Selective series-flow hydroprocessing system and method

Patent metadata

Field	Value
Publication number	US-9556388-B2
Application number	US-201213559958-A
Country	US
Kind code	B2
Filing date	Jul 27, 2012
Priority date	Jul 29, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatics-rich and aromatic-lean fractions separately, the hydrocracking operating severity and or catalyst reactor volume requirement decreases.

First claim

What is claimed is:

1. An integrated hydrocracking process for producing cracked hydrocarbons from a feedstock including:
a. separating, in an aromatic extraction zone, the hydrocarbon feed into an aromatic-lean fraction and an aromatic-rich fraction;
b. hydroprocessing the aromatic-rich fraction in a first vessel of a first stage hydroprocessing reaction zone at a reaction pressure in the range from about 130 bar to 200 bar to produce a first vessel first stage hydroprocessing reaction zone effluent;
c. hydroprocessing the aromatic-lean fraction in a second vessel of the first stage hydroprocessing reaction zone at a reaction pressure in the range from about 30 bar to 130 bar to produce a second vessel first stage hydroprocessing reaction zone effluent;
d. hydroprocessing a mixture of first vessel first stage hydroprocessing reaction zone effluent and second vessel first stage hydroprocessing reaction zone effluent in a second stage hydroprocessing reaction zone to produce a second stage hydroprocessing reaction zone effluent; and
e. fractionating the second stage hydroprocessing reaction zone effluent to produce one or more product streams and one or more bottoms streams.

2. The method of claim 1 , wherein the first vessel first stage hydroprocessing reaction zone is operated under relatively severe conditions effective to remove heteroatoms from, and to hydrocrack, at least a portion of aromatic compounds contained in the aromatic-rich fraction.

3. The method of claim 1 , wherein the second vessel first stage hydroprocessing reaction zone is operated under relatively mild conditions effective to remove heteroatoms from, and to hydrocrack, at least a portion of paraffin and naphthene compounds contained in the aromatic-lean fraction.

4. The method of claim 1 , wherein the second stage hydroprocessing reaction zone is operated under relatively mild conditions effective to remove heteroatoms from, and to hydrocrack, at least a portion of paraffin and naphthene compounds contained in the mixture of first vessel first stage hydroprocessing reaction zone effluent and second vessel first stage hydroprocessing reaction zone effluent.

5. The method of claim 1 , wherein the aromatic-rich fraction includes aromatic nitrogen compounds including pyrrole, quinoline, acridine, carbazole and their derivatives.

6. The method of claim 1 , wherein the aromatic-rich fraction includes aromatic sulfur compounds including thiophene, benzothiophenes and their derivatives, and dibenzothiophenes and their derivatives.

7. The method of claim 1 , wherein separating the hydrocarbon feed into an aromatic-lean fraction and an aromatic-rich fraction comprises:
subjecting the hydrocarbon feed and an effective quantity of extraction solvent to the extraction zone to produce
an extract containing a major proportion of the aromatic content of the hydrocarbon feed and a portion of the extraction solvent and
a raffinate containing a major proportion of the non-aromatic content of the hydrocarbon feed and a portion of the extraction solvent;

separating at least substantial portion of the extraction solvent from the raffinate and retaining the aromatic-lean fraction; and
separating at least substantial portion of the extraction solvent from the extract and retaining the aromatic-rich fraction.

8. The process of claim 1 , wherein the second vessel of the first stage hydroprocessing reaction zone is operated at a reaction pressure at or below 100 bar.

Assignees

• Koseoglu Omer Refa
• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa

Classifications

• C10G67/14 Primary

  including at least two different refining steps in the absence of hydrogen · CPC title

• C10G67/0445 Primary

  The hydrotreatment being a hydrocracking · CPC title

• B01J2208/027

  Beds · CPC title

• B01J8/04

  the fluid passing successively through two or more beds · CPC title

• C10G2400/04

  Diesel oil · CPC title