Cross-linked polycarbonate resin with improved chemical and flame resistance

Patent metadata

Field	Value
Publication number	US-9546244-B2
Application number	US-201414560354-A
Country	US
Kind code	B2
Filing date	Dec 4, 2014
Priority date	Dec 20, 2012
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

Disclosed herein are processes for preparing articles from compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. The article is molded, then exposed to UV radiation. A plaque including the composition can achieve a UL94 5VA rating.

First claim

What is claimed is:

1. A process for preparing an article having improved flame retardance, comprising:
(a) providing a composition comprising (i) a non-cross-linked polycarbonate comprising about 0.5 mol % to about 5 mol % endcap groups that are derived from a monohydroxybenzophenone and all other endcaps being derived from phenol, p-cumylphenol, or p-tertiary-butylphenol, and (ii) a flame retardant;
(b) molding the composition of step (a) into an article, or coating an article with the composition of step (a); and
(c) exposing the molded article or coated article of step (b) to UV-radiation by passing the article through a UV-chamber to affect cross-linking of the non-cross-linked polycarbonate;
wherein a plaque formed from the composition achieves a UL 94 5VA rating at a thickness of 3.0 mm±10% or less after UV exposure.

2. The process of claim 1 , wherein the non-cross-linked polycarbonate comprises about 1 mol % to about 3 mol % endcap groups, wherein all endcap groups are derived from the monohydroxybenzophenone.

3. The process of claim 1 , wherein the plaque achieves a UL94 5VA rating at a thickness of 2.0 mm±10%.

4. The process of claim 1 , wherein the plaque achieves a UL94 5VA rating at a thickness of 1.5 mm±10%.

5. The process of claim 1 , wherein the flame retardant is potassium perfluorobutane sulfonate (Rimar salt), potassium diphenyl sulfone-3-sulfonate (KSS), or a combination thereof.

6. The process of claim 1 , wherein the composition further comprises a cyclic siloxane.

7. The process of claim 1 , wherein the flame retardant is present in an amount of about 0.08 wt % or less, based on the total weight of the composition.

8. The process of claim 1 , wherein the plaque achieves a UL94 5VA rating in the absence of a brominated and/or chlorinated flame retardant.

9. The process of claim 1 , wherein the plaque has a transparency of 70% or greater at a thickness of 3.2 mm, measured according to ASTM-D1003-00.

10. The process of claim 1 , wherein the plaque has a haze value of less than 10% at a thickness of 3.2 mm, measured according to ASTM D1003-00.

11. The process of claim 1 , wherein when the exposed article is an ASTM part, the part has full ductility under multiaxial impact test conditions per ASTM D3763 at −30° C. determined using a 4-inch (10 cm) diameter, 3.2 millimeter (mm)-thick disk sample, ½-inch (12.7 mm) diameter dart, and an impact velocity of 3.3 meters per second (m/s).

12. The process of claim 1 , wherein when the exposed article is a ASTM Type 1 tensile bar, the bar has an elongation at break of at least 100% using the ASTM D 638 Type I method at 50 mm/min after exposure to acetone under 1% strain at 23° C.

13. The process of claim 1 , wherein when the exposed article is an ASTM part, the part has an elongation at break of 50% to about 200% according to ASTM D 638.

14. The process of claim 1 , wherein the non-cross-linked polycarbonate has a molecular weight greater than 17,000 Daltons and less than or equal to 80,000 Daltons, as measured by gel permeation chromatography using polycarbonate standards.

15. The process of claim 1 , wherein the non-cross-linked polycarbonate has a melt volume flow rate ranging from about 5 to about 30 cc/10 min at 300° C./1.2 kg.

