Multiple stage curable polymer with controlled transitions

Patent metadata

Field	Value
Publication number	US-9550845-B2
Application number	US-201514626327-A
Country	US
Kind code	B2
Filing date	Feb 19, 2015
Priority date	Apr 8, 2014
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

The invention provides a polymer system, including a first composition and a second composition. The first composition is different from the second composition. The first composition includes a first gelator, the first gelator including a plurality of acylhydrazine moieties. The second composition includes a second gelator, the second gelator including a plurality of formyl moieties. At least one of the first composition and the second composition includes a prepolymer. The invention further provides a method of using the polymer system to form a polymeric material via multiple stages to more effectively control the rheology of the components over a variety of timescales.

First claim

What is claimed is:

1. A polymer-formation system comprising a first composition and a second composition separated from one another, wherein the first composition is different from the second composition, and the first and second compositions are stable in isolation from each other, but react in the presence of each other; wherein
the first composition comprises a first gelator and the first gelator comprises a plurality of acylhydrazine moieties;
the second composition comprises a second gelator and the second gelator comprises a plurality of formyl moieties;
at least one of the first composition and the second composition comprises a prepolymer;
one of the first composition and the second composition comprises a gelation catalyst; and
when combined, the first composition and the second composition react with one another, resulting in the formation of a gel prior to polymerization that results in a solid polymer.

2. The polymer-formation system of claim 1 wherein one of the first and second compositions comprises a polymerization promoter, and the other of the first and second compositions comprises a polymerization initiator.

3. The polymer-formation system of claim 1 wherein the first gelator comprises at least two acylhydrazine moieties, and the second gelator comprises at least three formyl moieties.

4. The polymer-formation system of claim 3 wherein a gelator is present in both the first and second compositions.

5. The polymer-formation system of claim 3 wherein the first gelator comprises bis-acylhydrazine terminated poly(ethylene)glycol.

6. The polymer-formation system of claim 3 wherein the second gelator comprises tris[(4-formylphenoxy) methyl]ethane.

7. The polymer-formation system of claim 3 wherein:
the first gelator comprises bis-acylhydrazine terminated poly(ethylene) glycol;
the second gelator comprises tris[(4-formylphenoxy) methyl]ethane;
the prepolymer comprises 2-hydroxyethyl methacrylate (HEMA) or a combination of trimethylolpropane tris(3-mercaptopropionate) (TMPTMP) and 1,3-glyceryl dimethacrylate (GDMA); and
the system optionally further comprises a polymerization initiator, a polymerization promoter, a polymerization inhibitor, or a combination thereof.

8. The polymer-formation system of claim 1 wherein the prepolymer is an alkyl acrylate, a thiol-ene, or a combination thereof.

9. The polymer-formation system of claim 8 wherein the alkyl acrylate is a monomer precursor selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-hydroxyethyl methacrylate (HEMA), and 1,3-glyceryl dimethylacrylate (GDMA), and if present, the thiol-ene is a monomer precursor selected from the group consisting of trimethylpropane tris(3-mercaptopropionate) (TMPTMP), triallyl-1,3,5-triazine-2,4,6-trione (TATATO), pentaerythritol tetra(3-mercaptopropionate) (PETM), 1,2-ethylene glycol bis(3-mercaptopropionate), ethylene glycol bis(thioglycolate), trimethylolpropane tris(3-mercaptopropanoate), pentaerythritol (3-mercaptopropionate), trimethylolpropane tris(thioglycolate), and tris[2-(3-mercaptopropionyloxy)ethyl] isocyanurate.

10. The polymer-formation system of claim 1 wherein the first composition and the second composition, upon contacting each other, first form a gel, followed by a polymerization product within 24 hours, wherein the two transitions occur at ambient temperature.

11. The polymer-formation system of claim 1 wherein the system is a self-healing system.

12. A device for forming a polymer system, the device comprising a first vessel and a second vessel wherein:
the first vessel contains a first composition, and the second vessel contains a second composition, where the first composition is different from the second composition, and the first and second compositions are stable in isolation from each other, but react in the presence of each other;
the first composition comprises a first gelator, the first gelator comprising a plurality of acylhydrazine moieties;
the second composition comprises a second gelator, the second gelator comprising a plurality of formyl moieties;
at least one of the first composition and the second composition comprises a prepolymer;
one of the first composition and the second composition comprises a gelation catalyst;
the first composition or the second composition optionally further comprises a polymerization initiator, a polymerization promoter, a polymerization inhibitor, or a combination thereof; and
when combined, the first composition and the second composition react with one another, resulting in the formation of a gel prior to polymerization that results in a solid polymer.

13. The device of claim 12 wherein the first gelator comprises at least two acylhydrazine moieties and the second gelator comprises at least three formyl moieties.

14. The device of claim 13 wherein the first gelator comprises bis-acylhydrazine terminated poly(ethylene) glycol.

15. The device of claim 13 wherein the second gelator comprises tris[(4-formylphenoxy) methyl]ethane.

16. A method of forming a solid polymeric material, comprising:
providing a first composition and a second composition separated from one another, wherein the first composition is different from the second composition;
the first composition is a liquid and comprises a first gelator, the first gelator comprising a plurality of acylhydrazine moieties;
the second composition is a liquid and comprises a second gelator, the second gelator comprising a plurality of formyl moieties;
at least one of the first composition and the second composition comprises a prepolymer;
one of the first composition and the second composition comprises a gelation catalyst;
the first composition or the second composition optionally further comprises a gelation catalyst, a polymerization initiator, a polymerization promoter, a polymerization inhibitor, or a combination thereof; and
triggering the combination of the first composition and the second composition to initiate a dual-stage reaction of the components, the liquid reactants sequentially transitioning first to a gel, and second to a polymer, to form the solid polymeric material.

17. The method of claim 16 wherein the first gelator comprises at least two acylhydrazine moieties and the second gelator comprises at least three formyl moieties.

18. The method of claim 17 wherein the first gelator comprises bis-acylhydrazine terminated poly(ethylene) glycol and the second gelator comprises tris[(4-formylphenoxy)methyl]ethane.

19. The method of claim 16 wherein the prepolymer forms a thermoplastic or thermoset polymer.

20. The method of claim 16 wherein the polymeric material comprises a first polymer and a second polymer, wherein the first polymer comprises a polymer of Formula I:

wherein is an additional moiety as shown within the brackets of Formula I;
R is

 and
R′ is

 wherein n is about 3 to about 150; and
the second polymer comprises a polymer of Formula II:

 wherein n is about

Assignees

• Univ Illinois

Inventors

• White Scott
• Sottos Nancy
• Moore Jeffrey
• Gergely Ryan
• Krull Brett
• Santa Cruz Windy Ann

Classifications

• C08G63/6884

  derived from polycarboxylic acids and polyhydroxy compounds · CPC title

• C08G63/688

  containing sulfur · CPC title

• C08F120/28 Primary

  containing no aromatic rings in the alcohol moiety · CPC title

• C08F222/10

  Esters · CPC title

• C08L79/06

  Polyhydrazides; Polytriazoles; Polyamino-triazoles; Polyoxadiazoles · CPC title