Method of bonding a fluoroelastomer compound to a metal substrate using low molecular weight functional hydrocardons as bonding promoter

Patent metadata

Field	Value
Publication number	US-9567450-B2
Application number	US-201214238124-A
Country	US
Kind code	B2
Filing date	Aug 3, 2012
Priority date	Aug 11, 2011
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Provided are methods of bonding a fluoroelastomer to a metal substrate; fluoropolymer compounds comprising a fluoroelastomer, a curing agent and a bonding promoter; and composite materials obtained by curing the compound. Further provided is the use of bonding promoters for increasing the bond strength between a fluoroelastomer and a metal substrate.

First claim

The invention claimed is:

1. A method of bonding a fluoroelastomer to a metal substrate, said method comprises:
i) providing a fluoroelastomer compound comprising a) one or more fluoroelastomer that is curable by a bisphenol curing and b) one or more curing agent with which the fluoroelastomer can be cured, and bringing the fluoroelastomer compound in contact with the metal substrate to form a common interface,
ii) curing the fluoroelastomer compound in the presence of an effective amount of at least one bonding promoter, wherein the bonding promoter has a molecular weight of less than 5,000 g/mole and a boiling point of at least 150° C. at 760 Torr and is selected from saturated aliphatic or aromatic hydroxy ethers, aliphatic monoalkyl esters of an aliphatic or aromatic carboxylic acid and a combination thereof.

2. The method according to claim 1 , wherein the bonding promoter is capable of reducing the glass transition temperature of the fluoroelastomer by at least 4° C. when present in the fluoroelastomer at an amount of 5% by weight based on 100% weight of fluoroelastomer.

3. The method according to claim 1 , wherein the bonding promoter is present in the fluoroelastomer compound.

4. The method according to claim 1 , wherein the bonding promoter is present in an amount of from about 500 ppm to about 10,000 ppm based on the weight of the fluoroelastomer.

5. The method according to claim 1 , wherein the fluoroelastomer has a Mooney viscosity (ML1+10 at 120° C.) of 5 to 150.

6. A composite material comprising a fluoroelastomer component and a metal substrate, wherein the fluoroelestomer component is bonded to the metal and wherein the bond is the result of a curing reaction according to the method of claim 1 .

7. An article comprising the composite material of claim 6 .

8. The article of claim 7 being a seal.

Assignees

• Lochhaas Kai H
• Hintzer Klaus
• Arren Dirk H C
• Eberl Karl
• 3M Innovative Properties Co

Inventors

• Lochhaas Kai H
• Hintzer Klaus
• Arren Dirk H C
• Eberl Karl

Classifications

• B32B2264/108

  Carbon, e.g. graphite particles · CPC title

• Y10T428/3154

  Of fluorinated addition polymer from unsaturated monomers · CPC title

• C08K5/101

  of monocarboxylic acids · CPC title

• C08K5/11 Primary

  of acyclic polycarboxylic acids · CPC title

• C08K5/13

  Phenols; Phenolates · CPC title