Method for producing polymer

Patent metadata

Field	Value
Publication number	US-9546240-B2
Application number	US-201314395987-A
Country	US
Kind code	B2
Filing date	Apr 24, 2013
Priority date	Apr 26, 2012
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

The present invention is related to a method for producing a polymer to efficiently remove metal residues of at least lithium and/or titanium from a polymer solution comprising the at least lithium and/or titanium to thereby obtain a refined polymer solution having little metal residue.

First claim

The invention claimed is:

1. A method of producing a polymer, comprising:
step 1 of preparing a polymer solution comprising at least (i) titanium or (ii) lithium and titanium;
step 2 of adding and mixing water in a volume 0.1 to 20 times a volume of the polymer solution and an organic acid compound of formula (1) to the polymer solution to thereby obtain a mixed liquid, wherein the mixing is carried out by using a rotary dispersing machine having a meshing structure; and
step 3 of removing a water phase from the mixed liquid to thereby obtain a refined polymer solution, wherein said formula (1) is represented by

wherein each of R 1 , R 2 and R 3 independently consists of a single element or a plurality of elements selected from the group consisting of C, H, O and N, and
wherein the organic acid compound comprises 4 or more oxygen atoms in the molecule, and
said organic acid compound of formula (1) is the only acid compound mixed with the polymer solution.

2. The method for producing the polymer according to claim 1 , wherein the organic acid compound has number of a hydroxyl group (provided that —OH of a carboxyl group is excluded) of 0 or 1.

3. The method for producing the polymer according to claim 2 , wherein the polymer solution further comprises aluminum.

4. The method for producing the polymer according to claim 2 , wherein the organic acid compound has a total number of oxygen atoms of 5 or more.

5. The method for producing the polymer according to claim 2 , wherein the organic acid compound has a total number of oxygen atoms of 7 or more.

6. The method for producing the polymer according to claim 2 , wherein the organic acid compound has a total number of carbon atoms of 20 or less.

7. The method for producing the polymer according to claim 2 , wherein the organic acid compound is a polyvalent carboxylic acid.

8. The method for producing the polymer according to claim 1 , wherein the polymer solution further comprises aluminum.

9. The method for producing the polymer according to claim 1 , wherein the organic acid compound has a total number of oxygen atoms of 5 or more.

10. The method for producing the polymer according to claim 1 , wherein the organic acid compound has a total number of oxygen atoms of 7 or more.

11. The method for producing the polymer according to claim 1 , wherein the organic acid compound has a total number of carbon atoms of 20 or less.

12. The method for producing the polymer according to claim 1 , wherein the organic acid compound is a polyvalent carboxylic acid.

13. The method for producing the polymer according to claim 1 , wherein the organic acid compound comprises 3 or more carboxyl groups.

14. The method for producing the polymer according to claim 1 , wherein in the step 2, an oxidizing agent is further added and mixed.

15. The method for producing the polymer according to claim 14 , wherein the oxidizing agent is hydrogen peroxide.

16. The method for producing the polymer according to claim 1 , wherein each of R 1 , R 2 and R 3 in the formula (1) independently consists of the single element or the plurality of elements selected from the group consisting of C, H and O.

17. The method for producing the polymer according to claim 1 , wherein in the step 3, the water phase comprises lithium and/or titanium.

18. The method for producing the polymer according to claim 1 , wherein in the step 2, the mixed liquid has an alcohol concentration of 500 ppm or less.

Assignees

• Asahi Kasei Chemicals Corp

Inventors

• Shimizu Daisuke
• Shibuya Kenta

Classifications

• C08F8/04

  Reduction, e.g. hydrogenation · CPC title

• C08F6/02

  Neutralisation of the polymerisation mass, e.g. killing the catalyst (short-stopping C08F2/42 ){also removal of catalyst residues} · CPC title

• C08C2/04 Primary

  Removal of catalyst residues · CPC title

• C08F6/04

  Fractionation · CPC title

• C08C19/02

  Hydrogenation · CPC title