Methods for forming an electrodeposited coating over a coated substrate and articles made thereby

Patent metadata

Field	Value
Publication number	US-9556071-B2
Application number	US-75132807-A
Country	US
Kind code	B2
Filing date	May 21, 2007
Priority date	Mar 22, 2004
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

A coated article includes a non-conductive substrate, such as glass. At least one conductive coating is formed over at least a portion of the substrate, such as by chemical vapor deposition or physical vapor deposition. The conductive coating can be a functional coating and can have a thickness in the range of greater than 0 Å to less than 25,000 Å, such as less than 10,000 Å. At least one polymeric coating is electrodeposited over at least a portion of the conductive coating.

First claim

What is claimed is:

1. A method of making a coated article, comprising the steps of:
providing a substrate;
forming at least one conductive coating over at least a portion of the substrate, the conductive coating having a thickness in the range of greater than 0 Å to less than 25,000 Å; and
forming at least one polymeric coating over at least a portion of the conductive coating by an electrodeposition process, wherein the polymeric coating comprises a cationic acrylic urethane, and wherein the conductive coating functions as an electrode in the electrodeposition process,
wherein said conductive coating comprises a first dielectric layer, and a first metal layer, said first dielectric layer being interposed between said substrate and said first metal layer,
said first dielectric layer comprising a first metal alloy oxide film and a second metal oxide film, said first metal alloy oxide film being interposed between said substrate and said second metal oxide film,
said first metal alloy oxide film and said second metal oxide film independently selected from the group consisting of oxides of titanium, hafnium, zirconium, niobium, zinc, bismuth, lead, indium, tin, zinc/tin alloy, and combinations thereof, and
said coated article is free of a resinous primer.

2. The method of claim 1 , wherein the substrate is made of a non-conductive material.

3. The method of claim 1 , wherein the substrate is selected from glass and plastic.

4. The method of claim 1 , wherein the substrate is tempered or annealed glass.

5. The method of claim 1 , wherein the substrate is a bent substrate.

6. The method of claim 1 , wherein the substrate is a bent substrate and the method includes:
forming the conductive coating over at least a portion of the bent substrate; and
forming the polymeric coating over at least a portion of the conductive coating.

7. The method of claim 1 , including:
bending the substrate to a desired shape after formation of the conductive coating; and
forming the polymeric coating over the conductive coating on the bent substrate.

8. The method of claim 1 , wherein the conductive coating has a sheet resistance in the range of greater than 0 ohm/square to 1,000 ohms/square.

9. The method of claim 1 , wherein the conductive coating has a sheet resistance in the range of greater than 0 ohm/square to 30 ohms/square.

10. The method of claim 1 , wherein the conductive coating has a sheet resistance in the range of greater than 0 ohm/square to 15 ohms/square.

11. The method of claim 1 , wherein said first metal layer is at least one of heat reflective and radiation reflective.

12. The method of claim 11 , wherein the first metal layer includes silver.

13. The method of claim 1 , including depositing the conductive coating by a process selected from chemical vapor deposition or physical vapor deposition.

14. The method of claim 13 , including depositing the conductive coating by magnetron sputter vapor deposition.

15. The method of claim 1 , wherein the polymeric coating has a thickness in the range of 0.2 mils to 1.5 mils.

16. The method of claim 1 , including laminating another substrate to the article using the polymeric coating.

17. The method of claim 1 , wherein the substrate is non-conductive and the method includes electrically charging the conductive coating to electrodeposit the polymeric coating.

18. The method of claim 1 , further including:
deleting at least a portion of the conductive coating to form a plurality of conductive coating regions; and
selectively electrically charging one or more of the coating regions to selectively electrocoat the charged coating regions.

19. The method of claim 18 , wherein the deleting step includes at least one of masking, laser deletion, mechanical deletion, chemical deletion, or solvent deletion.

20. The method of claim 1 , wherein said conductive coating further comprises a primer layer and a second dielectric layer, said primer layer being interposed between said first metal layer and said second dielectric layer.

21. The method of claim 20 , wherein said second dielectric layer comprises a third metal oxide layer, a fourth metal alloy oxide layer, and a fifth metal oxide layer, said third metal oxide layer being interposed between said primer layer and said fourth metal alloy oxide layer, and said fourth metal alloy oxide layer being interposed between said third metal oxide layer and said fifth metal oxide layer.

22. The method of claim 21 , wherein said third metal oxide layer comprises zinc oxide, said fourth metal alloy oxide layer comprises zinc stannate, and said fifth metal oxide layer comprises zinc oxide.

23. The method of claim 1 , wherein said first metal alloy oxide film of said first dielectric layer comprises zinc stannate, and said second metal oxide film of said first dielectric layer comprises zinc oxide.

24. A method of making a coated article, comprising the steps of:
providing a substrate having at least one conductive coating formed over at least a portion of the substrate, the conductive coating having a thickness in the range of greater than 0 Å to less than 25,000 Å; and
forming at least one polymeric coating over at least a portion of the conductive coating by an electrodeposition process, wherein the polymeric coating comprises a cationic acrylic urethane, and wherein the conductive coating functions as an electrode in the electrodeposition process,
wherein said conductive coating comprises a first dielectric layer, and a first metal layer, said first dielectric layer being interposed between said substrate and said first metal layer,
said first dielectric layer comprising a first metal alloy oxide film and a second metal oxide film, said first metal alloy oxide film being interposed between said substrate and said second metal oxide film, and
said first metal alloy oxide film and said second metal oxide film independently selected from the group consisting of oxides of titanium, hafnium, zirconium, niobium, zinc, bismuth, lead, indium, tin, zinc/tin alloy, and combinations thereof, and
said coated article is free of a resinous primer.

25. The method of claim 24 , wherein the substrate comprises glass.

26. The method of claim 24 , wherein the at least one conductive coating is formed by a process selected from chemical vapor deposition or physical vapor deposition.

27. The method of claim 26 , including depositing the conductive coating by magnetron sputter vapor deposition.

28. A method of making a coated article, comprising the steps of:
providing a substrate having a plurality of conductive coating regions; and
selectively depositing one or more electrodepositable coating materials over the conductive coating regions by an electrodeposition process,
wherein each conductive coating region comprises a conductive coating comprising a first dielectric layer, and a first metal layer, said first dielectric layer being interposed between said substrate and said first metal layer,
said first dielectric layer comprising a first metal alloy oxide film and a second metal oxide film, said first metal alloy oxide film being interposed between said substrate and said second metal oxide film, and
said first metal alloy oxide film and said second metal oxide film independently selected from the group consisting of oxides of titanium, hafnium, zirconium, niobium, zinc, bismuth, lea

Assignees

• Finley James J
• Boyd Donald W
• Marietti Gary J
• Vitro Sab De Cv

Inventors

• Finley James J
• Boyd Donald W
• Marietti Gary J

Classifications

• C03C2218/156

  by magnetron sputtering · CPC title

• Y10T428/12007

  Component of composite having metal continuous phase interengaged with nonmetal continuous phase · CPC title

• C03C2218/115

  electro-enhanced deposition · CPC title

• C03C17/42 Primary

  at least one coating of an organic material and at least one non-metal coating · CPC title

• C25D13/20

  Pretreatment · CPC title