Process and reactor for producing synthesis gas

Patent metadata

Field	Value
Publication number	US-9561483-B2
Application number	US-201214116596-A
Country	US
Kind code	B2
Filing date	May 7, 2012
Priority date	May 10, 2011
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

For producing synthesis gas by autothermal reformation of gaseous, liquid and/or solid fuels, the fuel is reacted with an oxidizing agent in a reaction space at a pressure of 10 to 120 bar and a reaction space temperature of 800 to 2,000° C. to obtain synthesis gas, wherein the oxidizing agent is introduced centrally in the upper region of the reaction space and wherein a flame is formed in the reaction space. The oxidizing agent is introduced into the reaction space separate from the fuel.

First claim

The invention claimed is:

1. A process for producing synthesis gas by autothermal reformation of gaseous, liquid and/or solid fuels, in which the fuel is reacted with an oxidizing agent in a reaction space at a pressure of 10 to 120 bar and a reaction space temperature of 800 to 2,000° C. to obtain synthesis gas, wherein the oxidizing agent is introduced centrally in the upper region of the reaction space and wherein a flame is formed in the reaction space, wherein the oxidizing agent is introduced into the reaction space separate from the fuel, wherein the fuel is introduced at one or more points into a recirculation zone of the flame, wherein the recirculation zone is defined as the zone wherein the materials present in the flame flow back to the top, and
wherein the fuel is introduced into the recirculation zone along with a moderator such that a spray cone is formed within the recirculation zone.

2. The process according to claim 1 , wherein the fuel is introduced into the recirculation zone of the flame at more than one point.

3. The process according to claim 1 , wherein the oxidizing agent is introduced into the reaction space with a swirl.

4. The process according to claim 1 , wherein the oxidizing agent is introduced into the reaction space along with a moderator.

5. The process according to claim 1 , wherein the fuel is introduced into the reactor in atomized form.

6. The process according to claim 5 , wherein a moderator is used as atomizing medium.

7. The process according to claim 1 , wherein fuel is introduced into the reaction space via several inlets and that different fuels are supplied through the individual fuel inlets.

8. A reactor for producing synthesis gas in a reaction space with an inlet for fuel and an inlet for oxidizing agent, wherein the supply conduit for the oxidizing agent is provided centrally in the upper region of the reaction space, and with an outlet for the synthesis gas, wherein separate supply nozzles are provided for the oxidizing agent and the fuel into the reaction space such that the fuel is introduced at one or more points into a recirculation zone of the flame, wherein the recirculation zone is defined as the zone wherein the materials present in the flame flow back to the top,
wherein the fuel is introduced into the recirculation zone along with a moderator via the fuel supply nozzles, such that a spray cone is formed within the recirculation zone.

9. The reactor according to claim 8 , wherein around the inlet for the oxidizing agent an annular gap is provided for supplying a moderator into the reaction space.

10. The reactor according to claim 8 , wherein a plurality of supply nozzles for the fuel are arranged uniformly distributed around the circumference of the reaction space.

11. The reactor according to claim 10 , wherein the axes (B i ) of the supply nozzles for the fuel intersect on the reaction space axis (R).

12. The reactor according to claim 10 , wherein the axes (B i ) of the supply nozzles for the fuel intersect in a plane which is vertical to the reaction space axis (R).

13. The reactor according to claim 10 , wherein the axes (B i ) of the supply nozzles for the fuel are inclined at an angle of 1 to 180° to the reaction space axis (R).

14. The reactor according to claim 8 , wherein the supply nozzles for the fuel include a spray angle of 10 to 120°.

15. The reactor according to claim 8 , wherein at least in the lower region of the reaction space a catalyst bed is provided.

Assignees

• Mueller-Hagedorn Matthias
• Bartels Katja
• Judas Frederic
• L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
• Lurgi Gmbh

Inventors

• Mueller-Hagedorn Matthias
• Bartels Katja
• Judas Frederic

Classifications

• B01J8/0278

  Feeding reactive fluids (for solid material B01J8/0015) · CPC title

• B01J2208/00504

  by means of a burner · CPC title

• C01B3/363

  characterised by the burner · CPC title

• C10J3/506

  for entrained flow gasifiers · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title