Polyamide mixture

Patent metadata

Field	Value
Publication number	US-9546273-B2
Application number	US-201414504475-A
Country	US
Kind code	B2
Filing date	Oct 2, 2014
Priority date	Oct 4, 2013
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

A composition, containing at least 50% by weight of a polyamide fraction which comprises: a) from 50 to 95 parts by weight of a polyamide having as copolymerized units bis(4-aminocyclohexyl)methane (PACM) and a linear dicarboxylic acid having from 8 to 18 C atoms; and b) from 50 to 5 parts by weight of a linear aliphatic polyamide having an average of from 8 to 12 C atoms in the monomer units, where the sum of the parts by weight of a) and b) is 100 is provided. The composition can be processed to give a moulded article having high transparency, high toughness and high resistance to chemicals, to solvents and to stress cracking.

First claim

The invention claimed is:

1. A composition, comprising:
at least 50% by weight of a polyamide fraction;
the polyamide fraction consisting of:
a) from 50 to 95 parts by weight of a polyamide consisting of copolymerized bis(4-aminocyclohexyl)methane (PACM) and a linear dicarboxylic acid having from 10 to 12 C atoms; and
b) from 50 to 5 parts by weight of a linear aliphatic polyamide having an average of 12 C atoms in the monomer units,
wherein the sum of the parts by weight of a) and b) is 100,
a relative solution viscosity (η rel ) of the linear aliphatic polyamide b) is from 1.3 to 2.4; and
a trans,trans-isomer content of the bis(4-aminocyclohexyl)methane (PACM) is from 30 to 70% by weight of total PACM.

2. The composition of claim 1 , wherein the composition is in a form selected from the group consisting of a pellet mixture, a powder mixture and a blend.

3. The composition of claim 1 , wherein the linear dicarboxylic acid is selected from the group consisting of decanedoic acid, undecanedoic acid and dodecanedoic acid.

4. The composition of claim 1 , wherein an enthalpy of fusion of the polyamide a), measured in accordance with ISO 11357 in the 2nd heating procedure and with a heating and cooling rate of 20° C./ min, is from 5 to 40 J/g.

5. The composition of claim 4 , wherein the enthalpy of fusion of the polyamide a) is from 8 to 35 J/g.

6. The composition of claim 1 , wherein a transmittance of an injection-moulded test specimen of thickness 2 mm of the polyamide a) is at least 85% and its haze is less than 3%, both determined in accordance with ASTM D1003.

7. The composition of claim 1 , wherein the linear aliphatic polyamide b) is selected from the group consisting of PA12, PA1212, PA1113, PA1014, PA1410, PA816 and PA618.

8. The composition of claim 1 , further comprising at most 50% by weight of at least one constituent selected from the group consisting of a flame retardant, a stabilizer, a plasticizer, glass fiber, a filler, an antistatic agent, a dye, a pigment, a mould-release agent, a flow aid, a compatibilizer and an impact modifier.

9. The composition of claim 8 , wherein the at least one constituent is a compatibilizer for the polyamide a) and the linear aliphatic polyamide b).

10. The composition of claim 9 , wherein the compatibilizer is a polyamine-polyamide graft copolymer comprising as copolymerized units:
a) from 0.5 to 25% by weight, based on the graft copolymer, of a branched polyamine having at least 4 nitrogen atoms and a number-average molar mass M n of at least 146 g/lmol and
b) from 99.5 to 75% by weight, based on the graft copolymer, of polyamide-forming monomers selected from the group consisting of a lactam, an ω-aminocarboxylic acid and an equimolar combination of a diamine and a dicarboxylic acid.

11. The composition of claim 10 , wherein after mixing in a melt, a transmittance of an injection-moulded test specimen of thickness 2 mm is at least 85% and its haze is less than 3%, both determined in accordance with ASTM D1003.

12. An article obtained by moulding the composition of claim 1 .

13. The article of claim 12 , wherein the article is one selected from the group consisting of a film, a bristle and a fiber.

14. The article of claim 12 , wherein the article is a spectacle frame or a spectacle lens.

15. The article of claim 12 , wherein the article is a component of a sports shoe.

Assignees

• Huelsmann Klaus
• Peirick Heinrich
• Gruhn Maximilian
• Castelli Luca
• Evonik Degussa Gmbh

Inventors

• Huelsmann Klaus
• Peirick Heinrich
• Gruhn Maximilian
• Castelli Luca

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08G69/26

  derived from polyamines and polycarboxylic acids · CPC title

• G02C7/02

  Lenses; Lens systems {; Methods of designing lenses} · CPC title

• G02C5/00

  Constructions of non-optical parts · CPC title