Processes for the separation of ores

Patent metadata

Field	Value
Publication number	US-9567655-B2
Application number	US-201314056498-A
Country	US
Kind code	B2
Filing date	Oct 17, 2013
Priority date	Oct 22, 2012
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Methods for purifying one or more value materials are provided. The method can include contacting an aqueous mixture comprising a value material and a contaminant with a dispersant and a depressant to produce a treated mixture. A weight ratio of the dispersant to the depressant can be from about 1:1 to about 30:1. The method can also include recovering a purified product comprising the value material from the treated mixture. The purified product can have a reduced concentration of the contaminant relative to the aqueous slurry.

First claim

What is claimed is:

1. A method for purifying a value material, comprising:
contacting an aqueous mixture comprising a phosphorus containing ore and a contaminant comprising sand, clay, or a mixture thereof with a dispersant and a depressant to produce a treated mixture, wherein:
an amount of the dispersant in the treated mixture is from about 1.5 kg/tonne of solids in the treated mixture to about 15 kg/tonne of solids in the treated mixture,
a weight ratio of the dispersant to the depressant is from about 1:1 to about 30:1,
the dispersant comprises a silicate, and
the depressant comprises a cationic guanidine-aldehyde polymer; and

recovering a purified phosphorous containing ore product from the treated mixture, wherein the purified phosphorous containing ore product has a reduced concentration of the contaminant relative to the aqueous slurry.

2. The method of claim 1 , wherein the weight ratio of the dispersant to the depressant is from about 9:1 to about 15:1.

3. The method of claim 1 , wherein the amount of the dispersant in the treated mixture is from about 2 kg/tonne of solids in the treated mixture to about 6 kg/tonne of solids in the treated mixture.

4. The method of claim 1 , wherein the phosphorus containing ore comprises triphylite, monazite, hinsdalite, pyromorphite, vanadinite, erythrite, amblygonite, lazulite, wavellite, turquoise, autunite, carnotite, phosphophyllite, struvite, one or more apatites, one or more mitridatites, or any mixture thereof.

5. The method of claim 1 , wherein the contaminant comprises clay.

6. The method of claim 1 , wherein:
the weight ratio of the dispersant to the depressant is from about 10:1 to about 15:1,
the dispersant comprises sodium silicate, and
the cationic guanidine-aldehyde polymer comprises a cationic guanidine-formaldehyde polymer.

7. The method of claim 1 , wherein:
the cationic guanidine-aldehyde polymer comprises a cationic guanidine-formaldehyde polymer,
the dispersant comprises sodium silicate,
the weight ratio of the dispersant to the depressant is from about 9:1 to about 15:1,
a pH of the treated mixture is about 10 to about 12, and
the amount of the dispersant in the treated mixture is from about 2 kg/tonne of solids in the treated mixture to about 6 kg/tonne of solids in the treated mixture.

8. The method of claim 7 , wherein:
the dispersant is added to the aqueous mixture to produce a first mixture,
the depressant is added to the first mixture to produce the treated mixture, and
the first mixture is agitated for about 30 seconds to about 24 hours prior to adding the depressant.

9. The method of claim 1 , further comprising passing air through the treated mixture, wherein a relatively hydrophobic fraction floats to the surface and a relatively hydrophilic fraction sinks to the bottom.

10. The method of claim 9 , wherein the purified phosphorus containing ore product is recovered in the hydrophobic fraction.

11. The method of claim 1 , further comprising treating the aqueous slurry with a collector to produce the treated mixture, wherein the collector comprises fatty acids, an amine, a xanthate, a fuel oil, a fatty acid soap, a nonionic surfactant, an alkyl dithiophosphate, an alkyl thiophosphate, a fatty hydroxamate, an alkyl sulfonate, an alkyl sulfate, an alkyl phosphonate, an alkyl phosphate, an alkyl ether amine, an alkylether diamine, an alkyl amido amine, or any mixture thereof.

12. The method of claim 1 , wherein the amount of the dispersant in the treated mixture is from about 3 kg per tonne of solids in the treated mixture to about 6 kg per tonne of solids in the treated mixture, and wherein the dispersant comprises sodium silicate.

