Accelerating transport through graphene membranes

Patent metadata

Field	Value
Publication number	US-9545600-B2
Application number	US-201514703730-A
Country	US
Kind code	B2
Filing date	May 4, 2015
Priority date	Jan 27, 2012
Publication date	Jan 17, 2017
Grant date	Jan 17, 2017

Abstract

Technologies are generally described for a membrane that may incorporate a graphene layer perforated by a plurality of nanoscale pores. The membrane may also include a gas sorbent that may be configured to contact a surface of the graphene layer. The gas sorbent may be configured to direct at least one gas adsorbed at the gas sorbent into the nanoscale pores. The nanoscale pores may have a diameter that selectively facilitates passage of a first gas compared to a second gas to separate the first gas from a fluid mixture of the two gases. The gas sorbent may increase the surface concentration of the first gas at the graphene layer. Such membranes may exhibit improved properties compared to conventional graphene and polymeric membranes for gas separations, e.g., greater selectivity, greater gas permeation rates, or the like.

First claim

What is claimed is:

1. A membrane, comprising:
a graphene layer perforated by a plurality of nanoscale pores; and
a gas sorbent comprising a material perforated by a plurality of gas sorbent pores, wherein the material contacts a surface of the graphene layer such that at least one portion of the plurality of nanoscale pores and at least one portion of the plurality of gas sorbent pores are aligned and the at least one portion of the plurality of nanoscale pores is free from obstruction by the material, wherein the material adsorbs at least one gas and is permeable to the adsorbed at least one gas such that the gas sorbent is configured to direct the at least one gas into the plurality of nanoscale pores, and wherein a hydrogen and methane separation selectivity of the membrane is between about 200:1 and about 10^23:1.

2. The membrane of claim 1 , wherein the plurality of nanoscale pores have an average diameter in a range from about 0.1 nanometers to about 4 nanometers.

3. The membrane of claim 1 , wherein the plurality of nanoscale pores are substantially a same size such that the graphene layer has substantially uniform pore sizes throughout.

4. The membrane of claim 3 , wherein each of the plurality of nanoscale pores includes one or more carbon vacancy defects in the graphene layer such that the graphene layer has substantially uniform defects throughout.

5. The membrane of claim 1 , wherein the gas sorbent comprises a plurality of nanoparticles that have a diameter in a range from about 1 nanometer to about 250 nanometers.

6. The membrane of claim 1 , wherein the material comprises one or more of platinum, calcium oxide, magnesium oxide, magnesium salen, and cobalt salen.

7. The membrane of claim 1 , wherein the material comprises at least one of palladium or a permeable organic polymer.

8. The membrane of claim 1 , wherein the gas sorbent comprises at least one atomic monolayer.

9. The membrane of claim 8 , wherein the gas sorbent at the surface of the graphene layer is in a range between about 1 atom and about 1 micron in thickness.

10. The membrane of claim 1 , wherein the gas sorbent comprises palladium nanoparticles with an average diameter in a range from about 20 nanometers to about 100 nanometers.

11. The membrane of claim 1 , wherein the gas sorbent excludes gold nanoparticles.

12. A method to form a membrane, comprising:
providing a graphene layer perforated by a plurality of nanoscale pores;
providing a gas sorbent comprising a material perforated by a plurality of gas sorbent pores; and
contacting the gas sorbent to a surface of the graphene layer such that at least one portion of the plurality of nanoscale pores and at least one portion of the plurality of gas sorbent pores are aligned and the at least one portion of the plurality of nanoscale pores is free from obstruction by the material, wherein the material increases a surface concentration of at least one gas at the surface of the graphene layer, wherein the material adsorbs the at least one gas and is permeable to the adsorbed at least one gas such that the gas sorbent is configured to direct the at least one gas into the plurality of nanoscale pores, and wherein a hydrogen and methane separation selectivity of the membrane is between about 200:1 and about 10^23:1.

13. The method of claim 12 , wherein contacting the gas sorbent to the surface of the graphene layer includes applying at least a portion of the gas sorbent at the surface of the graphene layer as a plurality of gas sorbent nanoparticles.

14. The method of claim 12 , further comprising occluding at least another portion of the plurality of nanoscale pores with the material.

15. The method of claim 12 , wherein contacting the gas sorbent to the surface of the graphene layer includes contacting the gas sorbent to the surface of the graphene layer via one or more of: electrochemical deposition from a solution of the gas sorbent; chemical precipitation from a solution of the gas sorbent; dip coating, spin coating, contact printing, or jet coating of a suspension of gas sorbent nanoparticles; dip coating, spin coating, contact printing, or jet coating of a solution of soluble gas sorbent; atomic vapor deposition of the was sorbent; atomic layer deposition of the gas sorbent; chemical vapor deposition of the gas sorbent; physical vapor deposition of the gas sorbent; and/or electrostatic deposition of particles of the gas sorbent.

16. A method to separate a gas from a fluid mixture, comprising:
providing a fluid mixture that includes a first gas and a second gas, wherein a molecule of the second gas is larger than a molecule of the first gas;
providing a graphene layer perforated by a plurality of nanoscale pores, wherein each of the plurality of nanoscale pores has a diameter that selectively facilitates passage of the first gas compared to the second gas;
providing a gas sorbent that comprises a material perforated by a plurality of gas sorbent pores, wherein the material contacts a surface of the graphene layer such that at least one portion of the plurality of nanoscale pores and at least one portion of the plurality of gas sorbent pores are aligned and the at least one portion of the plurality of nanoscale ores is free from obstruction by the material;
increasing a concentration of the first gas at the surface of the graphene layer by contacting the fluid mixture to the gas sorbent at the graphene layer, wherein the material adsorbs the first gas and is permeable to the first gas such that the gas sorbent is configured to direct the first gas into the plurality of nanoscale pores; and
selectively separating the first gas from the second gas according to size by employing the plurality of nanoscale pores perforated in the graphene layer, wherein a hydrogen and methane separation selectivity is between about 200:1 and about 10^23:1.

17. The method of claim 16 , wherein selectively separating the first gas from the second gas includes directing the first gas through the plurality of nanoscale pores by applying a processing gradient across the graphene layer, wherein the processing, gradient corresponds to one or more of a temperature gradient, a pressure gradient, a gas concentration gradient, or an electric field gradient.

18. The method of claim 16 , wherein increasing the concentration of the first gas at the surface of the graphene layer includes increasing a concentration of the first gas within about 1 micron of the graphene layer.

Assignees

• Empire Technology Dev Llc

Inventors

• Miller Seth A
• Duerksen Gary L

Classifications

• B01D71/021

  Carbon · CPC title

• B01D2325/12

  Adsorbents being present on the surface of the membranes or in the pores · CPC title

• B01D67/0069

  by deposition from the liquid phase, e.g. electrochemical deposition (B01D67/0046 takes precedence) · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• B01D53/229 Primary

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title