Composition and method for controlling pests

Patent metadata

Field	Value
Publication number	US-9549559-B2
Application number	US-201414764524-A
Country	US
Kind code	B2
Filing date	Jan 30, 2014
Priority date	Jan 31, 2013
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

The present invention provides a composition for controlling pests comprising a compound represented by the formula (1):

wherein each of symbols are the same as defined in the Description, or N-oxide thereof; and

at least one compound selected from the group consisting of neonicotinoid compound, synthetic pyrethroid compound, phenylpyrazole compound, macrolide compound, diamide compound, and insecticidal compound selected from the group consisting of pymetrozine, pyridalyl, pyriproxyfen, spirotetramat, sulfoxaflo and flupyradifurone, which has an excellent control efficacy on pests.

First claim

The invention claimed is:

1. A composition for controlling pests comprising a compound represented by the formula (1) or N-oxide thereof and at least one compound selected from the below-mentioned Group (A);
the formula (1):

wherein
A 1 represents —NR 7 —, an oxygen atom, or a sulfur atom;
A 2 presents a nitrogen atom or ═CR 8 —;
R 1 represents a C1-C6 alkyl group which may be substituted with one or more atoms or group selected from Group X;
R 2 , R 3 and R 4 are the same or different to each other and each independently represent a C1-C6 alkyl group which may be substituted with one or more atoms or groups selected from Group X, a —OR 10 group, a —S(O) m R 10 group, a —S(O) 2 NR 10 R 11 group, a —NR 10 R 11 group, a —NR 10 CO 2 R 11 group, a —NR 10 C(O)R 11 group, a —CO 2 R 10 group, a —C(O)R 10 group, a —C(O)NR 10 R 11 group, a —SF 5 group, a cyano group, a nitro group, a halogen atom, or a hydrogen atom;
R 5 and R 6 are the same or different to each other and each independently represent a C1-C6 alkyl group which may be substituted with one or more atoms or groups selected from Group X, a —OR 10 group, a —S(O) m R 10 group, a —S(O) 2 NR 10 R 11 group, a —NR 10 R 11 group, a —NR 10 CO 2 R 11 group, a —NR 10 C(O)R 11 group, a —CO 2 R 10 group, a —C(O)R 10 group, a —C(O)NR 10 R 11 group, —OC(O)R 10 , a —SF 5 group, a cyano group, a nitro group, a halogen atom, or a hydrogen atom, wherein R 5 and R 6 do not represent a hydrogen atom at the same time;
R 7 represents a C1-C6 alkyl group which may be substituted with one or more atoms or groups selected from Group W, a —CO 2 R 10 group, a —C(O)R 10 group, a —CH 2 CO 2 R 10 group, a C3-C6 cycloalkyl group, or a hydrogen atom;
R 8 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a —OR 10 group, a —S(O) m R 10 group, a —NR 10 R 11 group, a —CO 2 R 10 group, a —C(O)R 10 group, a cyano group, a nitro group, a halogen atom, or a hydrogen atom;
R 10 and R 11 are the same or different to each other and each independently represent a C1-C6 alkyl group which may be substituted with one or more atoms or groups selected from Group X or a hydrogen atom, except for a —S(O) m R 10 group wherein m is 1 or 2 and R 10 is a hydrogen atom;
m independently represents 0, 1 or 2; and
n represents 0, 1 or 2;

Group X comprising
a C1-C6 alkoxy group which may be substituted with one or more halogen atoms,
a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms or one or more C1-C3 alkyl groups,
a cyano group,
a hydroxy group, and
a halogen atom;

Group W comprising:
a C1-C6 alkoxy group which may be substituted with one or more halogen atoms,
a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms,
a hydroxy group,
a halogen atom, and
a cyano group;

at least one compound selected from the below-mentioned Group (A):
group consisting of the following Sub-group A-1, A-2, A-3, A-4, A-5 and A-6:
Sub-group A-1:

neonicotinoid compound selected from the group consisting of imidacloprid, clothianidin thiamethoxam, dinotefuran, acetamiprid, thiacloprid and nitenpyram;
Sub-group A-2:

synthetic pyrethroid compound selected from the group consisting of acrinathrin, bifenthrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, etofenprox, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate fluvalinate, tau-fluvalinate, halfenprox, permethrin, silafluofen, tefluthrin, tralomethrin and protrifenbute;
Sub-group A-3:

phenylpyrazole compound selected from the group consisting of ethiprole, fipronil, acetoprole, vaniliprole, pyriprole and pyrafluprole;
Sub-group A-4:

macrolide compound selected from the group consisting of abamectin, emamectin, emamectin benzoate, milbemectine, doramectin and lepimectin;
Sub-group A-5:

diamide compound selected from the group consisting of flubendiamide and the compound represented by formula (2):

