Lubricants comprising 2-hydroxyalkylamide friction modifying compositions

Patent metadata

Field	Value
Publication number	US-9562207-B2
Application number	US-201313795328-A
Country	US
Kind code	B2
Filing date	Mar 12, 2013
Priority date	May 23, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

Lubricant compositions comprising an improved ashless organic friction modifier additive, capable of reducing both friction and wear, is provided. It has been found that mixtures of fatty-alkanolamides containing secondary hydroxyls on the amino alkyl substituent, such as amide mixtures prepared from bis(2-hydroxyporopyl)amine and mixtures of at least two different C 8-24 fatty acids, provide better oil solubility and friction reduction than alkanolamides with primary hydroxyl functionality, such as amide mixtures prepared from di-ethanol)amine.

First claim

What is claimed:

1. A lubricant composition comprising:
a) a major portion of a lubricating oil comprising one or more naturally occurring and/or synthetic base stocks, and
b) from 0.5 to 1 wt % based on the total weight of the lubricant composition of a friction reducing/antiwear additive composition comprising a mixture of two or more fatty acid 2-hydroxyalkylamides of formula II

wherein R is methyl;
and R′ is selected from C 7-19 alkyl or alkenyl, wherein
about 20 to about 35% by weight of the 2-hydroxyalkylamides are compounds where R′ is C 15 alkyl or alkenyl, wherein about 75% or more of said C 15 alkyl or alkenyl are alkyl,
about 50 to about 75% by weight of the 2-hydroxyalkylamides are compounds where R′ is C 17 alkyl or alkenyl, wherein about 40% to about 95% of said C 17 alkyl or alkenyl are alkenyl
wherein the mixture of two or more fatty acid 2-hydroxyalkylamides of formula II are prepared from a hydroxyalkylamine and a mixture of fatty acids or fatty acid esters with different alkylcarboxy chain lengths obtained from beef tallow.

2. The lubricant composition according to claim 1 , comprising
a) from about 90 to about 99.5 wt % of a natural or synthetic lubricating oil base stock,
b) from 0.5 to 1 wt % based on the total weight of the lubricant composition, of the friction reducing/antiwear additive composition comprising a mixture of two or more fatty acid 2-hydroxyalkylamides of formula I, and
c) one or more additional lubricant additives selected from the group consisting of dispersants, detergents, corrosion/rust inhibitors, antioxidants, other anti-wear agents, anti-foamants, other friction modifiers, seal swell agents, demulsifiers, V.I. improvers and pour point depressants,
wherein the combined amount of b) and c) present in the composition is from about 0.5 to about 10 weight percent based on the total weight of the lubricant composition.

Assignees

• Chemtura Corp

Inventors

• Deblase Frank J
• Corbo Faith A

Classifications

• C10N2040/135

  Steam engines or turbines · CPC title

• C10M2207/289

  containing free hydroxy groups · CPC title

• C10M133/56

  Amides; Imides · CPC title

• C10N2020/067

  Unsaturated Compounds · CPC title

• C10N2020/065

  Saturated Compounds · CPC title