13. The method of claim 1 , wherein the guanidine-aldehyde polymer is produced by reacting a monomer mixture comprising formaldehyde and a guanidine salt, and wherein the guanidine salt comprises guanidine carbonate, guanidine chloride, guanidine nitrate, or any mixture thereof.

14. A method for purifying a value material, comprising:
combining a dispersant and a depressant with an aqueous mixture comprising a phosphorus containing ore and a contaminant comprising sand, clay, or a mixture thereof to produce a treated mixture, wherein:
an amount of the dispersant in the treated mixture is from about 1.5 kg/tonne of solids in the treated mixture to about 7 kg/tonne of solids in the treated mixture,
a weight ratio of the dispersant to the depressant is from about 1:1 to about 20:1,
the dispersant comprises sodium silicate,
the depressant comprises a cationic guanidine-formaldehyde polymer, and
a pH of the treated mixture is about 10 to about 12; and

passing air through the treated mixture, wherein a relatively hydrophobic fraction floats to the surface and a relatively hydrophilic fraction sinks to the bottom; and
recovering a purified phosphorus containing ore product from the relatively hydrophobic fraction, wherein the purified phosphorus containing ore product has a reduced concentration of the contaminant relative to the aqueous slurry.

15. The method of claim 14 , wherein the cationic guanidine-formaldehyde polymer is produced by reacting a monomer mixture comprising formaldehyde and a guanidine salt, and wherein the guanidine salt comprises guanidine carbonate, guanidine chloride, guanidine nitrate, or any mixture thereof.

16. The method of claim 14 , wherein the contaminant comprises clay.

17. The method of claim 14 , wherein the weight ratio of the dispersant to the depressant is from about 9:1 to about 15:1.

18. The method of claim 17 , wherein the phosphorus containing ore comprises triphylite, monazite, hinsdalite, pyromorphite, vanadinite, erythrite, amblygonite, lazulite, wavellite, turquoise, autunite, carnotite, phosphophyllite, struvite, one or more apatites, one or more mitridatites, or any mixture thereof.

19. A method for purifying a value material, comprising:
adding sodium silicate to an aqueous mixture comprising a phosphorus containing ore and a contaminant comprising sand, clay, or a mixture thereof to produce a first mixture;
adding a cationic guanidine-formaldehyde polymer to the first mixture to produce a treated mixture, wherein:
the first mixture is agitated for about 30 seconds to about 24 hours prior to adding the cationic guanidine-formaldehyde polymer,
an amount of the sodium silicate in the treated mixture is from about 1.5 kg/tonne of solids in the treated mixture to about 7 kg/tonne of solids in the treated mixture,
a weight ratio of the sodium silicate to the cationic guanidine-formaldehyde polymer is from about 10:1 to about 20:1, and
a pH of the treated mixture is about 10 to about 12;

passing air through the treated mixture, wherein a relatively hydrophobic fraction floats to the surface and a relatively hydrophilic fraction sinks to the bottom; and
recovering a purified phosphorus containing ore product from the relatively hydrophobic fraction, wherein the purified phosphorus containing ore product has a reduced concentration of the contaminant relative to the aqueous slurry.

20. The method of claim 19 , wherein the weight ratio of the sodium silicate to the cationic guanidine-formaldehyde polymer is from about 10:1 to about 15:1, and wherein the amount of the sodium silicate in the treated mixture is from about 1.5 kg/tonne of solids in the treated mixture to about 5 kg/tonne of solids in the treated mixture.

Assignees

• Georgia Pacific Chemicals Llc

Inventors

• Kerns Michael S
• Dopico Pablo G
• Hines John B

Classifications

• B03D1/018

  Mixtures of inorganic and organic compounds · CPC title

• B03D1/016

  Macromolecular compounds · CPC title

• B03D2203/02

  Ores · CPC title

• B03D2201/06

  Depressants · CPC title

• B03D1/021

  for treatment of phosphate ores · CPC title