Two-stage anaerobic digestion systems wherein one of the stages comprises a two-phase system

Patent metadata

Field	Value
Publication number	US-9567611-B2
Application number	US-201414522075-A
Country	US
Kind code	B2
Filing date	Oct 23, 2014
Priority date	Nov 22, 2011
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Low cost, efficient two-stage anaerobic digestion systems for the production of biogas (e.g. methane) are provided. During the first stage, biogas is produced in a first reactor by anaerobic microbes cultured in two phases: a high solids phase and a low solids phase. During the second stage, biogas is produced in a second reactor by a methanogen-rich anaerobic culture cultured in low solids medium. Removal of effluent comprising pH lowering reaction products assists in maintaining a suitable pH in the high solids phase. The transfer of effluent from the second reactor to the first reactor assists in maintaining a suitable pH in the high solids phase, in mixing of the high solids phase, and in reseeding the high solids phase with methanogens. Methane is produced in and recovered from both reactors.

First claim

The invention claimed is:

1. A method of producing biogas, comprising the steps of
i) in a first reactor, culturing at least one anaerobic microbial consortium in a high solids medium comprising 10 to 20% solids and having a pH in the range of from 6.0 to 7.5, for a period of time sufficient to produce biogas containing methane and to form a high solids phase and a low solids phase within said first reactor, wherein
a) said high solids phase is positioned within a top portion of said first reactor and floats directly on said low solids phase, and wherein oxygen tolerant microorganisms within said high solids phase hydrolyze and produce VFAs from biodegradable solids, and
b) said low solids phase is positioned beneath said high solids phase within a bottom portion of said first reactor, wherein microbial populations within said low solids phase perform anaerobic processes that produce biogases;
and wherein said high solids phase and said low solids phase are in direct contact with each other;
ii) culturing, in a second reactor, at least one methanogen-rich anaerobic culture in a low solids medium comprising at most 1% solids and having a pH in the range of from 6.5 to 8.5, for a period of time sufficient to generate methane;
iii) during one or both of step i) of culturing and step ii) of culturing, removing effluent containing volatile fatty acids (VFAs) from said low solids phase in said first reactor at a rate that is sufficient to at least partially offset a decrease in pH within said high solids phase;
iv) transferring effluent removed from said low solids phase in said first reactor to said second reactor;
v) removing effluent from said low solids medium in said second reactor;
vi) transferring effluent removed from said second reactor to said first reactor at a rate that is sufficient to at least partially offset said decrease in pH within said high solids phase; and
vii) recovering biogas produced in at least one of said first and second reactors.

2. The method of claim 1 , further comprising a step of processing, in a buffer tank, said effluent removed from said first reactor prior to said step iv) of transferring.

3. The method of claim 2 , wherein said step of processing includes adjusting a pH of said effluent by alkalinization.

4. The method of claim 1 , wherein said effluent transferred from said low solids medium in said second reactor to said first reactor comprises anaerobic seeds.

5. The method of claim 4 , wherein said anaerobic seeds include methanogenic seeds.

6. The method of claim 1 , wherein said high solids medium comprises organic municipal solid waste.

7. The method of claim 1 , wherein said steps of i) culturing and ii) culturing are performed simultaneously.

8. The method of claim 1 , further comprising a step of transferring H 2 and CO 2 produced in said first reactor to said second reactor.

9. The method of claim 1 , wherein said biogas recovered in said recovering step includes methane.

10. The method of claim 1 , further comprising the step of i) recovering nutrients from said effluent removed from said second reactor prior to said step vi) of transferring.

11. The method of claim 1 , further comprising the steps of
i) transferring effluent from said first reactor and/or said second reactor to a buffer tank;
ii) recovering nutrients from said effluent transferred to said buffer tank; and
iii) transferring nutrient depleted effluent from said buffer tank to said first reactor.

12. The method of claim 1 , further comprising a step of mixing said high solids phase.

13. The method of claim 12 , wherein said step of mixing is performed by one or more of: i) mechanical mixing; ii) introducing effluent from said second reactor into said top portion of said first reactor; and iii) upward movement of biogas.

14. The method of claim 1 wherein said vi) transferring step transfers anaerobic seeds from said second reactor to said first reactor.

15. The method of claim 14 , wherein said anaerobic seeds include methanogenic seeds.

16. The method of claim 1 wherein said iv) transferring step transfers effluent from a low solids phase positioned within a bottom portion of said first reactor to said second reactor.

17. The method of claim 1 , wherein said high solids phase comprises from about 15 to about 50% solids.

18. The method of claim 1 , wherein said low solids phase comprises from about 0 to about 5% solids.

19. The method of claim 1 , wherein an oxygen concentration of said high solids phase is higher than an oxygen concentration of said low solids phase.

20. The method of claim 13 , wherein said mechanical mixing is intermittent.

Assignees

• Univ Washington State

Inventors

• Yu Liang
• Ma Jingwei
• Frear Craig
• Zaher Usama
• Chen Shulin

Classifications

• C12M21/04

  for producing gas, e.g. biogas (digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10) · CPC title

• Y02E50/343

  Cross-Sectional Technologies · mapped topic

• C12M29/18

  External loop; Means for reintroduction of fermented biomass or liquid percolate (loop type reactors for chemical or physical processes B01J19/2435) · CPC title

• C12P5/023 Primary

  Methane · CPC title

• C12M23/58

  Reaction vessels connected in series or in parallel (combinations of bioreactors with other apparatus, C12M43/00) · CPC title