Dispersion stabilizer for suspension polymerization and method for producing vinyl resin

Patent metadata

Field	Value
Publication number	US-9562115-B2
Application number	US-201414910595-A
Country	US
Kind code	B2
Filing date	Aug 6, 2014
Priority date	Aug 7, 2013
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

The present invention provides an easy-to-handle dispersion stabilizer for suspension polymerization that meets the following requirements: even if the amount of the dispersion stabilizer for suspension polymerization used for suspension polymerization of a vinyl compound is small, the resulting vinyl resin has high plasticizer absorptivity and is easy to work with; it is easy to remove residual monomer components from the resulting vinyl resin; and the resulting vinyl resin contains fewer coarse particles. The present invention relates to a dispersion stabilizer for suspension polymerization in the form of an aqueous liquid. This dispersion stabilizer contains, at a concentration of 20 mass % or more and 50 mass % or less, a PVA having a degree of saponification of 35 mol % or more and 65 mol % or less, a viscosity average degree of polymerization of 100 or more and 480 or less, a terminal aliphatic hydrocarbon group having 6 to 12 carbon atoms, and a block character of residual ester groups of 0.5 or more. In this dispersion stabilizer, the viscosity average degree of polymerization (P) of the PVA and the degree of modification (S) of the aliphatic hydrocarbon group satisfies 50≦S×P/1.880≦100.

First claim

The invention claimed is:

1. A dispersion stabilizer for suspension polymerization in the form of an aqueous liquid, comprising:
a vinyl alcohol polymer (A) having a degree of saponification of 35 to less than 60 mol %, a viscosity average degree of polymerization (P) of 100 to 480, a terminal aliphatic hydrocarbon group having 6 to 12 carbon atoms, and a block character of residual ester groups of 0.5 to 2; and
water, wherein
the block character is determined by 13 C-NMR spectroscopy, the viscosity average degree of polymerization (P) is calculated using the following Nakajima's equation,
[η] acetone, 30° C. =7.94×10 −4 ·P 0.62

the dispersion stabilizer is in the form of an aqueous liquid,
the vinyl alcohol polymer (A) is present at a concentration of 20 to 50 mass % in said aqueous liquid, and
wherein the relationship between the viscosity average degree of polymerization (P) of the vinyl alcohol polymer (A) and a degree of modification (S) of the aliphatic hydrocarbon group satisfies the following formula (1):
50≦ S×P/ 1.880≦100  (1).

2. The dispersion stabilizer for suspension polymerization according to claim 1 , wherein the viscosity average degree of polymerization (P) of the vinyl alcohol polymer (A) is 150 to 480.

3. The dispersion stabilizer for suspension polymerization according to claim 1 , further comprising a vinyl alcohol polymer (B) having a degree of saponification of more than 65 to 95 mol % and a viscosity average degree of polymerization of more than 480 to 8,000, wherein
the viscosity average degree of polymerization (P) is calculated using the following Nakajima's equation,
[η] acetone, 30° C. =7.94×10 −4 ·P 0.62 .

4. The dispersion stabilizer for suspension polymerization according to claim 3 , wherein the mass ratio between the vinyl alcohol polymer (A) and the vinyl alcohol polymer (B) ([vinyl alcohol polymer (A)]/[vinyl alcohol polymer (B)]) is 10/90 to 55/45 in terms of solid content ratio.

5. A method for producing a vinyl resin, comprising conducting suspension polymerization of a vinyl compound in the presence of the dispersion stabilizer for suspension polymerization according to claim 1 .

6. The method according to claim 5 , wherein the suspension polymerization is conducted in the presence of water, and the mass ratio between the vinyl compound and the water ([vinyl compound]/[water]) is more than 3/4 to less than 10/9.

Assignees

• Kuraray Co

Inventors

• Fukuhara Tadahito
• Kumaki Yosuke

Classifications

• C08L2201/54

  Aqueous solutions or dispersions · CPC title

• C08F2/20 Primary

  with the aid of macromolecular dispersing agents · CPC title

• C08F8/12

  Hydrolysis · CPC title

• C08F2/30

  non-ionic · CPC title

• C08F114/06

  Vinyl chloride · CPC title