Silicone pressure-sensitive adhesive composition having improved substrate adhesion and pressure-sensitive adhesive article

Patent metadata

Field	Value
Publication number	US-9567501-B2
Application number	US-201514619358-A
Country	US
Kind code	B2
Filing date	Feb 11, 2015
Priority date	Feb 27, 2014
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

A silicone pressure-sensitive adhesive composition is provided comprising (A) an organopolysiloxane having at least two alkenyl-containing organic groups, (B) a polyorganosiloxane comprising R 2 3 SiO 1/2 and SiO 4/2 units in a molar ratio of 0.5 to 1.0, (C) a polyorganohydrogensiloxane containing at least three Si—H groups, (D) a platinum group metal base catalyst, and (E) an adhesion promoting compound containing at least one recurring unit of formula (3) and at least one Si—H group.

First claim

The invention claimed is:

1. A silicone pressure-sensitive adhesive composition, comprising:
(A) 100 to 40 parts by weight of an organopolysiloxane represented by the average compositional formula (1) and having at least two alkenyl-containing organic groups per molecule,

wherein R 1 is each independently a C 1 -C 10 monovalent hydrocarbon group, at least two of R 1 containing a C 2 -C 10 alkenyl-containing organic group, a is an integer of at least 2, b is an integer of at least 1, c is an integer of at least 0, d is an integer of at least 0, and 50≦a+b+c+d≦15,000;
(B) 60 to 0 parts by weight of a polyorganosiloxane comprising R 2 3 SiO 1/2 units and SiO 4/2 units wherein R 2 is each independently a C 1 -C 10 monovalent hydrocarbon group free of aliphatic unsaturation or a C 2 -C 6 alkenyl group, in a molar ratio R 2 3 SiO 1/2 /SiO 4/2 of 0.5 to 1.0, wherein the total amount of components (A) and (B) is 100 parts by weight;
(C) a polyorganohydrogensiloxane represented by the average compositional formula (2) and containing at least three Si—H groups per molecule, in an amount to provide 0.2 to 15 moles of Si—H groups per mole of alkenyl groups in components (A) and (B),
R 3 e H f SiO (4-e-f)/2   (2)

wherein R 3 is each independently a substituted or unsubstituted C 1 -C 10 monovalent hydrocarbon group, e and f are numbers in the range: e>0, f>0, and 0<e+f≦3;
(D) a platinum group metal base catalyst for curing by promoting hydrosilylation addition between alkenyl groups in components (A) and (B) and Si—H groups in component (C), in an amount to give 1 to 500 ppm of metal based on the total weight of components (A) to (C);
(E) 0.01 to 10 parts by weight relative to the total weight of components (A) to (C) of a compound containing at least one recurring unit having the formula (3) and at least one Si—H group per molecule,

wherein R 4 to R 11 are each independently hydrogen, halogen, hydroxyl or a C 1 -C 6 monovalent hydrocarbon group, X is selected from divalent organic groups having the formula (4):

wherein R 12 and R 13 are each independently hydrogen, halogen, hydroxyl or a C 1 -C 6 monovalent hydrocarbon group, and g is an integer of at least 1, and Y is each independently a C 1 -C 6 divalent hydrocarbon group which may contain an ether moiety in its structure; and
(F) 0.01 to 100 parts by weight relative to the total weight of components (A) to (C) of an organohydrogenpolysiloxane represented by the average compositional formula (5), exclusive of component (C),

wherein R 14 is each independently a C 1 -C 10 monovalent hydrocarbon group, h is 1, i is an integer of at least 1, j is an integer of at least 1, k and 1 each are an integer of at least 0, and 5≦h+i+j+k+l≦500, and the organohydrogenpolysiloxane has only one Si—H group at a molecular end.

2. The composition of claim 1 , further comprising (G) 0.01 to 5 parts by weight relative to the total weight of components (A) to (C) of a regulator.

3. The composition of claim 1 wherein component (E) is a compound obtained from hydrosilylation addition of (E1) an organic compound having the formula (6) and (E2) a compound having at least two Si—H groups per molecule in the presence of a catalyst,

wherein R 15 to R 22 are each independently hydrogen, halogen, hydroxyl or a C 1 -C 6 monovalent hydrocarbon group, W is a divalent organic group selected from the formula (7):

wherein R 23 and R 24 are each independently hydrogen, halogen, hydroxyl or a C 1 -C 6 monovalent hydrocarbon group, and m is an integer of at least 1, and Z is each independently a C 1 -C 6 hydrocarbon group which may contain an ether moiety in its structure.

4. A pressure-sensitive adhesive article comprising a substrate and a pressure-sensitive adhesive layer on at least one surface of the substrate, the pressure-sensitive adhesive layer being formed by coating the silicone pressure-sensitive adhesive composition of claim 1 onto at least one surface of the substrate and curing the composition.

5. The article of claim 4 wherein the substrate is a plastic film.

6. The composition of claim 1 , wherein component (F) is selected from organohydrogenpolysiloxane represented by following formulae,

wherein i-Pr is isopropyl, n-Bu is normal butyl, Me is methyl group, A is a number of 4 to 300, and B is a number of 1 to 10.

7. The composition of claim 1 , wherein the amount of component (A) is 90 to 40 parts by weight and the amount of component (B) is 60 to 10 parts by weight.

Assignees

• Shinetsu Chemical Co

Inventors

• Tsuchida Osamu

Classifications

• Y10T428/2852

  Adhesive compositions · CPC title

• C09J183/14

  in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms (C09J183/10 takes precedence) · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• C08G77/12

  containing silicon bound to hydrogen · CPC title

• C09J183/04 Primary

  Polysiloxanes · CPC title