Polishing agent, polishing agent set and method for polishing base
US-2015232704-A1 · Aug 20, 2015 · US
US9566685B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9566685-B2 |
| Application number | US-201414769377-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 14, 2014 |
| Priority date | Feb 21, 2013 |
| Publication date | Feb 14, 2017 |
| Grant date | Feb 14, 2017 |
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This invention provides a polishing composition comprising an abrasive, a water-soluble polymer and water. The water-soluble polymer comprises a polymer A having an adsorption ratio of lower than 5% and a polymer B having an adsorption ratio of 5% or higher, but lower than 95% based on a prescribed adsorption ratio measurement. Herein, the polymer B is selected from polymers excluding hydroxyethyl celluloses.
Opening claim text (preview).
The invention claimed is: 1. A polishing composition comprising an abrasive, a water-soluble polymer and water, the composition comprising, as the water-soluble polymer, a polymer A having an adsorption ratio of lower than 5% and a polymer B having an adsorption ratio of 5% or higher, but lower than 95% based on an adsorption ratio measurement as follows: (1) a test solution L0 is obtained, comprising 0.018% by mass of a measured polymer and 0.01% by mass of ammonia with the rest being water; (2) a test solution L1 is obtained, comprising 0.18% by mass of the abrasive as well as 0.018% by mass of the measured polymer and 0.01% by mass of ammonia with the rest being water; (3) the test solution L1 is centrifuged to precipitate the abrasive; and (4) the measured polymer in the test solution L0 has a mass W0, the measured polymer in the supernatant of the centrifuged test solution L1 has a mass W1, and the measured polymer has an adsorption ratio determined by the next equation: Adsorption ratio (%)=[( W 0− W 1)/ W 0]×100; wherein, the polymer B is selected from polymers excluding hydroxyethyl celluloses. 2. The polishing composition according to claim 1 , wherein the polymer B has a weight average molecular weight (Mw) to number average molecular weight (Mn) ratio (Mw/Mn) of 5.0 or lower. 3. The polishing composition according to claim 1 , wherein the polymer B has a weight average molecular weight (Mw) of 1×10 4 or larger, but smaller than 25×10 4 . 4. The polishing composition according to claim 1 , wherein the polymer B is a nonionic polymer. 5. The polishing composition according to claim 1 , wherein the polymer B comprises a pendant group having an amide bond. 6. The polishing composition according to claim 1 , wherein the polymer A is a polyvinyl alcohol. 7. The polishing composition according to claim 1 , further comprising a basic compound. 8. The polishing composition according to claim 1 used for polishing a silicon wafer. 9. A method for producing a polished article, the method comprising: obtaining a polishing liquid that comprises the polishing composition according to claim 1 ; supplying the polishing liquid to a polishing object; and polishing a surface of the polishing object with the polishing liquid. 10. The polished article production method according to claim 9 , wherein the polishing object is a silicon wafer.
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