Precipitated calcium carbonate, a method for its manufacture and uses thereof

Patent metadata

Field	Value
Publication number	US-9567234-B2
Application number	US-201414775823-A
Country	US
Kind code	B2
Filing date	Mar 17, 2014
Priority date	Mar 18, 2013
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

Dry precipitated calcium carbonate and a slurry of precipitated calcium carbonate (“PCC”) particles at least partially in the form elongated entities, especially of nanofibers or nanochain like agglomerates constituted by at least two interconnected primary particles, and preferably, with a content of scalenohedron particles, is provided having opacifying properties. The slurry may be produced on site of its use and, due to its high concentration of CaCO 3 , may be applied directly after its manufacture.

First claim

The invention claimed is:

1. A precipitated calcium carbonate comprising scalenohedron particles and
particles which are at least partially in the form of nanofibers or nanochain like agglomerates constituted by at least two interconnected primary particles, wherein
at least a part of the scalenohedron particles and the nanofibers or nanochain like agglomerates form microshells.

2. The precipitated calcium carbonate according to claim 1 wherein the primary particle size of the nanofibers or nanochain like agglomerates is from 50 to 200 nm.

3. The precipitated calcium carbonate according to claim 1 wherein the average length of the scalenohedron particles is in a range of from 250 to 500 nm.

4. The precipitated calcium carbonate according to claim 1 , wherein the precipitated calcium carbonate particles comprise a crystallization controller.

5. The precipitated calcium carbonate according to claim 3 , wherein the crystallization controller has an average molecular weight from 500 to 15000 g/mol.

6. The precipitated calcium carbonate according to claim 1 , wherein the nanofibers or nanochain like agglomerates have an average diameter from 50 to 200 nm, and wherein the nanofibers or nanochain like agglomerates have an average length from 80 to 1000 nm.

7. The precipitated calcium carbonate according to claim 1 , wherein the nanofibers or nanochain like agglomerates are at least partially combined in the form of microshell like aggregates.

8. The precipitated calcium carbonate according to claim 1 wherein the precipitated calcium carbonate is in the form of an aqueous slurry.

9. The precipitated calcium carbonate in the form of an aqueous slurry according to claim 8 which comprises 19 to 60% by weight of the precipitated calcium carbonate.

10. The precipitated calcium carbonate of claim 8 , obtained by
a) reacting CaO with water to form Ca(OH) 2 ,
a1) drying the Ca(OH) 2 of step a) to provide dry Ca(OH) 2 ;
b) contacting the dry Ca(OH) 2 with water to form a slurry; and
c) carbonating the slurry of Ca(OH) 2 from step b) with CO 2 .

11. A process for the manufacture of precipitated calcium carbonate which is suitable as opacifier, which process comprises
a) reacting CaO with water to form dry Ca(OH) 2 ,
b) contacting the dry Ca(OH) 2 of step a) with water to form a slurry; and
c) carbonating the slurry of Ca(OH) 2 from step b) with CO 2 to form scalenohedron particles.

12. The process of claim 11 , wherein step a) comprises drying the Ca(OH) 2 to provide dry Ca(OH) 2 .

13. A method for the manufacture of paint, plastics, paper, plastisol, sealant or ink wherein the precipitated calcium carbonate of claim 1 is applied in a production plant to provide precipitated calcium carbonate as filler.

14. The method of claim 13 wherein the precipitated calcium carbonate, in the form of a slurry, is applied in a production planter for the manufacture of paint, plastics, paper, or ink.

15. The method of claim 14 wherein the slurry is produced on site of the production plant.

16. The method of claim 13 comprising a step of drying the slurry to provide dry precipitated calcium carbonate which is then applied for the manufacture of plastisols, sealants or polymers.

17. The method of claim 13 wherein the paint, plastics, paper, plastisol, sealant or ink do not contain any TiO 2 filler.

18. The method of claim 13 wherein the plastics are polyethylene plastics.

Assignees

• Solvay
• Imerys Sa

Inventors

• Rico Jean-Luc
• Raboteau Cédric
• Jakob Alexandra

Classifications

• C01F11/182

  Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C09D11/00

  Inks · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title