16. The process of claim 1 , wherein the monohydroxybenzophenone is 4-hydroxybenzophenone.

17. The process of claim 1 , wherein the cross-linked polycarbonate comprises repeating units derived from bisphenol-A.

18. The process of claim 1 , wherein the non-cross-linked polycarbonate has repeating units having branching groups.

19. The process of claim 1 , wherein the non-cross-linked polycarbonate comprises a compound of formula (I),

wherein each repeating unit —O—Z—OC(═O)— is independently derived from a carbonate source and
(i) a monomer having the structure HO-A 1 -Y 1 -A 2 -OH wherein each of A 1 and A 2 comprise a monocyclic divalent arylene group, and Y 1 is a bridging group having one or more atoms; or
(ii) a monomer having the structure

wherein each R h is independently a halogen atom, a C 1 -C 10 hydrocarbyl, or a halogen substituted C 1 -C 10 hydrocarbyl, and n is 0 to 4;

R 1 is halogen, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, aryl, or arylalkyl;
R 2 is halogen, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, aryl, or arylalkyl;
x and y are 0; and
n′ ranges from 29 to 65.

20. The process of claim 19 , wherein the non-cross-linked polycarbonate comprises a compound of formula (II):

wherein n′ ranges from 29 to 65.

21. The process of claim 1 , wherein the plaque contains at least 5 wt % of an insoluble methylene chloride insoluble fraction in a 1 mm thick film.

22. The process of claim 1 , wherein the composition further comprises one or more additional polymers, and optionally one or more additives.

23. The process of claim 22 , wherein the composition further comprises a p-cumyl phenol capped poly(isophthalate-terephthalate-resorcinol ester)-co-(bisphenol-A carbonate) polymer or a polycarbonate polysiloxane copolymer wherein the polysiloxane content is from 0.4 wt % to 25 wt %.

24. The process of claim 23 , wherein the polycarbonate polysiloxane copolymer is a siloxane block co-polycarbonate comprising from about 6 wt % siloxane±10% to about 20 wt % siloxane±10%.

25. The process of claim 1 , wherein the plaque formed from the composition, comprising potassium perfluorobutane sulfonate (Rimar salt) in an amount of about 0.05 wt % to about 0.085 wt %, based on the total weight of the composition, achieves a UL94 5VA rating at a thickness of 3.0 mm±10% or less in the absence of a brominated and/or chlorinated flame retardant; and
wherein the plaque has a transparency of 70 to 90% at a thickness of 3.2 mm, measured according to ASTM-D1003-00.

26. The process of claim 25 , wherein the potassium perfluorobutane sulfonate (Rimar salt) is present in an amount of about 0.06 wt % to about 0.08 wt %.

27. The process of claim 25 , wherein the cross-linked polycarbonate does not contain any soft block segments from aliphatic polyesters, aliphatic polyethers, aliphatic polythioethers, aliphatic polyacetals, aliphatic polycarbonates, C-C linked polymers, or polysiloxanes.

28. The process of claim 25 , wherein the cross-linked polycarbonate does not contain any repeating units derived from a dihydroxybenzophenone, a trihydroxybenzophenone, or a tetrahydroxybenzophenone.

29. The process of claim 1 , wherein the article is at least one of an automotive bumper, an automotive exterior component, an automobile mirror housing, an automobile wheel cover, an automobile instrument panel or trim, an automobile glove box, an automobile door hardware or other interior trim, an automobile exterior light, an automobile part within the engine compartment, an agricultural tractor or device part, a construction equipment vehicle or device part, a marine or personal water craft part, an all terrain vehicle or all terrain vehicle part, plumbing equipment, a valve or pump, an air condit

Assignees

• Sabic Global Technologies Bv

Inventors

• Morizur Jean-Francois
• Sybert Paul Dean

Classifications

• C08G64/14 Primary

  containing a chain-terminating or -crosslinking agent · CPC title

• B29C2035/0827

  using UV radiation · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08G64/045

  containing aliphatic unsaturation · CPC title

• C08K5/5393

  Phosphonous compounds, e.g. R—P(OR')2 · CPC title