Catalyst for the production of polyols having lower amounts of high molecular weight tail

Patent metadata

Field	Value
Publication number	US-9562134-B2
Application number	US-201313795146-A
Country	US
Kind code	B2
Filing date	Mar 12, 2013
Priority date	Mar 12, 2013
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

This invention relates to novel double metal cyanide catalysts and to a process for the production of these double metal cyanide catalysts. These DMC catalysts can be used to prepare polyoxyalkylene polyols which have low amounts of high molecular weight tail compared polyoxyalkylene polyols prepared from DMC catalysts of the prior art.

First claim

What is claimed is:

1. A double-metal cyanide catalyst comprising:
(a) at least one metal salt,
(b) at least one metal cyanide salt,
(c) at least one alkali metal salt of an oxyacid with a pKa equal to or less than 3.5,
(d) at least one organic complexing ligand,
and
(e) optionally, one or more functionalized polymers;
wherein alkali metal is present in the catalyst in an amount of from 0.4 to 10 wt. %, based on the total weight of the catalyst.

2. The double-metal cyanide catalyst of claim 1 , wherein alkali metal is present in the catalyst in an amount of from 0.8 to 8 wt. %, based on the total weight of the catalyst.

3. The double-metal cyanide catalyst of claim 1 , wherein the oxyacid has a pKa equal to or less than 3.0.

4. The double-metal cyanide catalyst of claim 1 , wherein the oxyacid is selected from the group consisting of sulfuric acid, sulfonic acid, sulfurous acid, phosphoric acid, nitric acid, nitrous acid and mixtures thereof.

5. The double-metal cyanide catalyst of claim 1 , wherein the alkali metal of (c) said alkali metal salt is selected from the group consisting of sodium, potassium, cesium and mixtures thereof.

6. The double-metal cyanide catalyst of claim 1 , wherein (c) said alkali metal salt is selected from the group consisting of potassium nitrate, potassium sulfate and mixtures thereof.

7. A process for preparing a double-metal cyanide catalyst comprising
(1) reacting
(a) at least one metal salt,
(b) at least one metal cyanide salt,
and
(c) at least one alkali metal salt of an oxyacid with a pKa equal to or less than 3.5,
in the presence of
(d) at least one organic complexing ligand,
and
(e) optionally, one or more functionalized polymer;
under conditions sufficient to form a catalyst, wherein alkali metal is present in the catalyst in an amount of from 0.4 to 10 wt. %, based on the total weight of the catalyst.

8. The process of claim 7 , wherein alkali metal is present in the catalyst in an amount of from 0.8 to 8 wt. %, based on the total weight of the catalyst.

9. The process of claim 7 , wherein the oxyacid has a pKa equal to or less than 3.0.

10. The process of claim 7 , wherein the oxyacid is selected from the group consisting of sulfuric acid, sulfonic acid, sulfurous acid, phosphoric acid, nitric acid, nitrous acid and mixtures thereof.

11. The process of claim 7 , wherein the alkali metal of (c) said alkali metal salt is selected from the group consisting of sodium, potassium, cesium and mixtures thereof.

12. The process of claim 7 , wherein (c) said alkali metal salt is selected from the group consisting of potassium nitrate, potassium sulfate and mixtures thereof.

13. A process for preparing a polyoxyalkylene polyol comprising reacting i) at least one starter compound having active hydrogen atoms, with ii) at least one alkylene oxide, in the presence of iii) the double-metal cyanide catalyst of claim 1 .

Assignees

• Bayer Materialscience Llc
• Covestro Llc

Inventors

• Mcdaniel Kenneth G
• Combs George G

Classifications

• B01J2531/26

  Zinc · CPC title

• C08G65/2606

  containing hydroxyl groups · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J2531/845

  Cobalt · CPC title

• B01J31/068

  Polyalkylene glycols · CPC title