Catalysts and methods of using the same

Patent metadata

Field	Value
Publication number	US-9567265-B2
Application number	US-201314015206-A
Country	US
Kind code	B2
Filing date	Aug 30, 2013
Priority date	Nov 30, 2012
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

The present invention provides a catalyst including a mesoporous silica nanoparticle and a catalytic material comprising iron. In various embodiments, the present invention provides methods of using and making the catalyst. In some examples, the catalyst can be used to hydrotreat fatty acids or to selectively remove fatty acids from feedstocks.

First claim

What is claimed is:

1. A method comprising:
combining a catalyst with at least one first molecule comprising at least one of a fatty acid, a fatty acid ester, a monoglyceride, a diglyceride, and a triglyceride, to provide a mixture, the catalyst comprising a mesoporous silica nanoparticle comprising a catalytic material, the catalytic material comprises iron nanoparticles that are at least partially within pores of the mesoporous silica nanoparticle, wherein
the catalyst is an adsorbent catalyst,
the catalyst comprises at least one adsorbent functional group comprising a functional group selected from the group consisting of an amino(C 1 -C 20 )alkyl group or a salt thereof, a (C 1 -C 20 )alkyl carboxylic acid group or a salt thereof, a (C 1 -C 20 )alkyl sulfonic acid group or a salt thereof, and a perfluoro(C 1 -C 20 )alkyl group,
the alkyl unit of the aminoalkyl group, the alkyl carboxylic acid group, the alkyl sulfonic acid group, and of the perfluoroalkyl group is covalently bound to the mesoporous silica nanoparticle, and
the C 1 -C 20 alkyl groups of the amino(C 1 -C 20 )alkyl group are independently optionally interrupted by one or two —NH— groups; and

combining the mixture with a hydrogen gas under conditions so that the catalytic material in the catalyst catalyzes a chemical transformation of the first molecule comprising hydrotreatment to form a hydrotreatment product, the chemical transformation comprising at least one of hydrogenation, reduction, decarboxylation, and hydrodeoxygenation of the first molecule, wherein the catalyzing of the chemical transformation comprises catalyzing of at least one of the hydrogenation, the reduction, the decarboxylation, and the hydrodeoxygenation at a higher rate than hydrocracking.

2. The method of claim 1 , wherein the catalytic material has a particle size equal to or less than a pore size of the catalytic material.

3. The method of claim 1 , wherein the catalytic material has a particle size of about 5 nm to about 15 nm.

4. The method of claim 1 , wherein about 0.1 wt % to about 30 wt % of the catalyst is the catalytic material.

5. The method of claim 1 , wherein the catalyst has a particle size of about 50 nm-1200 nm.

6. The method of claim 1 , wherein the catalyst has a pore size of about 5 nm to about 15 nm.

7. The method of claim 1 , wherein the first molecule is selectively adsorbed by the adsorbent functional group.

8. The method of claim 1 , wherein the catalyst is sufficient to catalyze hydrocracking of a (C 5 -C 50 ) fatty acid in the presence of H 2 such that, at about 100% conversion of the fatty acid, at a temperature of about 200° C. to about 400° C., about 0.01-15% of the yield of the reaction is hydrocracking product.

9. The method of claim 1 , wherein the catalyst is sufficient to catalyze at least one of hydrogenation, reduction, decarboxylation, and hydrodeoxygenation of at least one of a C 5-50 fatty acid C 1-50 ester and a triglyceride having C 5-50 fatty acid groups in the presence of H 2 at a temperature of about 200° C. to about 400° C.

10. The method of claim 1 , wherein the adsorbent functional group adsorbs fatty acids at a higher rate than it adsorbs at least one of fatty acid esters and triglycerides.

11. The method of claim 1 , wherein the adsorbent functional group comprises at least one of an amino(C 1-10 )alkyl group and a salt thereof wherein the alkyl unit is covalently bound to the mesoporous silica nanoparticle.

12. The method of claim 1 , wherein the adsorbent functional group is present in a concentration of about 0.01 mmol to about 50 mmol per gram of the mesoporous silica nanoparticle.

13. The method of claim 1 , wherein the adsorbent catalyst is sufficient to catalyze decarboxylation and hydrodeoxygenation of a fatty acid at a higher rate than a corresponding mesoporous silica nanoparticle not having the adsorbent functional group bound thereto.

14. The method of claim 1 , wherein:
the mesoporous silica nanoparticle comprises a particle size of about 50 nm to about 1200 nm, a pore size of about 5 nm to about 15 nm, and a pore volume of about 0.5 to about 1.5 cm 3 /g,
the catalytic material comprises iron nanoparticles having a particle size of about 5 nm to about 15 nm at least partially within pores of the mesoporous silica nanoparticle, the iron nanoparticles comprising about 1-10 wt % of the catalyst, and
the catalyst has a surface area of about 150 m 2 /g to about 375 m 2 /g.

Assignees

• Univ Iowa State Res Found Inc

Inventors

• Slowing Igor Ivan
• Kandel Kapil

Classifications

• B01J2235/10

  Infrared [IR] · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/1019

  Operations & Transport · mapped topic