Dye-labeled polymers and methods for preparing same
US-2024327655-A1 · Oct 3, 2024 · US
US9567354B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9567354-B2 |
| Application number | US-201213370426-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 10, 2012 |
| Priority date | Feb 10, 2011 |
| Publication date | Feb 14, 2017 |
| Grant date | Feb 14, 2017 |
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Novel amino acid-modified silane compounds having a weakly acidic amino group and a weakly basic carboxyl group are useful as a surface treating agent or textile treating agent.
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The invention claimed is: 1. An amino acid-modified silane compound having the general formula (1): wherein R 1 , R 4 and R 5 each are hydrogen, R 2 and R 3 each are a substituted or unsubstituted, C 1 -C 20 monovalent hydrocarbon group, R 6 is hydrogen or carboxyl group, a is 1, b is 3, and n is 0, 1 or 2. 2. The silane compound of claim 1 , which is N-(3-trimethoxysilylpropyl)-β-alanine, N-(3-methyldimethoxysilylpropyl)-β-alanine, N-(3-triethoxysilylpropyl)-β-alanine, N-(3-methyldiethoxysilylpropyl)-β-alanine, N-(3-trimethoxysilylpropyl)aspartic acid, N-(3-methyldimethoxysilylpropyl)aspartic acid, N-(3-triethoxysilylpropyl)aspartic acid, or N-(3-methyldiethoxysilylpropyl)aspartic acid. 3. A method for preparing the amino acid-modified silane compound of claim 1 , comprising de-triorganosilylation reaction of a silyl-protected, amino acid-modified silane compound having the general formula (2): wherein R 1′ is R 1 or a triorganosilyl group of R 10 R 11 R 12 Si—, R 1 , R 4 and R 5 each are hydrogen, R 2 and R 3 each are a substituted or unsubstituted, C 1 -C 20 monovalent hydrocarbon group, R 6′ is hydrogen or a silyl-protected carboxyl group, R 7 , R 8 , R 9 , R 10 , R 11 and R 12 each are a substituted or unsubstituted, C 1 -C 20 monovalent hydrocarbon group, a is 1, b is 3, and n is 0, 1 or 2.
Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title
Wall, ceiling, or floor bases; Fixing pendants or arms to the bases (F21V21/08 takes precedence; bases for movable standing lamps F21V21/06) · CPC title
Use or application of lighting devices or systems for decorative purposes, not provided for in codes F21W2102/00 – F21W2107/00 · CPC title
Housings, e.g. material or assembling of housing parts (F21V15/02 takes precedence {housings forming signs or letters G09F13/04}) · CPC title
characterised by specific fastening means or way of fastening (F21V17/02 - F21V17/08 take precedence) · CPC title
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