Blue phase liquid crystal composite material and liquid crystal display comprising the same

Patent metadata

Field	Value
Publication number	US-9567523-B2
Application number	US-201314355248-A
Country	US
Kind code	B2
Filing date	Nov 15, 2013
Priority date	May 31, 2013
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

A blue phase liquid crystal composite material and a liquid crystal display comprising the same, can solve the problem of small Kerr constant of the current blue phase liquid crystal and the liquid crystal display comprising the same. The blue phase liquid crystal composite material of the present disclosure is produced by the photo polymerization of the components comprising: a parent blue phase liquid crystal, a benzyne compound, a chiral compound, a photo-polymerizable monomer, and a photoinitiator. The blue phase liquid crystal composite material of the present disclosure has the advantages of large Kerr constant, low voltage, high contrast, rapid response to electric field, good stability, and the like.

First claim

The invention claimed is:

1. A blue phase liquid crystal composite material, comprising 55.0 wt %-84.9 wt % of a parent blue phase liquid crystal, 5.0 wt %-30.0 wt % of a benzyne compound, 5.0 wt %-30.0 wt % of a chiral compound, 5.0 wt %-30.0 wt % of a photo-polymerizable monomer, and 0.1 wt %-2.0 wt % of a photoinitiator,
wherein the benzyne compound has the structural of formula below:

wherein R 1 is any one of alkylphenyl, alkoxyphenyl, alkylbiphenyl, alkoxybiphenyl, alkylphenylethynyl, alkoxyphenylethynyl, alkylnaphthyl, or alkoxynaphthyl;
R 2 is hydrogen or fluoro;
R 3 is hydrogen or fluoro; and
R 4 is any one of cyano, thiocyano, trifluoromethyl, p-cyanophenyl, p-thiocyanophenyl, or p-trifluoromethylphenyl,
wherein the blue phase liquid crystal composite material having a Kerr constant up to an order of magnitude of 10 −10 mV 2 and a voltage as low as 34V.

2. The blue phase liquid crystal composite material according to claim 1 , wherein R 1 has the structure of formula selected from the group consisting of:

wherein n is an integer between 1-20.

3. The blue phase liquid crystal composite material according to claim 1 , wherein R 4 has the structure of formula selected from the group consisting of:

wherein X and Y are independently selected from a hydrogen atom or a fluorine atom.

4. The blue phase liquid crystal composite material according to claim 1 , wherein the chiral compound is an isosorbitol compound or a mannitol chiral compound.

5. The blue phase liquid crystal composite material according to claim 4 , wherein the isosorbitol compound or the mannitol chiral compound has the structure of formula selected from the group consisting of:

wherein R is alkyl having from 1 to 10 carbon atoms.

6. The blue phase liquid crystal composite material according to claim 1 , wherein the photo-polymerizable monomer is one or more of 12HMA, TMPTMA, C6M, and C3M, wherein 12HMA, TMPTMA, C6M, and C3M have the structure of formula below:

7. The blue phase liquid crystal composite material according to claim 1 , wherein the photoinitiator is an ultraviolet photoinitiator 2,2-Dimethoxy-2-phenylacetophenone having the structural of formula below:

8. A liquid crystal display comprising the blue phase liquid crystal composite material according to claim 1 .

Assignees

• Boe Technology Group Co Ltd

Inventors

• Yang Huai
• Li Birong
• He Wanli
• Wang Ling

Classifications

• C09K19/0275 Primary

  Blue phase · CPC title

• C09K19/52

  characterised by components which are not liquid crystals, e.g. additives {with special physical aspect: solvents, solid particles} · CPC title

• C09K19/588

  Heterocyclic compounds · CPC title

• C09K2019/0448

  the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate · CPC title

• C09K19/542

  Macromolecular compounds · CPC title