Systems for converting ethane and ethanol to liquid transportation fuels

Patent metadata

Field	Value
Publication number	US-9545613-B2
Application number	US-201414571911-A
Country	US
Kind code	B2
Filing date	Dec 16, 2014
Priority date	Dec 20, 2013
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

Systems relating to thermal activation (or cracking) of ethane to an intermediate, low purity raw ethylene stream in a first stage. The system then mixes this stream with a stream of raw biomass-derived ethanol that may contain more than four volume percent of water. The resulting mixture is reacted over a suitable catalyst at temperatures and pressures suitable to produce gasoline-range and diesel-range blend stock.

First claim

We claim:

1. A system for converting ethane to liquid fuels, comprising:
a) an ethane stream;
b) a thermal activation unit adapted to operate at an internal temperature of between about 500° C. and about 1000° C. and comprising:
at least one inlet for receiving the ethane stream, said thermal activation unit adapted to convert the ethane stream to products comprising an intermediate hydrocarbon stream and a raw ethylene stream comprising less than 60 weight percent ethylene,
at least a first outlet for the intermediate hydrocarbon stream,
at least a second outlet for the raw ethylene stream;

c) a conversion unit adapted to operate at an internal temperature of between about 20° C. and 400° C. and comprising:
at least one catalyst contained within the conversion unit,
at least a first inlet adapted to receive the raw ethylene stream,
at least a second inlet adapted to receive a raw ethanol stream that is derived from biomass and comprises at least 4 volume percent water,
wherein the arrangement of the at least one first inlet and the at least one second inlet on the conversion unit are adapted to facilitate rapid mixing of the raw ethylene stream with the raw ethanol stream to form a mixture and convert the water to steam prior to contacting the at least one catalyst,
at least one outlet to convey a mixed product stream to a separation column; and

d) a separation column adapted to receive and separate the mixed product stream into an intermediate hydrocarbon stream comprising hydrocarbons containing four or more carbon atoms and a light hydrocarbon stream comprising hydrocarbons containing from one to three carbon atoms.

2. The system according to claim 1 , further comprising:
e) a fractionator adapted to separate the intermediate hydrocarbon stream into a gasoline fraction suitable for blending into gasoline fuel, and a diesel fraction suitable for blending into diesel fuel.

3. The system according to claim 1 , further comprising a separator adapted to receive the raw ethylene stream and to separate a hydrogen stream from the raw ethylene stream prior to combining the raw ethylene stream with the raw ethanol stream.

4. The system according to claim 1 , wherein the thermal activation unit is adapted to produce a raw ethylene stream comprising less than 40 weight percent ethylene.

5. The system according to claim 1 , wherein the raw ethanol stream comprises at least 20 weight percent water.

6. The system according to claim 1 , wherein the raw ethanol stream comprises at least 40 weight percent water.

7. The system according to claim 1 , wherein the raw ethanol stream comprises at least 60 weight percent water.

8. The system according to claim 1 , wherein the catalyst comprises a solid phosphoric acid catalyst, zeolite catalyst, Ni-containing catalyst or mixtures thereof.

9. The system according to claim 1 , further comprising:
f) a hydrogenation reactor adapted to receive and hydrogenate at least part of the light hydrocarbon stream and produce a mixture comprising light paraffins stream and hydrogen gas;
g) a separator adapted to receive the mixture and separate the hydrogen gas from the light paraffins stream;
h) a conduit adapted to receive and convey the light paraffins stream; and
i) a natural gas fractionator adapted to receive the light paraffins stream and produce the ethane stream.

10. The system according to claim 9 , wherein the conduit is adapted to convey the light paraffins stream from the separator to the thermal activation unit.

11. The system according to claim 9 , wherein the thermal activation unit is adapted to produce a raw ethylene stream comprising less than 40 weight percent ethylene.

12. The system according to claim 9 , wherein the raw ethanol stream comprises at least 20 weight percent water.

13. The system according to claim 9 , wherein the raw ethanol stream comprises at least 40 weight percent water.

14. The system according to claim 9 , wherein the raw ethanol stream comprises at least 60 weight percent water.

15. The system according to claim 9 , wherein the catalyst comprises a solid phosphoric acid catalyst, zeolite catalyst, Ni-containing catalyst or mixtures thereof.

Assignees

• Phillips 66 Co

Inventors

• Yao Jianhua
• Ghonasgi Dhananjay
• Choudhary Tushar
• Ewert Warren

Classifications

• B01J19/245 Primary

  placed in series · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C10L2200/0446

  Diesel · CPC title

• C10L1/06

  for spark ignition · CPC title

• C10G2300/1081

  Alkanes · CPC title