Cross-linked polycarbonate resin with improved chemical and flame resistance

Patent metadata

Field	Value
Publication number	US-9562133-B2
Application number	US-201314137002-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 20, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.

First claim

What is claimed is:

1. A composition having improved flame resistance comprising:
a cross-linked polycarbonate, the cross-linked polycarbonate derived from a non-cross-linked polycarbonate with an endcap content that consists of endcap groups derived from a monohydroxybenzophenone, wherein the endcap content is about 0.5 mol% to about 5 mol% of the non-cross-linked polycarbonate; and
a flame retardant;
wherein the composition does not comprise an impact modifier;
wherein a plaque formed from the composition achieves a UL94 5VA rating at a thickness of 1.5 ±10% mm or less.

2. The composition of claim 1 , wherein the endcap content of the non-cross-linked polycarbonate is about 1 mol% to about 3mol% of the non-cross-linked polycarbonate.

3. The composition of claim 1 , wherein the flame retardant is potassium perfluorobutane sulfonate (Rimar salt), potassium diphenyl sulfone-3-sulfonate (KSS), or a combination thereof.

4. The composition of claim 1 , further comprising a cyclic siloxane.

5. The composition of claim 1 , wherein the flame retardant is present in an amount of about 0.08 wt % or less, based on the total weight of the composition.

6. The composition of claim 1 , wherein the composition achieves a UL94 5VA rating in the absence of a brominated and/or chlorinated flame retardant.

7. The composition of claim 1 , wherein the plaque formed from the composition has a transparency of 70% or greater at a thickness of 3.2 mm, measured according to ASTM-D1003-00.

8. The composition of claim 1 , wherein the plaque formed from the composition has a haze value of less than 10% at a thickness of 3.2 mm, measured according to ASTM D1003-00.

9. The composition of claim 1 , wherein an ASTM part formed from the composition has full ductility under multiaxial impact test conditions per ASTM D3763 at −30° C. determined using a 4-inch (10 cm) diameter, 3.2 millimeter (mm)-thick disk sample, 1/2 -inch (12.7 mm) diameter dart, and an impact velocity of 3.3meters per second (m/s).

10. The composition of claim 1 , wherein an ASTM Type 1 tensile bar part formed from the composition has an elongation at break of at least 100% using the ASTM D 638 Type I method at 50 mm/min after exposure to acetone under 1% strain at 23 ° C.

11. The composition of claim 1 , wherein an ASTM part formed from the composition has an elongation at break of 50% to about 200% according to ASTM D 638.

12. The composition of claim 1 , wherein the non-cross-linked polycarbonate has a molecular weight greater than 17,000 Daltons and less than or equal to 80,000 Daltons, as measured by gel permeation chromatography using polycarbonate standards.

13. The composition of claim 1 , wherein the non-cross-linked polycarbonate has a melt volume flow rate ranging from about 5 to about 30 cc/10 min at 300 ° C./1.2 kg.

14. The composition of claim 1 , wherein the monohydroxybenzophenone is 4-hydroxybenzophenone.

15. The composition of claim 1 , wherein the cross-linked polycarbonate comprises repeating units derived from bisphenol-A.

16. The composition of claim 1 , wherein the non-cross-linked polycarbonate has repeating units having branching groups.

17. The composition of claim 1 , wherein the non-crossed-linked polycarbonate is a compound of formula (I),

wherein each repeating unit —O—Z—OC(═O)— is independently derived from a carbonate source and
(i) a monomer having the structure HO-A 1 -Y 1 -A 2 -OH wherein each of A 1 and A 2 comprise a monocyclic divalent arylene group, and Y 1 is a bridging group having one or more atoms; or
(ii) a monomer having the structure

wherein each R h is independently a halogen atom, a C 1 -C 10 hydrocarbyl, or a halogen substituted C 1 -C 10 hydrocarbyl, and n is 0 to 4;
R 1 is halogen, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, aryl, or arylalkyl;
R 2 is halogen, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, aryl, or arylalkyl;
x is 0, 1, 2, 3, or 4;
y is 0, 1, 2, 3, 4, or 5; and
n′ ranges from 29 to 65.

18. The composition of claim 17 , wherein the non-crossed-linked polycarbonate is a compound of formula (II):

wherein n′ ranges from 29 to 65.

19. The composition of claim 1 , wherein the composition contains at least 5 wt % of an insoluble methylene chloride insoluble fraction in a 1 mm thick film.

20. The composition of claim 1 , further comprising a p-cumyl phenol capped poly(isophthalate-terephthalate-resorcinol ester)-co-(bisphenol-A carbonate) polymer or a polycarbonate polysiloxane copolymer wherein the polysiloxane content is from 0.4 wt % to 25 wt %.

21. The composition of claim 20 , wherein the polycarbonate polysiloxane copolymer is a siloxane block co-polycarbonate comprising from about 6 wt % siloxane ±10% to about 20 wt % siloxane ±10%.

22. A composition having improved flame resistance, comprising a cross-linked polycarbonate derived from a non-cross-linked polycarbonate with an endcap content consisting of endcap groups derived from a monohydroxybenzophenone, and potassium perfluorobutane sulfonate (Rimar salt) in an amount of about 0.05 wt % to about 0.085 wt %, based on the total weight of the composition, wherein the endcap content is about 0.5 mol % to about 5mol % of the non-cross-linked polycarbonate;
wherein the composition does not comprise an impact modifier;
wherein a plaque formed from the composition achieves a UL94 5VA rating at a thickness of 1.5 ±10% mm or less in the absence of a brominated and/or chlorinated flame retardant; and
wherein the plaque comprising the composition has a transparency of 70to 90% at a thickness of 3.2 mm, measured according to ASTM-D1003-00.

23. The composition of claim 22 , wherein the potassium perfluorobutane sulfonate (Rimar salt) is present in an amount of about 0.06 wt % to about 0.08 wt %.

24. The composition of claim 22 , wherein the cross-linked polycarbonate does not contain any soft block segments from aliphatic polyesters, aliphatic polyethers, aliphatic polythioeithers, aliphatic polyacetals, aliphatic polycarbonates, C-C linked polymers, or polysiloxanes.

25. The composition of claim 22 , wherein the cross-linked polycarbonate does not contain any repeating units derived from a dihydroxybenzophenone, a trihydroxybenzophenone, or a tetrahydroxybenzophenone.

26. An article formed from the composition of claim 1 .

27. The article of claim 26 , wherein the article is at least one of an automotive bumper, an automotive exterior component, an automobile mirror housing, an automobile wheel cover, an automobile instrument panel or trim, an automobile glove box, an automobile door hardware or other interior trim, an automobile exterior light, an automobile part within the engine compartment, an agricultural tractor or device part, a construction equipment vehicle or device part, a marine or personal water craft part, an all terrain vehicle or all terrain vehicle part, plumbing equipment, a valve or pump, an air conditioning heating or cooling part, a furnace or heat pump part, a computer part, a computer router, a desk top printer, a large office/industrial printer, an electronics part, a projector

Assignees

• Sabic Innovative Plastics Ip Bv
• Sabic Global Technologies Bv

Inventors

• Morizur Jean-Francois
• Sybert Paul Dean

Classifications

• C08G64/045

  containing aliphatic unsaturation · CPC title

• B29C2035/0827

  using UV radiation · CPC title

• B29K2069/00

  Use of PC, i.e. polycarbonates {or derivatives thereof}, as moulding material · CPC title

• B29C45/0001

  characterised by the choice of material · CPC title

• C08J2469/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title