Low z high performance carbon composite materials

Patent metadata

Field	Value
Publication number	US-9546438-B2
Application number	US-201514694270-A
Country	US
Kind code	B2
Filing date	Apr 23, 2015
Priority date	Apr 23, 2015
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

A carbon/carbon part and processes for making carbon/carbon parts are provided. The process involves forming steps, carbonization steps and densification steps. The forming steps may include needling fibrous layers to form fibers that extend in three directions. Pressure may be applied to a fibrous preform at an elevated temperature to increase the fiber volume ratio of the fibrous preform. The densification steps may include filling the voids or pores of the fibrous preform with a carbon matrix.

First claim

The invention claimed is:

1. A method for forming a fibrous preform comprising:
superposing a first fibrous layer aligned in a machine direction with an additional fibrous layer aligned in an acute angle to the machine direction;
needling the first fibrous layer and the additional fibrous layer together at a needle density of between approximately 60 and 65 needle punches per square centimeter to form a first combined fibrous mat;
superposing an additional combined fibrous mat with the first combined fibrous mat;
needling the first combined fibrous mat and the additional combined fibrous mat at a needle density of between approximately 45 and 55 needle punches per square centimeter to form the fibrous preform comprising oxidized polyacrylonitrile (OPF) fibers extending in multiple directions and having pores extending therethrough,
wherein a fiber volume ratio of the fibrous preform is between about 30% fiber volume and about 35% fiber volume;
compressing the fibrous preform; and
carbonizing the fibrous preform by heating the fibrous preform to convert fibers of the fibrous preform into carbon fibers, wherein the fiber volume ratio of the fibrous preform after the carbonizing is between about 20% to 24% fiber volume.

2. The method of claim 1 , wherein the step of compressing the fibrous preform comprises applying a mechanical pressure to the fibrous preform during carbonizing to compress a thickness of the fibrous preform.

3. The method of claim 1 , wherein the step of compressing the fibrous preform comprises applying a mechanical pressure to the fibrous preform prior to carbonizing to compress a thickness of the fibrous preform at a temperature less than 200° C.

4. The method of claim 1 , further comprising densifying the fibrous preform by depositing a carbon matrix within at least a portion of the pores.

5. The method of claim 1 , wherein the additional fibrous layer is oriented at an angle between 30 degrees and 70 degrees to the machine direction.

6. The method of claim 1 , wherein the step of superposing comprises superposing at least two additional fibrous layers with the first fibrous layer at two separate acute angles to the machine direction.

7. The method of claim 1 , wherein the first fibrous layer is needled prior to the superposing with the additional fibrous layer.

8. A method for forming a fibrous preform comprising:
needling a first fibrous layer and an additional fibrous layer together at a needle density of between approximately 60 and 65 needle punches per square centimeter to form a first combined fibrous mat;
needling the first combined fibrous mat and an additional fibrous mat at a needle density of between approximately 45 and 55 needle punches per square centimeter to form the fibrous preform;
applying mechanical pressure to the fibrous preform prior to a carbonization step to compress a thickness of the fibrous preform and thereby increase a fiber volume ratio of the fibrous preform; and
carbonizing the fibrous preform by heating the fibrous preform in a furnace to convert the fibers into substantially carbon fibers, wherein the fiber volume ratio of the fibrous preform after the carbonizing is between about 20% and 24% fiber volume.

9. The method of claim 8 , wherein the mechanical pressure is applied at less than 200° C.

10. The method of claim 8 , wherein the mechanical pressure is applied for between 90 minutes and 180 minutes.

11. The method of claim 8 , wherein the mechanical pressure is applied along a direction of a plurality of z-fibers via a mechanical platen press.

12. The method of claim 11 , wherein the mechanical platen press generates a compressive force of between 10 lbs/in 2 (psi) and 60 psi on the fibrous preform.

13. The method of claim 8 , further comprising densifying the fibrous preform by depositing a carbon matrix within at least a portion of pores of the fibrous preform.

14. The method of claim 8 , wherein at least one of the first fibrous layer and the additional fibrous layer comprises oxidized polyacrylonitrile (OPF).

15. The method of claim 8 , wherein a fiber volume ratio of the fibrous preform before applying the mechanical pressure is between 30% fiber volume and 35% fiber volume.

Assignees

• Goodrich Corp

Inventors

• Fiala Robert

Classifications

• D04H1/43

  Acrylonitrile series · CPC title

• C04B35/83

  Carbon fibres in a carbon matrix · CPC title

• D04H1/46

  by needling or like operations to cause entanglement of fibres (D04H1/45 takes precedence; needling machines D04H18/00) · CPC title

• D04H1/4242 Primary

  Carbon fibres · CPC title

• F16D69/023

  Composite materials containing carbon and carbon fibres or fibres made of carbonizable material · CPC title