[wherein,
R 1 represents a methyl group or a bromine group,
R 2 represents a bromine atom, a chlorine atom or a cyano group,
R 3 represents a methyl group, a 1-cyclopropylmethyl group or a methoxycarbonylamino group, and
R 4 represents a hydrogen atom or an ethyl group]
Sub-group A-6:

insecticidal compound selected from the group consisting of pymetrozine, pyridalyl, pyriproxyfen, spirotetramat, sulfoxaflo and flupyradifurone.

2. The composition for controlling pests according to claim 1 , wherein in the compound represented by the formula (1) or N-oxide thereof,
R 1 is a C1-C6 alkyl group which may be substituted with one or more atoms or groups selected from Group Y;
R 2 and R 4 are hydrogen atoms;
R 3 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —C(OR 10 ) 3 group, a halogen atom, or a hydrogen atom;
R 5 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —OR 10 group, a —S(O) m R 10 group, a —CO 2 R 10 group, a —SF 5 group, or a halogen atom;
R 6 is a —OR 10 group, a —NR 10 R 11 group, a —CO 2 R 10 group, a —C(O)NR 10 R 11 group, —OC(O)R 10 , a cyano group, a halogen atom, or a hydrogen atom;
R 7 is a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a —CH 2 CO 2 R 10 group, a C3-C6 cycloalkyl group, or a hydrogen atom,
R 8 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —OR 10 group, a —S(O) m R 10 group, a cyano group, a halogen atom, or a hydrogen atom;
R 10 and R 11 are the same or different to each other and each independently represent a C1-C3 alkyl group which may be substituted with one or more halogen atoms or a hydrogen atom, except for a —S(O) m R 10 group wherein m is 1 or 2 and R 10 is a hydrogen atom; and
Group Y comprising:
a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms and
a halogen atom.

3. The composition for controlling pests according to claim 1 , wherein in the compound represented by the formula (1) or N-oxide thereof,
R 1 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms;
R 2 and R 4 are hydrogen atoms;

R 3 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —C(OR 10 ) 3 group, a halogen atom, or a hydrogen atom;
R 5 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —OR 10 group, a —S(O) m R 10 group, or a halogen atom;
R 6 is a cyano group, a —NR 10 R 11 group, a halogen atom, or a hydrogen atom;
R 7 is a C1-C6 alkyl group which may be substituted with one or more halogen atoms;
R 8 is a —S(O) m R 10 group, a cyano group, a halogen atom, or a hydrogen atom; and
R 10 and R 11 are the same or different to each other and each independently represent a C1-C3 alkyl group which may be substituted with one or more halogen atoms.

4. The composition for controlling pests according to claim 1 , wherein in the compound represented by the formula (1) or N-oxide thereof:
R 1 is an ethyl group;
R 2 and R 4 are hydrogen atoms;
R 3 is a C1-C3 alkyl group which may be substituted with one or more halogen atoms, a —C(OR 10 ) 3 group, a halogen atom, or a hydrogen atom;
R 5 is a C1-C3 haloalkyl group, a —OR 20 group, a —S(O) m R 20 group, or a halogen atom;
R 6 is a cyano group, a —NR 10 R 11 group, a halogen atom, or a h

Assignees

• Sumitomo Chemical Co

Inventors

• Shimizu Chie
• Kamezaki Masashi
• Nokura Yoshihiko

Classifications

• A01N43/707

  1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines · CPC title

• A01N51/00

  Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring · CPC title

• A01N43/40

  six-membered rings · CPC title

• A01N43/90 Primary

  having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system · CPC title

• A01N47/40

  the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides · CPC title