Method for revamping a secondary reformer

Patent metadata

Field	Value
Publication number	US-9561484-B2
Application number	US-201314391912-A
Country	US
Kind code	B2
Filing date	May 7, 2013
Priority date	May 9, 2012
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A method for revamping a secondary reformer ( 1 ), the reformer comprising an internal gas riser pipe ( 8 ) for routing a process gas from a bottom gas inlet to a combustion chamber ( 5 ) located above a catalytic zone ( 6 ), and a distributor ( 9 ) for introduction of an oxidation agent such as process air into the combustion chamber. The original distributor of the oxidation agent is discontinued, the gas riser pipe is shortened ( 8 ′) and the outlet end of the shortened gas riser pipe is arranged to deliver a gas flow directed upwards. A new burner ( 20 ) is installed on top of the reformer, the new burner being arranged to deliver an oxidation agent such as process air with a downward flow, thus obtaining a counterflow mixing zone ( 23 ) and formation of a diffusion flame above the outlet end of the gas riser pipe.

First claim

The invention claimed is:

1. A method for revamping a secondary reformer wherein said reformer comprises:
a vertical pressure vessel, a bottom inlet for a process gas;
a combustion chamber and a catalytic zone, the catalytic zone being located below the combustion chamber;
an internal gas riser pipe connected to said bottom inlet for a process gas;
distribution means for introduction of an oxidation agent into said combustion chamber;
wherein said gas riser pipe has a gas outlet end which is above the combustion chamber and comprises means arranged to direct the process gas downwards, so that said process gas traverses the combustion chamber and then the catalytic zone flowing from top to bottom, and the method comprises at least the following steps:
discontinuing the original distribution means of the oxidation agent,
shortening the gas riser pipe so that the gas outlet end of the gas riser pipe is brought to a lower height in the pressure vessel and closer to the catalytic zone, compared to the original gas riser pipe, and the outlet end of the shortened gas riser pipe is arranged to deliver a gas flow directed upwards; and
installing a new burner on top of the reformer, said new burner being arranged to deliver an oxidation agent with a downward flow, in a mixing zone above the gas outlet end of the shortened gas riser pipe.

2. The method according to claim 1 , wherein said new burner comprises a duct for the oxidation agent which is parallel to the axis of the vertical pressure vessel, thus delivering a substantially axial flow of said oxidation agent.

3. The method according to claim 1 , wherein the gas riser pipe is shortened by removing a top portion of the existing gas riser pipe, or a new gas riser pipe shorter than the original pipe is installed.

4. The method according to claim 1 , wherein an existing piping originally designed for feeding an oxidation agent to said distribution means is modified in order to redirect said oxidation agent to the newly-installed burner.

5. The method according to claim 1 , wherein a top cover of the reformer is modified or replaced in order to allow the installation of the new burner.

6. The method according to claim 1 , wherein said new burner is made of a Ni/Cr/Fe alloy.

7. The method according to claim 1 , wherein said new burner comprises a swirl generator to provide a swirling motion of the oxidation agent.

8. The method according to claim 1 , wherein said oxidation agent is air or enriched air or pure oxygen.

9. The method according to claim 1 , wherein said secondary reformer is part of a front-end of an ammonia plant for the generation of a make-up synthesis gas for the synthesis of ammonia.

10. The method according to claim 1 , wherein said secondary reformer is an autothermal reformer.

Assignees

• Casale Sa

Inventors

• Zanichelli Luca
• Beretti Andrea

Classifications

• B01J8/0257 Primary

  in a cylindrical annular shaped bed · CPC title

• B01J2208/02

  with stationary particles · CPC title

• B01J2219/00024

  Revamping, retrofitting or modernisation of existing plants · CPC title

• Y10T29/49716

  Converting · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title