Fuel cell and proces for manufacturing a fuel cell

Patent metadata

Field	Value
Publication number	US-9543606-B2
Application number	US-201414221955-A
Country	US
Kind code	B2
Filing date	Mar 21, 2014
Priority date	Oct 10, 2007
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

The present invention pertains to a fuel cell with a storage unit ( 4 ) for storing hydrogen (H x ), with a proton conductive layer, which covers a surface of the storage unit ( 4 ), and with a cathode ( 7 ) on a side of the proton conductive layer, which side is located opposite, wherein the storage unit ( 4 ) is directly coupled with an anode and/or the storage unit ( 4 ) is incorporated in a substrate ( 1 ) of a semiconductor. The storage unit ( 4 ) is preferably connected to the substrate ( 1 ) at least via a stress compensation layer ( 3 ).

First claim

The invention claimed is:

1. A fuel cell comprising:
a storage unit for storing hydrogen;
a proton-conductive layer, which covers a first surface of said storage unit; and
a cathode on a side of said proton-conductive layer, the side being located opposite said storage unit,
wherein said storage unit is directly coupled with an anode and said storage unit is arranged within a cavity in a substrate of a semiconductor, and wherein the storage unit has a lamellar structure filling the cavity, the lamellar structure being composed of palladium.

2. The fuel cell of claim 1 , wherein a second surface of the storage unit, adjacent to the substrate, is covered with a hydrogen diffusion barrier.

3. A fuel cell, comprising:
a storage unit for storing hydrogen;
a proton-conductive layer that covers a first surface of the storage unit;
a cathode disposed on a first side of the proton-conductive layer, the side being located opposite the storage unit, wherein the storage unit, capable of absorbing hydrogen, forms an anode and is embedded in a cavity or depression of a substrate comprising silicon;
a hydrogen diffusion barrier formed between the storage unit and the substrate; and
a stress compensation layer formed between the storage unit and the substrate.

4. The fuel cell of claim 3 , wherein the hydrogen diffusion barrier is disposed on a second surface of the storage unit opposite the proton diffusion layer and adjacent to the substrate.

5. The fuel cell of claim 3 , wherein a portion of the proton-conductive layer is formed between the anode and the cathode.

6. The fuel cell of claim 3 , wherein the stress compensation layer is formed between the hydrogen diffusion barrier and the storage unit.

7. The fuel cell of claim 6 , further comprising a bonding agent layer formed between the hydrogen diffusion barrier and the stress compensation layer.

8. The fuel cell of claim 7 , wherein the bonding agent layer is made of polysilicon and an electroplating starting layer.

9. The fuel cell of claim 8 , wherein the polysilicon comprises a palladium-silicide layer.

10. The fuel cell of claim 3 , wherein the stress compensation layer is formed between the hydrogen diffusion barrier and the substrate.

11. The fuel cell of claim 3 , wherein the stress compensation layer is formed from a ductile material, the ductile material comprising tin, gold, silver, lead, cadmium, or indium.

12. The fuel cell of claim 3 , wherein the stress compensation layer is formed on all surfaces of the storage unit that directly face the substrate.

13. The fuel cell of claim 3 , wherein the hydrogen diffusion barrier between the storage unit and the substrate is formed such that hydrogen is reduced or cannot escape from the storage unit to the substrate.

14. The fuel cell of claim 3 , wherein the hydrogen diffusion barrier is formed from silicon nitride or silicon oxide or an oxynitride layer.

15. The fuel cell of claim 3 , wherein the storage unit is completely surrounded by a combination of the proton conductive layer and the hydrogen diffusion barrier, wherein a portion of a circumferential area of the storage unit is covered by the proton-conductive layer and a remaining portion of the circumferential area is covered by the hydrogen diffusion barrier, and wherein the proton conducting layer is a proton-conducting and non-hydrogen-conducting layer.

16. The fuel cell of claim 3 , wherein the first surface of the storage unit is in contact with a second side of the proton-conductive layer, and wherein, on the first side of the proton-conductive layer opposite the second side, a self-breathing air diffusion layer is formed as the cathode, wherein the self-breathing air diffusion layer is porous and allows for the passage of air or oxygen.

17. The fuel cell of claim 3 , wherein the cathode extends, on at least one circumferential edge region, laterally from the proton-conductive layer to the substrate.

18. The fuel cell of claim 3 , wherein an anode contact is formed, which extends from an edge area on the first surface of the storage unit, across edge sections of the stress compensation layer and the hydrogen diffusion barrier, to a surface of the substrate.

19. A monolithic arrangement comprising: CMOS technology and an integrated fuel cell according to claim 3 .

Assignees

• Micronas Gmbh

Inventors

• Lehmann Mirko
• Mueller Claas
• Reinecke Holger
• Frank Mirko
• Erdler Gilbert

Classifications

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M8/1097

  Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports · CPC title

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• H01M4/383

  Hydrogen absorbing alloys · CPC title

• H01M8/065

  by dissolution of metals or alloys; by dehydriding metallic substances · CPC title