Process for producing granules comprising one or more complexing agent salts

Patent metadata

Field	Value
Publication number	US-9562213-B2
Application number	US-201414272094-A
Country	US
Kind code	B2
Filing date	May 7, 2014
Priority date	Sep 27, 2010
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A process for producing granules comprising one or more complexing agent salts of formula (I):

from an aqueous starting solution, comprising the one or more complexing agent salts in a concentration of from 10 to 80% by weight, based on the total weight of the aqueous starting solution, in a jet apparatus.

First claim

The invention claimed is:

1. A process for producing granules, the process comprising:
spraying an aqueous starting solution into a driving jet of a jet apparatus, thereby drying the aqueous starting solution to obtain round compact granules; and
discharging the granules from the jet apparatus,

wherein:
the aqueous starting solution comprises at least one complexing agent salt in a concentration from 10 to 80% by weight, based on a total weight of the aqueous starting solution;
the at least one complexing agent salt is defined by formula (I):

in which
R′ is one of the groups

where
R″ is hydrogen, a C 1 -C 12 -alkyl radical or a —(CH 2 ) q —COOM radical where q=1 to 5,
n and m are in each case an integer from 0 to 5, and
R′″ is hydrogen or a C 1 -C 12 -alkyl radical or a C 2 -C 12 -alkenyl radical, which may be additionally substituted with up to 5 hydroxyl groups, or is one of the groups

in which
o and p are in each case an integer from 0 to 5, and
M is independently hydrogen, alkali metal, alkaline earth metal, ammonium or substituted ammonium in the corresponding stoichiometric amounts; and
in the jet apparatus
a gaseous driving jet positioned centrally and directed from bottom to top, or one or more gaseous driving jets positioned in a region of a central axis of the jet apparatus, induce an internal loop motion, with formation of a jet zone,
joined to an upper end of the jet apparatus is a fountain zone, which merges into a return zone in a wall region of the jet apparatus, and
the return zone, in its lower region, merges into the jet zone, where the aqueous starting solution is sprayed into the one or more gaseous driving jets.

2. The process according to claim 1 , wherein the jet apparatus is a cylindrical apparatus which is conically tapered in the lower region, and into which a central gaseous driving jet is sprayed.

3. The process according to claim 1 , wherein the jet apparatus has a rectangular cross section which tapers in its lower section and which has one or more gaseous driving jets positioned in the region of the central axis of the jet apparatus and directed from bottom to top.

4. The process according to claim 1 , wherein the jet apparatus includes the one or more gaseous driving jets that formed from a gas which is under a positive pressure in the range from 20 mbar to 1 bar above the pressure in the jet apparatus, such that the aqueous starting solution decompresses by passing through one or more openings in the jet apparatus and in so doing forms the one or more gaseous driving jets.

5. The process according to claim 1 , wherein the aqueous starting solution is sprayed in via one or more single-material or two-material nozzles into the lower region of the jet apparatus.

6. The process according to claim 1 , wherein crystalline fine dust with an average particle diameter in the range from about 1 to 100 μm, is added to the jet apparatus, separately from the aqueous starting solution, at a position in the jet apparatus which is different from a position at which the aqueous starting solution is sprayed into the jet apparatus.

7. The process according to claim 6 , wherein the crystalline fine dust has an average particle diameter ranging from about 1 to 20 μm.

8. The process according to claim 6 , wherein the crystalline fine dust comprises the at least one complexing agent salt of formula (I), or one or more complexing agent salts different therefrom.

9. The process according to claim 1 , wherein the aqueous starting solution and a crystalline fine dust with an average particle diameter in the range from about 1 to 100 μm, are premixed to give a suspension, and the suspension is sprayed into the lower region of the jet apparatus and sucked in by the driving jet.

10. The process according to claim 9 , wherein the crystalline fine dust has an average particle diameter ranging from about 1 to 20 μm.

11. The process according to claim 1 , wherein a gas stream forming the driving jet has a temperature ranging between 80 and 450° C.

12. The process according to claim 11 , wherein the gas stream forming the driving jet has a temperature ranging between 120 and 240° C.

13. The process according to claim 1 , wherein a temperature in the jet zone, in the fountain zone and in the return zone, ranges between 70 and 150° C.

14. The process according to claim 1 , wherein an average residence time of the granules in the jet apparatus is between 1 minute and 1 hour.

15. The process according to claim 14 , wherein the average residence time of the granules in the jet apparatus is between 10 minutes and 40 minutes.

16. The process according to claim 1 further comprising press agglomerating the granules to produce pressed agglomerates.

17. The process according to claim 16 , wherein the pressed agglomerates are adapted to function as solid cleaners.

18. The process according to claim 17 , wherein the solid cleaners are adapted to function in dishwashers.

Assignees

• Basf Se

Inventors

• Blei Stefan
• Schoenherr Michael
• Weber Franz
• Becker Francois

Classifications

• C07C229/24

  having more than one carboxyl group bound to the carbon skeleton, e.g. aspartic acid · CPC title

• C11D3/33 Primary

  Amino carboxylic acids · CPC title

• C11D17/0091 Primary

  Dishwashing tablets · CPC title

• C11D7/3245

  Aminoacids · CPC title

• C07C229/26

  having more than one amino group bound to the carbon skeleton, e.g. lysine · CPC title