Solubilizing surfactants into supercritical carbon dioxide for enhanced oil recovery

Patent metadata

Field	Value
Publication number	US-9545606-B2
Application number	US-201113701575-A
Country	US
Kind code	B2
Filing date	Jun 3, 2011
Priority date	Jun 4, 2010
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

Embodiments of the present disclosure include a process and a system for solubilizing a surfactant in supercritical carbon dioxide that include providing a turbulent flow of the supercritical carbon dioxide into which the surfactant solubilizes and injecting the surfactant into the turbulent flow of the supercritical carbon dioxide to achieve a Jet Mixing Number of 0.01 to 1.0. In one or more embodiments, a pump provides turbulent flow to supercritical carbon dioxide moving through at least a portion of piping, and an injector associated with the piping conveys the surfactant through surfaces defining a port in the injector to inject the surfactant into the turbulent flow of the supercritical carbon dioxide so as to achieve the Jet Mixing Number of 0.01 to 1.0.

First claim

What is claimed is:

1. A process for solubilizing a surfactant in supercritical carbon dioxide, the process comprising:
providing a turbulent flow in piping of the supercritical carbon dioxide into which the surfactant solubilizes;
injecting the surfactant through a port in a tube that extends into the piping containing the turbulent flow of the supercritical carbon dioxide through the port in a direction that cuts across a longitudinal flow direction of the supercritical carbon dioxide to achieve a Jet Mixing Number of 0.01 to 1.0, wherein the Jet Mixing Number is equal to a product of a quotient of a jet velocity of the surfactant in the port and a velocity of the supercritical carbon dioxide in the piping and a quotient of a diameter of the port and a radius of the piping; and
producing a droplet diameter for the surfactant of less than a maximum stable droplet diameter calculated for a prevailing turbulent flow condition of the supercritical carbon dioxide.

2. The process of claim 1 , further including producing droplet diameters of the surfactant that have a residence time in the supercritical carbon dioxide of less than 700 seconds.

3. The process of claim 1 , where injecting the surfactant is at a predetermined volumetric value relative a volumetric flow rate of the supercritical carbon dioxide.

4. The process of claim 1 , where providing turbulent flow includes providing a fitting in the piping conveying the supercritical carbon dioxide and where injecting the surfactant into the turbulent flow of the supercritical carbon dioxide is adjacent the fitting.

5. The process of claim 1 , where providing turbulent flow includes providing a hollow conical insert in the piping conveying the supercritical carbon dioxide to increase a local velocity of the supercritical carbon dioxide near the injected surfactant.

6. A system for solubilizing a surfactant in supercritical carbon dioxide, the system comprising:
the supercritical carbon dioxide in piping;
a pump to provide a turbulent flow of the supercritical carbon dioxide through at least a portion of the piping; and
an injector associated with the piping, the injector conveying the surfactant through surfaces defining a port in the injector, where the injector is a tube that extends into the piping containing the supercritical carbon dioxide and where the surfactant is injected into the turbulent flow of the supercritical carbon dioxide through the port in a direction that cuts across a longitudinal flow direction of the supercritical carbon dioxide so as to achieve a Jet Mixing Number of 0.01 to 1.0, wherein the Jet Mixing Number is equal to a product of a quotient of a jet velocity of the surfactant in the port and a velocity of the supercritical carbon dioxide in the piping and a quotient of a diameter of the port and a radius of the piping to produce a droplet diameter for the surfactant of less than a maximum stable droplet diameter calculated for a prevailing turbulent flow condition of the supercritical carbon dioxide.

7. The system of claim 6 , where the piping includes fittings and the injector associated with the piping is associated with the fittings of the piping.

8. The system of claim 6 , where the piping includes a hollow conical insert in the piping to increase a local velocity of the supercritical carbon dioxide near the port.

9. The system of claim 6 , where the port of the tube is in a position so the surfactant is injected into the supercritical carbon dioxide at an angle that is perpendicular to a longitudinal flow direction of the turbulent flow.

10. The system of claim 6 , where the port in the injector allows the surfactant injected into the turbulent flow of the supercritical carbon dioxide to achieve a droplet diameter for the surfactant of less than a maximum stable droplet diameter calculated for a prevailing turbulent flow condition of the supercritical carbon dioxide.

11. The system of claim 10 , where the droplet diameter of the surfactant has a residence time in the supercritical carbon dioxide of less than 700 seconds.

12. The system of claim 6 , where the port in the injector is positioned approximately at a radial center of the piping.

13. The system of claim 6 , where the injector injects the surfactant at a predetermined volumetric value relative a volumetric flow rate of the supercritical carbon dioxide.

Assignees

• Cloeter Michael D
• Jones Raymond M
• Dow Global Technologies Llc

Inventors

• Cloeter Michael D
• Jones Raymond M

Classifications

• C09K8/594 Primary

  Compositions used in combination with injected gas {, e.g. CO2 orcarbonated gas}(C09K8/592 takes precedence) · CPC title

• B01F2215/0409

  Relationships between different variables defining features or parameters of the apparatus or process · CPC title

• Y10T137/0391

  Affecting flow by the addition of material or energy · CPC title

• B01F2215/0481

  Numerical speed values · CPC title

• B01F2215/0477

  Numerical time values · CPC title