Adsorbent catalytic nanoparticles and methods of using the same

Patent metadata

Field	Value
Publication number	US-9556088-B2
Application number	US-201213691181-A
Country	US
Kind code	B2
Filing date	Nov 30, 2012
Priority date	Nov 30, 2012
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

The present invention provides an adsorbent catalytic nanoparticle including a mesoporous silica nanoparticle having at least one adsorbent functional group bound thereto. The adsorbent catalytic nanoparticle also includes at least one catalytic material. In various embodiments, the present invention provides methods of using and making the adsorbent catalytic nanoparticles. In some examples, the adsorbent catalytic nanoparticles can be used to selectively remove fatty acids from feedstocks for biodiesel, and to hydrotreat the separated fatty acids.

First claim

What is claimed is:

1. An adsorbent catalytic nanoparticle comprising:
at least one adsorbent functional group selected from the group consisting of an amino(C 1 -C 20 )alkyl group or a salt thereof, a (C 1 -C 20 )alkyl carboxylic acid group or a salt thereof, a (C 1 -C 20 )alkyl sulfonic acid group or a salt thereof, and a perfluoro(C 1 -C 20 )alkyl group, wherein the alkyl unit of the aminoalkyl group, the alkyl carboxylic acid group, the alkyl sulfonic acid group, and of the perfluoroalkyl group is covalently bound to the adsorbent catalytic nanoparticle, wherein the adsorbent catalytic nanoparticle is a mesoporous silica nanoparticle, and wherein the (C 1 -C 20 )alkyl groups of the amino(C 1 -C 20 )alkyl group are independently optionally interrupted by one or two —NH— groups; and
at least one catalytic material in pores of the mesoporous silica nanoparticle, the at least one catalytic material comprising nickel, nickel phosphide, elemental iron, rhodium, ruthenium, gold, cobalt, cobalt oxide, palladium, platinum, molybdenum, or a combination thereof.

2. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent functional group adsorbs fatty acids at a higher rate than it adsorbs at least one of fatty acid esters and triglycerides.

3. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent functional group comprises at least one of an amino(C 1-10 )alkyl group and a salt thereof wherein the alkyl unit is covalently bound to the mesoporous silica nanoparticle.

4. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent functional group is present in a concentration of about 0.01 mmol to about 50 mmol per gram of the mesoporous silica nanoparticle.

5. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent catalytic nanoparticle catalyzes decarboxylation and hydrodeoxygenation of a free fatty acid at a higher rate than a mesoporous nanoparticle not having the adsorbent functional group bound thereto.

6. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent catalytic nanoparticle catalyzes cracking of a free fatty acid at a lower rate than a corresponding mesoporous silica nanoparticle not having the adsorbent functional group bound thereto.

7. The adsorbent catalytic nanoparticle of claim 1 , wherein the catalytic material is a hydrotreatment catalyst.

8. The adsorbent catalytic nanoparticle of claim 1 , wherein the adsorbent catalytic nanoparticle comprises about 1 wt % to about 30 wt % of the catalytic material.

9. The adsorbent catalytic nanoparticle of claim 1 , wherein the mesoporous silica nanoparticle is magnetic.

10. The adsorbent catalytic nanoparticle of claim 1 , wherein the mesoporous silica nanoparticle comprises an ordered silicon oxide matrix with hexagonal symmetry.

11. A method comprising:
combining at least one adsorbent catalytic nanoparticle of claim 1 with at least one first molecule that is selectively adsorbed by the adsorbent functional group, to provide a mixture.

12. The method of claim 11 , comprising combining the mixture with a first reagent, under conditions so that the catalytic material in the adsorbent catalytic nanoparticle catalyzes a chemical transformation of the first molecule.

13. The method of claim 11 , wherein combining the adsorbent catalytic nanoparticle with the first molecule comprises combining the adsorbent catalytic nanoparticle with a solution comprising the first molecule, to provide the mixture, wherein the solution further comprises at least one second molecule that is at least one of a) not adsorbed by the adsorbent functional group and b) adsorbed by the adsorbent functional group at a lower rate than the first molecule is adsorbed by the adsorbent functional group.

14. The method of claim 13 , wherein the second molecule is at least one of a fatty acid ester and a triglyceride.

15. The method of claim 11 , wherein the first molecule is a fatty acid.

16. The method of claim 13 , comprising separating the adsorbent catalytic nanoparticle having the first molecule adsorbed thereto from the mixture.

17. The method of claim 16 , comprising combining the separated adsorbent catalytic nanoparticle with a first reagent under conditions so that the catalytic material in the adsorbent catalytic nanoparticle catalyzes a chemical transformation of the first molecule.

18. A method comprising:
combining at least one adsorbent catalytic nanoparticle of claim 1 with a free fatty acid, to provide a mixture; and
combining the mixture with hydrogen gas under conditions so that the catalytic material at least one of cracks, decarboxylates, and hydrodeoxygenates at least some of the free fatty acid.

19. A method comprising:
combining at least one adsorbent catalytic nanoparticle of claim 1 with a solution comprising a free fatty acid and at least one of a fatty acid ester and a triglyceride, to provide a mixture;
separating the adsorbent catalytic nanoparticle having the first molecule adsorbed thereto from the mixture; and
combining the separated adsorbent catalytic nanoparticle with hydrogen gas so that the catalytic material in the adsorbent catalytic nanoparticle catalyzes a chemical transformation of the fatty acid comprising at least one of cracking, decarboxylation, and hydrodeoxygenation.

Assignees

• Univ Iowa State Res Found Inc

Inventors

• Slowing Igor Ivan
• Kandel Kapil

Classifications

• B01J35/45

  Nanoparticles · CPC title

• C10G3/45

  containing iron group metals or compounds thereof · CPC title

• C07C9/22

  with more than fifteen carbon atoms · CPC title

• C07C1/2078

  by a transformation in which at least one -C(=O)-O- moiety is eliminated · CPC title

• B01J29/0308

  Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 · CPC title