Process for the production of storage-stable epoxy prepregs, and composites produced therefrom, based on epoxides and acids amenable to free-radical polymerisation

Patent metadata

Field	Value
Publication number	US-9550313-B2
Application number	US-201514685162-A
Country	US
Kind code	B2
Filing date	Apr 13, 2015
Priority date	Apr 25, 2014
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

A process for the production of storage-stable epoxy prepregs is provided. In addition, composites produced from the prepregs based on epoxides and acids having groups reactive to free-radical polymerization is provided.

First claim

The invention claimed is:

1. A process for the production of a composite, comprising:
I) preparing a reactive composition comprising:
A) at least one reactive resin component which has at least one acid group, and
B) at least one epoxy-based reactive resin component,
wherein

one or both of components A) and B) comprises a group capable of free-radical polymerisation, and
for each acid group of component A) there are from 03 to 3.0 epoxy groups of component B);
II) directly impregnating a fibrous substrate with the reactive composition prepared in I);
III) polymerizing the components capable of free-radical polymerisation in the impregnated substrate thermally or with electromagnetic radiation, activatable free-radical initiators, electromagnetic radiation, electron beams, or a plasma, to obtain a prepreg;
IV) shaping the prepreg to obtain a moulding; and
V) hardening of the epoxy components in the moulding to obtain the composite.

2. The process for the production of a composite according to claim 1 , wherein the reactive composition further comprises at least one component selected from the group consisting of:
C) at least one initiator selected from at least one thermal free-radical initiator and/or one photoinitiator,
D) other acids or epoxides without groups reactive in free-radical polymerisation,
E) other components reactive in free-radical polymerisation without acid groups or epoxy groups, and
F) other auxiliaries and additives.

3. The process for the production of a composite according to claim 2 , wherein the reactive composition further comprises component D), and at least one of B) and D) comprise an epoxy compound not having a group reactive to free-radical polymerisation selected from a diglycidyl ether based on bisphenol A and/or bisphenol F with epoxy equivalent weight of from 180 to 190 g/mol.

4. The process for the production of a composite according to claim 2 , wherein the reactive composition further comprises component D), and resin components A) and/or D) comprise a compound not having a group capable of free-radical polymerisation selected from the group consisting of a monomeric carboxylic acid, an oligomeric carboxylic acid and a polymeric carboxylic acid.

5. The process for the production of a composite according to claim 4 , wherein resin components A) and/or D) comprise at least one acid selected from the group consisting of succinic acid, adipic acid, suberic acid, azelaic acid, sebacic acid, phthalic acid, terephthalic acid, isophthalic acid, trimellitic acid, pyromellitic acid, tetrahydrophthalic acid, hexahydrophthalic acid, hexahydroterephthalic acid, di- and tetrachlorophthalic acid, endomethylenetetrahydrophthalic acid, glutaric acid, 1,4-cyclohexanedicarboxylic acid and an anhydride thereof.

6. The process for the production of a composite according to claim 4 , wherein resin components A) and/or D) comprise a carboxy-functionalised polyester.

7. The process for the production of a composite according to claim 2 , wherein the composition comprises a reactive resin as component E) which is selected from a resin obtained by polymerization of at least one selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isobornyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate; acrylamide, methacrylamide, dimethylaminoethyl (meth)acrylate and a poly(meth)acrylate.

8. The process for the production of a composite according to claim 2 , wherein the composition comprises a crosslinking agent as component E) and the crosslinking agent is at least one selected from the group consisting of allyl (meth)acrylate, 1,4-butanediol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, hexanediol diacrylate and trimethylolpropane tri(meth)acrylate, a polyester (meth)acrylate, a polyurethane (meth)acrylate and a poly(meth)acrylate.

9. The process for the production of a composite according to claim 1 , wherein a weight ratio of acid component A) to epoxy component B) is from 90:10 to 10:90.

10. The process for the production of a composite according to claim 1 , wherein the fibrous substrate comprises at least one layer comprising at least one material selected from the group consisting of a glass, a carbon, a plastic, a natural fibre and a mineral fibre.

11. The process for the production of a composite according to claim 1 , wherein the fibrous substrate is of a form selected from the group consisting of a non-woven textile sheet, a knitted fabric, a non-knitted fabric, a laid scrim, a braided fabric, a long-fibre material and a short-fibre material.

12. The process for the production of a composite according to claim 1 , wherein the fibrous substrate comprises at least one layer comprising at least one fibre selected from the group consisting of a glass fibre, a carbon fibre, an aramid fibre and a ceramic fibre.

13. The process for the production of a composite according to claim 1 , wherein component A) comprises at least one group selected from the group consisting of an acrylate group, a methacrylate group, and a vinyl ether group.

14. The process for the production of a composite according to claim 1 , wherein component A) comprises an acid selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, maleic acid, crotonic acid, itaconic acid, and vinylbenzoic acid.

15. The process for the production of a composite according to claim 1 , wherein component B) comprises at least one group selected from the group consisting of an acrylate group, a methacrylate group, and a vinyl ether group.

16. The process for the production of a composite according to claim 1 , wherein component B) comprises at least one selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, a reaction product of a polyepoxide with a substoichiometric quantity of acrylic acid and a reaction product of a polyepoxide with a substoichiometric quantity of methacrylic acid.

17. The process for the production of a composite according to claim 1 , wherein component B) comprises one selected from the group consisting of a reaction product of bisphenol A with a substoichiometric quantity of acrylic acid, a reaction product of bisphenol F with a substoichiometric quantity of acrylic acid, a reaction product of bisphenol A with a substoichiometric quantity of methacrylic acid, and a reaction product of bisphenol F with a substoichiometric quantity of methacrylic acid.

18. The process for the production of a composite according to claim 1 , wherein component C) is selected from the group consisting of permaleate, dilauroyl peroxide, dibenzoyl peroxide, tert-butyl peroctoate, di(tert-butyl)peroxide, di(tert-amyl)peroxide, tert-butyl peroxy(2-ethylhexyl) carbonate, N,N-dimethyl-p-toluidine, N,N-bis(2-hydroxyethyl)-p-toluidine and N,N-bis(2-hydroxypropyl)-p-toluidine.

19. A composite comprising at least one fibrous substrate and of at least one crosslinked reactive composition obtained according to the process of claim 1 .

Assignees

• Spyrou Emmanouil
• Loesch Holger
• Kreischer Susanne
• Thesing Andrea
• Evonik Degussa Gmbh

Inventors

• Spyrou Emmanouil
• Loesch Holger
• Kreischer Susanne
• Thesing Andrea

Classifications

• C08K7/14

  Glass · CPC title

• B29B15/105 Primary

  of reinforcement of definite length with a matrix in solid form, e.g. powder, fibre or sheet form (calendering B29C70/506) · CPC title

• B29K2307/04

  Carbon · CPC title

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title

• B29K2995/0096

  Dimensional stability · CPC title