Plant fiber-reinforced thermoplastic resin composition

Patent metadata

Field	Value
Publication number	US-9562152-B2
Application number	US-201213648738-A
Country	US
Kind code	B2
Filing date	Oct 10, 2012
Priority date	Oct 10, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

The present invention is directed to plant fiber-reinforced thermoplastic compositions and a method for reinforcing thermoplastic resins. The present invention provides a use for the cellulose portion of a plant material, which is the portion left over after processing the selected plant materials to separate the hemi-cellulose and lignin from the cellulose.

First claim

We claim:

1. A reinforced thermoplastic resin composition consisting of:
a) a thermoplastic resin;
b) from about 1 to about 60 weight percent cellulose fibers based on the weight of the composition, the cellulose fibers having a porous surface obtained by the mechanical shearing and subsequent chemical separation of the cellulose fiber fraction from hemi-cellulose and lignin fractions of a natural plant material, wherein the cellulose fibers and the thermoplastic resin are molecularly bonded to one another by the resin flowing into and diffusing or dissolving the cellulose fibers in the resin.

2. The composition of claim 1 wherein the natural plant material is selected form the group consisting of natural fibrous plant materials including a) seed fiber plants, linters, cotton, kapok and poplar down, b) bast fiber plants, sclerenchyma fiber plants, bamboo fiber plants, nettles, hemp, jute, linen or flax, and ramie, c) hard fiber plants, sisal, kenaf and manila, d) coir, and e) grasses.

3. The composition of claim 1 wherein the natural plant material is a bast fiber plant material.

4. The composition of claim 3 wherein the cellulose fibers are formed of at least 95% pure cellulose fibers.

5. The composition of claim 1 wherein the thermoplastic resin is selected from the group consisting of polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyacryl nitrite, polyamides, polyesters, polyacrylates and mixtures thereof.

6. The composition of claim 1 wherein the thermoplastic is a polyolefin or polyamide or an engineering plastic.

7. The composition of claim 6 wherein the thermoplastic is polypropylene or acrylonitrile butadiene styrene.

8. A reinforced thermoplastic resin composition comprising:
a) a thermoplastic resin; and
b) from about 1 to about 60 weight percent cellulose fibers based on the weight of the composition, the cellulose fibers having a porous surface obtained by the mechanical shearing and subsequent chemical separation of the cellulose fiber fraction from hemi-cellulose and lignin fractions of a natural plant material, wherein the cellulose fibers and the thermoplastic resin are molecularly bonded to one another by the resin flowing into and diffusing or dissolving the cellulose fibers in the resin.

9. A reinforced thermoplastic resin composition comprising:
a) a thermoplastic material; and
b) from about 1 to about 60 weight percent cellulose fibers based on the weight of the composition, the cellulose fibers having a porous surface obtained by the mechanical shearing and subsequent chemical separation of the cellulose fiber fraction from hemi-cellulose and lignin fractions of flax, wherein the cellulose fibers and the thermoplastic are molecularly bonded to one another as a result of the resin flowing into and molecularly bonding with the porous cellulose fibers that diffuse or dissolve into the resin.

Assignees

• Cnh Canada Ltd
• Cnh Ind Canada Ltd

Inventors

• Henry James
• Panigrahi Satyanarayan
• Kushwaha Radhey Lal

Classifications

• C08L1/02 Primary

  Cellulose; Modified cellulose · CPC title

• C08K7/02

  Fibres or whiskers · CPC title

• C08L97/02

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title

• C08J5/045

  with vegetable or animal fibrous material · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title