Treating hard water using an acid salt-regenerated ion exchange resin

Patent metadata

Field	Value
Publication number	US-9556043-B2
Application number	US-201313802870-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Dec 13, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

Methods and systems for acid regeneration of ion exchange resins are disclosed. Acid resins designed for use in a variety of cleaning application using a water source use a treated, softened, acidic water source according to the invention. Various methods of using the softened acidic water generated by acid regenerate-able ion exchange resins are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

First claim

What is claimed:

1. A method for treating hard water using an acid salt regenerated ion exchange resin comprising:
contacting a hard water source with a water treatment composition in a service cycle,
wherein the water treatment composition comprises at least one ion exchange resin,
wherein the ion exchange resin generates a treated water source by exchanging protons on said resin for dissolved cations including water hardness ions and total dissolved solids in said hard water source, and wherein said ion exchange resin is regenerated using an acid salt regenerant;

generating the treated water source having a specific water specification, wherein the water specification is a hardness level of less than about 2 grains per gallon, a TDS less than about 300 ppm, and a pH less than about 6, wherein the treated water source is used for washing and/or rinsing in a variety of cleaning applications;
measuring pH and/or proton concentration and/or total dissolved solids within the water treatment composition, water source and/or treated water source, and
triggering an event as a result of the obtained measurement,
wherein the triggered event is selected from the group consisting of regenerating the resin of the water treatment component, varying a detergent or other chemistry addition to the treated water source and combinations thereof.

2. The method according to claim 1 , wherein said ion exchange resin is a weak acid cation exchange resin selected from the group consisting of a cross-linked polyacrylic with carboxylic acid functional group, a cross-linked polymethacrylic with carboxylic acid functional group and mixtures of thereof, and/or a strong acid cation exchange resin selected from the group consisting of a polystyrene with sulfonic acid functional group, a polystyrene with sulfonic acid functional group and mixtures of thereof.

3. The method according to claim 2 , wherein said ion exchange resin is a layered bed system employing at least two of said cation exchange resins.

4. The method according to claim 1 , wherein a pH and/or proton concentration measurement is obtained from said treated water source.

5. The method according to claim 1 , wherein a differential pH and/or proton concentration measurement is obtained from said water source and said treated water source.

6. The method according to claim 1 , wherein the regeneration of the resin comprises providing said acid salt regenerant to the resin, displacing water hardness ions on the resin with protons from the acid regenerant, and generating a regeneration step effluent water.

7. The method of claim 1 , wherein said regenerant is a combination of from about 10 wt-% to about 50 wt-% urea sulfate and from about 50 wt-% to about 90 wt-% alkali metal salt, or is a regenerant selected from the group consisting of sodium chloride, urea sulfate, urea, sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, citric acid, acetic acid, methane sulfonic acid and a combination thereof.

Assignees

• Ecolab Usa Inc

Inventors

• Everson Terrence P
• Wen Li
• Tan Lylien
• Voss Peter
• Toetschinger Mark

Classifications

• B08B3/14

  Removing waste, e.g. labels, from cleaning liquid · CPC title

• B01J39/20

  obtained by reactions only involving unsaturated carbon-to-carbon bonds · CPC title

• B01J39/05

  in the strongly acidic form · CPC title

• B01J39/07

  in the weakly acidic form · CPC title

• B01J49/06

  containing cationic exchangers · CPC title