Sealing material sheet for solar cell modules

Patent metadata

Field	Value
Publication number	US-9570642-B2
Application number	US-201214362695-A
Country	US
Kind code	B2
Filing date	Dec 3, 2012
Priority date	Dec 5, 2011
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Provided is a sealing material sheet for solar cell modules, which is obtained by irradiating a polyethylene resin with ionizing radiation and has high transparency, heat resistance and adhesion at the same time. This sealing material sheet for solar cell modules contains a low density polyethylene having a density of 0.900 g/cm 3 or less, while having a gel fraction of from 0% to 40% (inclusive) and a degree of dispersity (Mw/Mn), which is the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn) in terms of polystyrene, of from 2.5 to 3.5 (inclusive).

First claim

The invention claimed is:

1. A sealing material sheet for a solar cell module, comprising a low density polyethylene having a density of 0.900 g/cm 3 or less in an amount of 90 parts by mass or more relative to 100 parts by mass of total resin components in the sealing material composition, wherein
a gel fraction is 0% or more to 10% or less, and
a degree of dispersity (Mw/Mn) being a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) in terms of polystyrene is 2.5 or more to 3.5 or less.

2. The sealing material sheet for a solar cell module according to claim 1 , wherein the number average molecular weight is 80000 g/mol or more to 120000 g/mol or less, and
the weight average molecular weight is 220000 g/mol or more to 300000 g/mol or less.

3. The sealing material sheet for a solar cell module according to claim 1 , wherein the gel fraction is 0% or more to less than 10%.

4. The sealing material sheet for a solar cell module according to claim 1 , wherein the gel fraction is 0% or more to less than 1%.

5. The sealing material sheet for a solar cell module according to claim 1 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

6. The sealing material sheet for a solar cell module according to claim 1 , wherein a haze value at a thickness of 400 μm is 4% or less.

7. A solar cell module, comprising the sealing material sheet according to claim 1 .

8. A method for producing a sealing material sheet for a solar cell module, wherein
a gel fraction of the sealing material sheet is 0% or more to 40% or less, and
a degree of dispersity (Mw/Mn) being a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) in terms of polystyrene of the sealing material sheet is 2.5 or more to 3.5 or less, and
wherein a sealing material composition containing a low density polyethylene having a density of 0.900 g/cm 3 or less, and a cross-linking agent in an amount of 0.01 percent by mass or more to less than 0.5 percent by mass in the composition is melt formed, and then irradiation with ionizing radiation onto the sealing material composition is performed.

9. The method for producing the sealing material sheet for a solar cell module according to claim 8 , wherein a difference determined by subtracting a degree of dispersity obtained before the irradiation with ionizing radiation from a degree of dispersity obtained after the irradiation with ionizing radiation is +0.3 or more to +1.0 or less.

10. The method for producing the sealing material sheet for a solar cell module according to claim 9 , wherein the number average molecular weight before the irradiation with ionizing radiation is 80000 g/mol or more to 120000 g/mol or less, and
the weight average molecular weight before the irradiation with ionizing radiation is 150000 g/mol or more to 250000 g/mol or less.

11. The sealing material sheet for a solar cell module according to claim 2 , wherein the gel fraction is 0% or more to less than 10%.

12. The sealing material sheet for a solar cell module according to claim 2 , wherein the gel fraction is 0% or more to less than 1%.

13. The sealing material sheet for a solar cell module according to claim 2 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

14. The sealing material sheet for a solar cell module according to claim 3 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

15. The sealing material sheet for a solar cell module according to claim 4 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

16. The sealing material sheet for a solar cell module according to claim 2 , wherein a haze value at a thickness of 400 μm is 4% or less.

17. The sealing material sheet for a solar cell module according to claim 1 , wherein the gel fraction is 0%.

18. The sealing material sheet for a solar cell module according to claim 2 , wherein the gel fraction is 0%.

19. The sealing material sheet for a solar cell module according to claim 17 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

20. The sealing material sheet for a solar cell module according to claim 18 , wherein a complex viscosity at 150° C. is 85000 Pa·S or more to 180000 Pa·S or less.

Assignees

• Dainippon Printing Co Ltd

Inventors

• Matsui Hideki
• Saeki Kosuke
• Shirahige Yasushi
• Akazawa Noritoshi
• Yoshihara Toshio

Classifications

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• C08L2207/06

  Properties of polyethylene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2312/08

  by silane · CPC title

• C09D123/0815

  Copolymers of ethene with aliphatic 1-olefins · CPC title