Rechargeable lithium battery

Patent metadata

Field	Value
Publication number	US-9553293-B2
Application number	US-201414327297-A
Country	US
Kind code	B2
Filing date	Jul 9, 2014
Priority date	Aug 14, 2013
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

A rechargeable lithium battery includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode. The separator includes a substrate having a first side facing the negative electrode and a second side facing the positive electrode. A first layer is positioned on the first side of the substrate and includes an organic material, and a second layer is positioned on the second side of the substrate and includes an inorganic material.

First claim

What is claimed is:

1. A rechargeable lithium battery comprising
a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode,
wherein the separator comprises:
a substrate comprising a first side facing the negative electrode and a second side facing the positive electrode;
a first layer on the first side of the substrate and comprising an organic material; and
a second layer on the second side of the substrate and comprising an inorganic material.

2. The rechargeable lithium battery of claim 1 , wherein the separator further comprises a third layer between the substrate and the first layer, each of the second layer and the third layer comprising the inorganic material.

3. The rechargeable lithium battery of claim 1 , wherein the separator further comprises a fourth layer between the substrate and the second layer, each of the first layer and the fourth layer comprising the organic material.

4. The rechargeable lithium battery of claim 1 , wherein the separator further comprises:
a fifth layer between the substrate and the first layer, each of the second layer and the fifth layer comprising the inorganic material; and
a sixth layer between the substrate and the second layer, each of the first layer and the sixth layer comprising the organic material.

5. The rechargeable lithium battery of claim 1 , wherein the substrate comprises a plurality of pores, and
wherein an average pore size of the plurality of pores is about 0.01 μm to about 1 μm, and
a porosity of the substrate is about 30 volume % to about 60 volume %.

6. The rechargeable lithium battery of claim 1 , wherein a thickness of the substrate is about 6 μm to about 25 μm.

7. The rechargeable lithium battery of claim 1 , wherein the organic material comprises a polymer having a melting point of about 85° C. to about 130° C.

8. The rechargeable lithium battery of claim 7 , wherein a weight average molecular weight of the polymer is about 300 g/mol to about 10,000 g/mol.

9. The rechargeable lithium battery of claim 7 , wherein a size of the polymer particle is about 100 nm to about 5 μm.

10. The rechargeable lithium battery of claim 1 , wherein a melting point of the organic material is lower than a melting point of the substrate.

11. The rechargeable lithium battery of claim 1 , wherein the organic material is present in an amount of about 1 part by weight to about 80 parts by weight based on 100 parts by weight of the substrate.

12. The rechargeable lithium battery of claim 1 , the separator further comprising a fourth layer between the substrate and the second layer and/or a sixth layer between the substrate and the second layer, each of the first layer, the fourth layer and the sixth layer comprising the organic material, wherein a thickness of each of the first layer, the fourth layer, and the sixth layer is about 1 μm to about 10 μm.

13. The rechargeable lithium battery of claim 12 , wherein the first layer, the fourth layer, and the sixth layer each further comprises a binder comprising a material different from the organic material.

14. The rechargeable lithium battery of claim 13 , wherein the binder comprises a styrene-butadiene rubber (SBR), carboxymethyl cellulose (CMC), polyvinylidene fluoride (PVdF), a polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) copolymer, ethylene vinylacetate (EVA), hydroxyethyl cellulose (HEC), polyvinyl alcohol (PVA), polyvinylbutyral (PVB), an ethylene-acrylic acid copolymer, acrylonitrile, a vinyl acetate derivative, polyethylene glycol, an acryl-based rubber, or a combination thereof.

15. The rechargeable lithium battery of claim 1 wherein the inorganic material comprises silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), aluminum hydroxide (Al(OH) 3 ), aluminum oxyhydroxide AlO(OH), titanium dioxide (TiO 2 ), barium titanate(IV) BaTiO 3 , zinc dioxide ZnO 2 , magnesium hydroxide (Mg(OH) 2 ), magnesium oxide (MgO), titanium hydroxide (Ti(OH) 4 ), aluminum nitride (AIN), silicon carbide (SiC), boron nitride (BN), or a combination thereof.

16. The rechargeable lithium battery of claim 1 , wherein the inorganic material has a particle size of about 0.1 μm to about 5 μm.

17. The rechargeable lithium battery of claim 1 , wherein the inorganic material is present in an amount of about 20 parts by weight to about 200 parts by weight based on 100 parts by weight of the substrate.

18. The rechargeable lithium battery of claim 1 the separator further comprising a third layer between the substrate and the first layer, and/or a fifth layer between the substrate and the first layer, each of the second layer, the third layer, and the fifth layer comprising the inorganic material, wherein a thickness of each of the second layer, the third layer, and the fifth layer is about 0.5 μm to about 7 μm.

19. The rechargeable lithium battery of claim 18 , wherein the second layer, the third layer, and the fifth layer each further comprises a binder.

20. The rechargeable lithium battery of claim 19 , wherein the binder comprises a styrene-butadiene rubber (SBR), carboxymethyl cellulose (CMC), polyvinylidene fluoride (PVdF), a polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) copolymer, ethylene vinylacetate (EVA), hydroxyethyl cellulose (HEC), polyvinyl alcohol (PVA), polyvinylbutyral (PVB), an ethylene-acrylic acid copolymer, acrylonitrile, a vinyl acetate derivative, polyethylene glycol, an acryl-based rubber, or a combination thereof.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Nam Jung-Hyun
• Park Jong-Hwan
• Choi Yeon-Joo
• Lee Eon-Mi
• Seok Hoon

Classifications

• H01M50/431 Primary

  Inorganic material · CPC title

• H01M50/457

  comprising three or more layers · CPC title

• H01M50/451

  comprising layers of only organic material and layers containing inorganic material · CPC title

• H01M50/489

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/491

  Porosity · CPC title