Crosslinking resin for sand consolidation operations

Patent metadata

Field	Value
Publication number	US-9567511-B2
Application number	US-201414771415-A
Country	US
Kind code	B2
Filing date	Nov 19, 2014
Priority date	Nov 19, 2014
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Methods including introducing a treatment fluid comprising a solvent-base fluid and a consolidation composition into a wellbore in a subterranean formation, the consolidation comprising, a crosslinking diverting agent, a hardening agent, and a multi-functional epoxy resin, the multi-functional epoxy resin comprising at least three epoxy groups; coating a face of the subterranean formation with the consolidation composition; and at least partially curing the consolidation composition in the wellbore, to reduce production of unconsolidated particulates from the subterranean formation into the wellbore.

First claim

The invention claimed is:

1. A method comprising:
introducing a treatment fluid comprising a solvent-base fluid and a consolidation composition into a wellbore in a subterranean formation, the consolidation comprising a multi-functional epoxy resin, a crosslinking diverting agent, and a hardening agent,
the multi-functional epoxy resin comprising at least three epoxy groups;

coating a face of the subterranean formation with the consolidation composition; and
at least partially curing the consolidation composition in the wellbore, to reduce production of unconsolidated particulates from the subterranean formation into the wellbore.

2. The method of claim 1 , wherein the multi-functional epoxy resin is present in an amount in the range of about 0.5% to about 40% by volume of the consolidation composition.

3. The method of claim 1 , wherein the at least three epoxy groups are glycidyl ether groups selected from the group consisting of an aliphatic glycidyl ether, a cycloaliphatic glycidyl ether, an aromatic glycidyl ether, a polyglycidyl ether, and any combination thereof.

4. The method of claim 1 , wherein the multi-functional epoxy resin is selected from the group consisting of glycerol triglycidyl ether; triphenylolmethane triglycidyl ether; 1,1,1-tris(4-hydroxyphenyl)ethane triglycidyl ether; triglycidyl-p-aminophenol; trimethylolpropane triglycidyl ether; 1,3,5-triglycidyl-isocyanurate; (R,R,R)-triglycidyl isocyanurate; isocyanuric acid (S,S,S)-triglycidyl ester; glycerol propoxylate triglycidyl ether; N,N-diglycidyl-4-glycidyloxyaniline; 2,4,6-tris(oxiranylmethoxy)-1,3,5-triazine; triglycidyl-m-aminophenol; triglycidyl-4-amino-m-cresol; triglycidyl-5-amino-o-cresol; pentaerythritol tetraglycidyl ether; 4-(3,3-dihydroxy-2,4,4-trimethyl-2H-1-benzopyran-2-yl)-1,3-benzenediol glycidyl; tris(4-hydroxyphenyl)methane triglycidyl ether; N,N-diglycidyl-2-chloro-4-[2-chloro-N-glycidyl aniline methyl]aniline; tetrafunctional o-glycidyl resin; tetraglycidyl-4,4′-methylenediamine; tetraglycidyl-4,4′-dimethyldianiline; N,N,N,N′-tetraglycidyl-m-xylenediamine; tetraglycidylmethylenedianiline; and any combination thereof.

5. The method of claim 1 , wherein the at least three epoxy groups are disposed symmetrically or asymmetrically in the multi-functional epoxy resin.

6. The method of claim 1 , wherein the crosslinking diverting agent is present in an amount in the range of about 0.1% to about 25% by volume of the consolidation composition.

7. The method of claim 1 , wherein the crosslinking diverting agent is a long-chain amine having a chain length in the range of about 8 to about 90 carbon atoms and having at least one primary amine group.

8. The method of claim 7 , wherein the crosslinking diverting agent is selected from the group consisting of a cocoamine, a cocodiamine, phenalkamine, a dimer amine, a dimer diamine, and any combination thereof.

9. The method of claim 1 , wherein the crosslinking diverting agent is a polymeric amine.

10. The method of claim 1 , wherein the hardening agent is present in an amount in the range of about 1% to about 75% by volume of the consolidation composition.

11. The method of claim 1 , wherein the hardening agent is selected from the group consisting of a cyclo-aliphatic amine, an aromatic amine, an aliphatic amine, an imidazole, a pyrazole, a 1H-indazole, a purine, an indazole, an amine, a polyamine, a polyimine, an amide, a polyamide, a 2-ethyl-4-methyl imidazole, and any combination thereof.

12. The method of claim 1 , wherein the consolidation composition is present in the treatment fluid in an amount in the range of about 5% to about 99.9% by volume of the treatment fluid.

13. The method of claim 1 , wherein the subterranean formation has a temperature of in the range of about 20° C. to about 175° C.

