Natural and synthetic ester-containing lubricants having enhanced hydrolytic stability

Patent metadata

Field	Value
Publication number	US-9556394-B2
Application number	US-201214118683-A
Country	US
Kind code	B2
Filing date	Jun 8, 2012
Priority date	Jun 14, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

A lubricant composition comprising (a) from 0.1 to 10 percent by weight of one or more polyalkylene glycols (PAG); and (2) one or more ester base oils selected from the group of natural esters, synthetic esters and combinations thereof; wherein the one or more PAG has a molecular weight in the range 1500 to 5000 g/mole, comprises from 10 to 40 percent by weight of units derived from ethylene oxide and from 90 to 60 percent by weight of units derived from propylene oxide; and wherein the one or more PAGs are in the form of block copolymer, reverse block copolymer or combinations thereof is provided. Also provided is a method of enhancing the hydrolytic stability of an ester base oil.

First claim

We claim:

1. A lubricant composition comprising:
(a) one or more ester base oils selected from the group of natural esters, synthetic esters and combinations thereof; and
(b) from 3 to 8 percent by weight of one or more Diol initiated polyalkylene glycols (PAGs) based on the total weight of the Diol initiated PAG and ester base oil(s); and
wherein the one or more Diol initiated PAGs have a molecular weight in the range 1500 to 5000 g/mole, comprise from 10 to 40 percent by weight of units derived from ethylene oxide and from 90 to 60 percent by weight of units derived from propylene oxide; and
wherein the one or more Diol initiated PAGs are in the form of block copolymer, reverse block copolymer or combinations thereof.

2. The lubricant composition according to claim 1 wherein the one or more ester base oils is one or more natural esters selected from the group consisting of vegetable oils.

3. The lubricant composition according to claim 1 wherein the one or more ester base oils is one or more natural esters selected from the group consisting soy oil, canola oil, and sunflower oil.

4. The lubricant composition according to claim 1 wherein the one or more ester base oils include from greater than 0 to 100 percent by weight of ester derived from a renewable resource.

5. The lubricant composition according to claim 1 wherein the one or more esters is one or more synthetic esters selected from the group consisting of polyol esters and dicarbonic acid esters.

6. The lubricant composition according to claim 1 further comprising one or more selected from the group of antioxidants, anti-wear additives and corrosion inhibitors.

7. The lubricant composition according to claim 6 wherein the antioxidants are selected from the group consisting of phenolic antioxidants, hindered phenolic antioxidants, aromatic amine antioxidants, secondary amine antioxidants, sulfurized phenolic antioxidants, sulfurized olefins, oilsoluble copper compounds, and combinations thereof.

8. The lubricant composition according to claim 6 wherein the corrosion inhibitors are selected from the group consisting of (1) amine salts of an aliphatic phosphoric acid ester; (2) alkenyl succinic acid half esters; (3) amine salts of an alkyl phosphoric acid combined with a dithiophosphoric acid derivative; (4) combinations of barium dinonylnaphthalene sulfonate and dinonylnaphthalene carboxylate in a hydrotreated naphthenic oil; and (5) combinations thereof.

9. The lubricant composition according to claim 6 wherein the anti-wear additives are selected from the group consisting of zinc dialkyldithiophosphates, tricresyl phosphate, didodecyl phosphite, sulfurized sperm oil, sulfurized terpenes, zinc dialkyldithiocarbamate, and combinations thereof.

10. The lubricant composition according to claim 1 wherein the one or more PAGs each have a molecular weight from 1700 to 3300 g/mole.

11. The lubricant composition according to claim 1 wherein the one or more Diol initiated PAGs are present in an amount from 5 to 8 percent by weight.

12. The lubricant composition according to claim 1 wherein the one or more PAGs has an amount of units derived from EO from 20 to 40 percent by weight.

13. A method of enhancing the hydrolytic stability of an ester based lubricant comprising:
(a) providing an ester base oil;
(b) adding to the ester base oil from 3 to 8 percent by weight one or more Diol initiated PAGs based on the total weight of the one or more Diol initiated PAGs and ester base oil; wherein the one or more Diol initiated PAGs have a molecular weight in the range 1500 to 5000 g/mole, comprise from 10 to 40 percent by weight of units derived from ethylene oxide and from 90 to 60 percent by weight of units derived from propylene oxide; and wherein the one or more Diol initiated PAG is in the form of block copolymer, reverse block copolymer or combinations thereof; and
(c) blending the one or more Diol initiated PAGs to form a lubricant composition.

14. The method according to claim 13 further comprising adding one or more additives selected from the group consisting of antioxidants, anti-wear additives and corrosion inhibitors to the lubricant composition.

15. The method according to claim 13 wherein the one or more Diol initiated PAGs are added in an amount from 5 to 8 percent by weight one or more Diol initiated PAGs based on the total weight of the Diol initiated PAG and ester base oil.

Assignees

• Khelidj Nadjet
• Greaves Martin R
• Zaugg-Hoozemans Evelyn A
• Dow Global Technologies Llc

Inventors

• Khelidj Nadjet
• Greaves Martin R
• Zaugg-Hoozemans Evelyn A

Classifications

• C10N2040/08

  Hydraulic fluids, e.g. brake-fluids · CPC title

• C10N2030/66

  Hydrolytic stability · CPC title

• C10M2207/401

  used as base material · CPC title

• C10M2207/301

  used as base material · CPC title

• C10M2209/104

  of alkylene oxides containing two carbon atoms only · CPC title