Magnetic resonance examination of porous samples

Patent metadata

Field	Value
Publication number	US-9551769-B2
Application number	US-201313971515-A
Country	US
Kind code	B2
Filing date	Aug 20, 2013
Priority date	Aug 23, 2012
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

A method of analyzing properties of a porous sample, typically a cylinder of porous rock, comprises centrifuging the sample while it contains at least one liquid, determining the distribution of at least one liquid in the sample by magnetic resonance imaging of the sample, and also determining the distribution of at least one magnetic resonance parameter, where the parameter is one of longitudinal relaxation time T 1 , transverse relaxation time T 2 and diffusion coefficient D. Pore throat sizes can be determined from the distribution of at least one liquid in the sample and pore body sizes can be determined from the distribution of the magnetic resonance parameter enabling determination of a relationship between pore throat sizes and pore body sizes in the sample. This can be a relationship between individual values of pore throat size and an average of body sizes of pores having that individual pore throat size.

First claim

The invention claimed is:

1. A method of analysing properties of a porous sample, comprising:
centrifuging the sample while it contains at least one liquid,
determining a distribution of at least one liquid in the sample, relative to the direction of centripetal acceleration by the centrifuge, by magnetic resonance imaging of the sample,
determining a distribution of at least one magnetic resonance parameter, relative to the direction of centripetal acceleration by the centrifuge, where the parameter is one of longitudinal relaxation time T 1 , transverse relaxation time T 2 and diffusion coefficient D;
distinguishing a portion of the porosity of the sample by a range of values of said at least one magnetic resonance parameter; and
determining the distribution of said at least one liquid relative to the direction of centripetal acceleration by the centrifuge, in the said portion of the porosity of the sample.

2. A method according to claim 1 further comprising determining a capillary pressure curve from the distribution of at least one liquid in the sample.

3. A method according to claim 1 further comprising determining a capillary pressure curve from the distribution of at least one liquid in the said portion of the porosity of the sample.

4. A method according to claim 1 wherein the magnetic resonance parameter is transverse relaxation time T 2 .

5. A method according to claim 4 wherein determining the distribution of transverse relaxation time T 2 is done by means of a frequency encoded method comprising:
placing the sample in a magnetic field;
applying a 90° radiofrequency pulse to the sample;
superimposing a magnetic field gradient on the magnetic field;
observing echo signals by a sequence of removing the superimposed magnetic field gradient, applying a 180° refocusing pulse, then again superimposing a magnetic field gradient on the magnetic field and observing the radiofrequency emitted from the sample over a range of frequencies while the magnetic field gradient is applied;
repeating the said sequence multiple times; and
calculating values correlating radiofrequency signal strength with T 2 at positions distributed within the sample.

6. A method according to claim 1 wherein centrifuging causes expulsion of said one liquid and replacement of the expelled liquid with gas.

7. A method according to claim 1 wherein centrifuging causes expulsion of one liquid and imbibition of another liquid, wherein one of the liquids is hydrocarbon and the other of them is an aqueous solution.

8. A method according to claim 7 wherein the aqueous solution contains paramagnetic cations.

9. A method according to claim 7 comprising determining a distribution of one of the two liquids relative to the direction of centripetal acceleration by the centrifuge.

10. A method according to claim 1 wherein said at least one magnetic resonance parameter comprises both the parameter of longitudinal relaxation time T 1 and the parameter of transverse relaxation time T 2 .

11. A method according to claim 1 wherein said at least one magnetic resonance parameter comprises both the parameter of transverse relaxation time T 2 and the parameter of diffusion coefficient D.

12. A method of analysing properties of a porous sample, comprising:
centrifuging the sample while it contains at least one liquid;
determining a distribution of at least one liquid in the sample, relative to the direction of centripetal acceleration by the centrifuge, by magnetic resonance imaging of the sample;
determining pore throat sizes from the distribution of at least one liquid in the sample;
determining a distribution of at least one magnetic resonance parameter, relative to the direction of centripetal acceleration by the centrifuge, where the parameter is one of longitudinal relaxation time T 1 , transverse relaxation time T 2 and diffusion coefficient D;
determining pore body sizes from the distribution of the magnetic resonance parameter; and
determining relationship between pore throat sizes and pore body sizes in the sample.

13. A method according to claim 12 wherein the relationship is between individual values of pore throat size and an average of body sizes of pores having pore throat sizes no greater than the said individual value of throat size.

14. A method according to claim 12 wherein the relationship is between individual values of pore throat size and an average of body sizes of pores having the said individual pore throat size.

15. A method of analysing properties of a porous sample, comprising:
centrifuging the sample while it contains at least one liquid,
determining a distribution of at least one liquid in the sample, relative to the direction of centripetal acceleration by the centrifuge, by magnetic resonance imaging of the sample,
determining a distribution of transverse relaxation time T 2 relative to the direction of centripetal acceleration by the centrifuge.

16. A method according to claim 15 wherein determining the distribution of transverse relaxation time T 2 is done by means of a frequency encoded method comprising:
placing the sample in a magnetic field;
applying a 90° radiofrequency pulse to the sample;
superimposing a magnetic field gradient on the magnetic field;
observing echo signals by a sequence of removing the superimposed magnetic field gradient, applying a 180° refocusing pulse, then again superimposing a magnetic field gradient on the magnetic field and observing the radiofrequency emitted from the sample over a range of frequencies while the magnetic field gradient is applied;
repeating the said sequence multiple times; and
calculating values correlating radiofrequency signal strength with T 2 at positions distributed within the sample.

17. A method according to claim 15 which also comprises determining the distribution of diffusion coefficient D relative to the direction of centripetal acceleration by the centrifuge.

Assignees

• Schlumberger Technology Corp

Inventors

• Fordham Edmund J
• Mitchell Jonathan

Classifications

• G01R33/50

  based on the determination of relaxation times {, e.g. T1 measurement by IR sequences; T2 measurement by multiple-echo sequences} · CPC title

• G01N15/08

  Investigating permeability, pore-volume, or surface area of porous materials · CPC title

• G01R33/4818 Primary

  MR characterised by data acquisition along a specific k-space trajectory or by the temporal order of k-space coverage, e.g. centric or segmented coverage of k-space · CPC title

• G01R33/56341

  Diffusion imaging · CPC title

• G01N24/081 Primary

  Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity · CPC title