Method for producing lubricant base oil

Patent metadata

Field	Value
Publication number	US-9562200-B2
Application number	US-201314388338-A
Country	US
Kind code	B2
Filing date	Mar 29, 2013
Priority date	Mar 30, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A method for producing a lubricant base oil, the method comprising a first step of fractionating, from a hydrocarbon oil containing a base oil fraction and a heavy fraction that is heavier than the base oil fraction, the base oil fraction and the heavy fraction, and a second step of obtaining a dewaxed oil by isomerization and dewaxing of the base oil fraction fractionated in the first step, wherein a hydrocracked oil obtained by hydrocracking the heavy fraction fractionated in the first step is returned to the first step.

First claim

The invention claimed is:

1. A method for producing a lubricant base oil, the method comprising:
fractionating, from a hydrocarbon oil containing a base oil fraction and a heavy fraction that is heavier than the base oil fraction, the base oil fraction and the heavy fraction to form a fractionated base oil and a fractionated heavy fraction;
obtaining a dewaxed oil by isomerization and dewaxing of the fractionated base oil fraction in the presence of a hydroisomerization catalyst,
hydrocracking the fractionated heavy fraction to form a hydrocracked fraction, and returning the hydrocracked heavy fraction to the fractionating step;
wherein in the isomerization and dewaxing of the fractionated base oil fraction, the hydroisomerization catalyst is a hydroisomerization catalyst containing a support that includes a zeolite having a one-dimensional porous structure including a 10-membered ring and a binder, and platinum and/or palladium supported on the support, in which a carbon content of the catalyst is 0.4 to 3.5% by mass and a micropore volume is 0.02 to 0.12 cc/g; and
the zeolite is derived from an ion-exchanged zeolite obtained by ion-exchanging an organic template-containing zeolite that contains an organic template and has a one-dimensional porous structure including a 10-membered ring in a solution containing ammonium ions and/or protons, in which a micropore volume per unit mass is 0.01 to 0.12 cc/g.

2. The method according to claim 1 , wherein the base oil fraction is a fraction having a boiling point range of 330 to 520° C.

3. The method according to claim 1 , wherein the hydrocarbon oil contains a Fischer-Tropsch synthesis reaction oil, and
the hydrocracking is carried out in the presence of hydrogen by bringing the heavy fraction into contact with a hydrocracking catalyst containing an inorganic support that is a solid acid and one or more metals selected from group 6, group 8, group 9 and group 10 of the periodic table that is supported on the inorganic support and that has a hydrogenation activity.

4. The method according to claim 1 , wherein the hydrocarbon oil contains a petroleum-derived hydrocarbon oil, and
the hydrocracking is carried out in the presence of hydrogen by bringing the heavy fraction into contact with a hydrocracking catalyst containing a porous inorganic oxide that includes two or more elements selected from aluminum, silicon, zirconium, boron, titanium, and magnesium, and one or more metals selected from the elements of group 6, group 8, group 9 and group 10 of the periodic table that are supported on the porous inorganic oxide.

5. The method according to claim 1 , wherein a conversion rate of the hydrocracking is 20 to 50% by volume.

Assignees

• Jx Nippon Oil & Energy Corp

Inventors

• Iwama Marie
• Hayasaka Kazuaki
• Nagayasu Yoshiyuki
• TAKAHAMA Koshi

Classifications

• B01J29/068

  Noble metals · CPC title

• C10G2300/1022

  Fischer-Tropsch products · CPC title

• C10G47/12

  Inorganic carriers · CPC title

• C10G45/64

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10M2203/1006

  used as base material · CPC title