Process for producing articles formed from polylactic acid and articles made therefrom
US-9732184-B2 · Aug 15, 2017 · US
US9555564B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9555564-B2 |
| Application number | US-201314076438-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 11, 2013 |
| Priority date | Nov 11, 2013 |
| Publication date | Jan 31, 2017 |
| Grant date | Jan 31, 2017 |
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A method of fabricating a foamed, injection-molded component is provided. The method includes the step of plasticizing pellets including a first polymeric material and a second polymeric material within an injection barrel to form an injection material. The first polymeric material defines a first phase of the injection material and the second polymeric material defines a second phase of the injection material. The first and second phases of the injection material are immiscible. The injection material is injected into a mold to fabricate the foamed injection-molded component having microscale, microcellular voids. Upon tensile loading, submicron, secondary phase cavities are formed in the injection-molded component, resulting in improved ductility and toughness.
Opening claim text (preview).
We claim: 1. A method of fabricating an injection-molded component, comprising the steps of: introducing pellets and a supercritical fluid into an injection barrel of an injection molding machine, the pellets including a first polymeric material and a second polymeric material; plasticizing the pellets within the injection barrel to form an injection material, the first polymeric material defining a first phase of the injection material and the second polymeric material defining a second phase of the injection material; injecting the injection material into a mold to fabricate the injection-molded component; and forming microcellular voids having diameters in the injected-molded component; wherein secondary phase cavities having diameters are formed in the injected-molded component in response to the tensile loading of the injected-molded component, the diameters of the microcellular voids being greater than the diameters of the secondary phase cavities. 2. The method of claim 1 wherein the microcellular voids have diameters greater than 10 micrometers. 3. The method of claim 2 wherein the secondary phase cavities have diameters less than 1 micrometer. 4. The method of claim 2 wherein the microcellular voids have diameters in the range of 50 to 100 micrometers. 5. The method of claim 1 wherein the first phase and the second phase are immiscible. 6. The method of claim 1 comprising the additional steps of: heating the first and second polymeric materials and the supercritical fluid to produce a melt; extruding the melt; and forming the pellets from the extruded melt. 7. The method of claim 1 wherein the supercritical fluid is introduced into the injection barrel downstream of the pellets. 8. The method of claim 1 wherein the first polymeric material is polypropylene (PP) and the second polymeric material is high-density polyethylene (HDPE). 9. The method of claim 1 wherein the injection material includes at least 50% of the first polymeric material and less than 50% of the second polymeric material. 10. The method of claim wherein the first polymeric material is in the range of 60% to 85% of the injection material. 11. A method of fabricating a foamed, injection-molded component, comprising the steps of: plasticizing a first polymeric material and a second polymeric material within an injection barrel to form an injection material, the first polymeric material defining a first phase of the injection material and the second polymeric material defining a second phase of the injection material; injecting the injection material into a mold to fabricate the foamed, injection-molded component; forming microcellular voids having diameters in the injected-molded component; subjecting the injected-molded component to tensile loading; and forming secondary phase cavities having diameters in the injected-molded component in response to the tensile loading of the injected-molded component, the diameters of the microcellular voids being greater than the diameters of the secondary phase cavities; wherein the first phase and the second phase of the injection material are immiscible. 12. The method of claim 11 wherein the microcellular voids have diameters greater than 10 micrometers. 13. The method of claim 12 wherein the secondary phase cavities have diameters less than 1 micrometer. 14. The method of claim 13 wherein the microcellular voids have diameters in the range of 50 to 100 micrometers. 15. The method of claim 11 comprising the additional steps of: heating the first and second polymeric materials and a supercritical fluid to produce a melt; extruding the melt; forming pellets from the extruded melt; and introducing the pellets into the injection barrel. 16. The method of claim 15 wherein a supercritical fluid is introduced into the injection barrel downstream of the pellets. 17. The method of claim 11 wherein the first polymeric material is polypropylene (PP) and the second polymeric material is high-density polyethylene (HDPE). 18. The method of claim 11 wherein the injection material includes at least 50% of the first polymeric material and less than 50% of the second polymeric material. 19. The method of claim 18 wherein the first polymeric material is in the range of 60% to 85% of the injection material. 20. A method of fabricating a foamed, injection-molded component, comprising the steps of: plasticizing a first polymeric material and a second polymeric material within an injection barrel to form an injection material; and injecting the injection material into a mold to fabricate the foamed injection-molded component, the foamed injection-molded component including microcellular voids having diameters; wherein: secondary phase cavities having diameters are formed in the injected-molded component in response to tensile loading of the injection molded component; and the diameters of the microcellular voids are greater than the diameters of the secondary phase cavities. 21. The method of claim 20 wherein the microcellular voids have diameters greater than 10 micrometers. 22. The method of claim 21 wherein the secondary phase cavities have diameters less than 1 micrometer. 23. The method of claim 21 wherein the microcellular voids have diameters in the range of 50 to 100 micrometers. 24. The method of claim 20 wherein the first polymeric material defines a first phase of the injection material and the second polymeric material defines a second phase of the injection material, the first and second phases of the injection material being immiscible. 25. The method of claim 20 wherein the first polymeric material is polypropylene (PP) and the second polymeric material is high-density polyethylene (HDPE). 26. The method of claim 20 wherein the injection material includes at least 50% of the first polymeric material and less than 50% of the second polymeric material. 27. The method of claim 26 wherein the first polymeric material is in the range of 60% to 85% of the injection material.
PP, i.e. polypropylene · CPC title
by regulating the temperature and/or the pressure, e.g. suppression of foaming until the pressure is rapidly decreased · CPC title
by using a heated or cooled preformed part, e.g. in the mould · CPC title
through the screw · CPC title
for articles of definite length, i.e. discrete articles · CPC title
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