the composition; and
wherein both the high molecular weight (HMW) ethylene-based polymer, and the low molecular weight (LMW) ethylene-based polymer are prepared using a Ziegler/Natta catalyst.

12. The composition of claim 11 , wherein the blend has a high density fraction, as determined by ATREF, greater than, or equal to, 70 percent.

13. The composition of claim 11 , wherein the blend has a purge fraction, as determined by ATREF, less than, or equal to, 20 percent.

14. An article comprising at least one component formed from the composition of claim 11 .

15. The composition of claim 11 , wherein the composition has an I21/I2 ratio from 70 to 100.

16. The composition of claim 15 , wherein the composition has a high flow melt index (I 21 ) less than, or equal to, 30.

17. The composition of claim 16 , wherein the composition has a I21/I2 from 75 to 95.

18. An injection blow molded article comprising at least one component formed from the composition of claim 17 , and wherein the article has an ESCR (100% IGEPAL), F50 value greater than 1000 hours, and a water vapor transmission rate less than 0.7 g-mil/100 in 2 ×day.

19. The injection blow molded article of claim 18 , wherein the article is a small sized container of 16 oz. or less.

20. The composition of claim 11 , wherein the composition has an I2 from 0.3 to 0.7 g/10 min.

Assignees

• Kapur Mridula
• Radwanski Alan T
• Dow Global Technologies Llc

Inventors

• Kapur Mridula
• Radwanski Alan T

Classifications

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• B29L2031/712

  Containers; Packaging elements or accessories, Packages (closures therefor B29L2031/56; ink or toner cartridges B29L2031/7678; squeeze tubes B29L2023/20; suitcases B29L2031/7418) · CPC title

• B29C49/06

  Injection blow-moulding · CPC title

• B29C37/0067

  Using separating agents during or after moulding; Applying separating agents on preforms or articles, e.g. to prevent sticking to each other (separating agents B29C33/60) · CPC title