14. The method of claim 1 , further comprising a tubular extending into the wellbore and a pump fluidly coupled to the tubular, wherein the treatment fluid is introduced into the wellbore through the tubular.

15. A method comprising:
introducing a treatment fluid comprising a solvent-base fluid and a consolidation composition into a wellbore in a subterranean formation,
the wellbore having a length of greater than about 30 meters and exhibiting variable permeability,
the consolidation comprising a multi-functional epoxy resin, a crosslinking diverting agent, and a hardening agent, and
the multi-functional epoxy resin comprising at least three epoxy groups;

coating a face of the subterranean formation with the consolidation composition; and
at least partially curing the consolidation composition in the wellbore, thereby reducing production of unconsolidated particulates from the subterranean formation into the wellbore.

16. The method of claim 15 , wherein the at least three epoxy groups are glycidyl ether groups selected from the group consisting of an aliphatic glycidyl ether, a cycloaliphatic glycidyl ether, an aromatic glycidyl ether, a polyglycidyl ether, and any combination thereof.

17. The method of claim 15 , wherein the multi-functional epoxy resin is selected from the group consisting of glycerol triglycidyl ether; triphenylolmethane triglycidyl ether; 1,1,1-tris(4-hydroxyphenyl)ethane triglycidyl ether; triglycidyl-p-aminophenol; trimethylolpropane triglycidyl ether; 1,3,5-triglycidyl-isocyanurate; (R,R,R)-triglycidyl isocyanurate; isocyanuric acid (S,S,S)-triglycidyl ester; glycerol propoxylate triglycidyl ether; N,N-diglycidyl-4-glycidyloxyaniline; 2,4,6-tris(oxiranylmethoxy)-1,3,5-triazine; triglycidyl-m-aminophenol; triglycidyl-4-amino-m-cresol; triglycidyl-5-amino-o-cresol; pentaerythritol tetraglycidyl ether; 4-(3,3-dihydroxy-2,4,4-trimethyl-2H-1-benzopyran- 2 -yl)-1,3-benzenediol glycidyl; tris(4-hydroxyphenyl)methane triglycidyl ether; N,N-diglycidyl-2-chloro-4-[2-chloro-N-glycidyl aniline methyl]aniline; tetrafunctional o-glycidyl resin; tetraglycidyl-4,4′-methylenediamine; tetraglycidyl-4,4′-dimethyldianiline; N,N,N,N′-tetraglycidyl-m-xylenediamine; tetraglycidylmethylenedianiline; and any combination thereof.

18. The method of claim 15 , wherein the crosslinking diverting agent is selected from the group consisting of a long-chain amine having in the range of about 8 to about 90 carbon atoms and having at least one primary amine group, a polymeric amine, and any combination thereof.

19. The method of claim 15 , further comprising a tubular extending into the wellbore and a pump fluidly coupled to the tubular, wherein the treatment fluid is introduced into the wellbore through the tubular.

20. A consolidation composition comprising:
a multi-functional epoxy resin comprising at least three epoxy groups,
the multi-functional epoxy resin being present in an amount in the range of about 0.5% to about 40% by volume of the consolidation composition;

a crosslinking diverting agent selected from the group consisting of a long-chain amine having in the range of about 8 to about 90 carbon atoms and having at least one primary amine group, a polymeric amine, and any combination thereof,
the crosslinking diverting agent being present in an amount in the range of about 0.1% to about 25% by volume of the consolidation composition; and

a hardening agent selected from the group consisting of a cyclo-aliphatic amine, an aromatic amine, an aliphatic amine, an imidazole, a pyrazole, a 1H-indazole, a purine, an indazole, an amine, a polyamine, a polyimine, an amide, a polyamide, a 2-ethyl-4-methyl imidazole, and any combination thereof,
wherein the hardening agent is present in an am

Assignees

• Halliburton Energy Services Inc

Inventors

• Wadekar Sushant Dattaram
• Agashe Snehalata Sachin
• Kshirsagar Ranjeet Gangadhar

Classifications

• C08G59/32

  Epoxy compounds containing three or more epoxy groups · CPC title

• C09K8/56

  Compositions for consolidating loose sand or the like around wells without excessively decreasing the permeability thereof (compositions for plastering borehole walls C09K8/50; {Soil-conditioning materials or soil-stabilising materials in general C09K17/00}) · CPC title

• C09K8/565 Primary

  Oil-based compositions · CPC title

• E21B33/138

  Plastering the borehole wall; Injecting into the formation · CPC title

• C09K8/5751

  Macromolecular compounds (C09K8/5756 takes precedence) · CPC title